Ultrabroadband metal-black absorbers and the performance simulations based on a three-dimensional cluster-structure model.

Abstract

Broadband light absorbers are attractive for their applications in photodetection and thermo-photovoltaics. Metal-black porous coatings have been experimentally proven to have broadband light absorption. However, a theoretical model is of importance for the design and fabrication of metal-black absorbers. Here we propose a three-dimensional cluster-structure model to simulate the absorption of metal-black films. Based on experimental data, a model of uniform clusters formed by nanoparticles with Gaussian random distribution in position was constructed for the gold-black absorbers. The absorption spectra were simulated with this model by finite-difference time-domain method. The gold-black absorbers were fabricated by the one-step magnetron sputtering process. The average absorption of gold-black absorbers with sputtering pressure of 50, 65 and 80\u2005Pa were 72.34%, 87.25% and 91.08% in the visible spectral range and 81.77% (80\u2005Pa) in 3-12 µm infrared spectrum. The high broadband absorption was attributed to the multiple scattering of incident light inside the gold-black porous structure. The simulations showed good agreements with experimental results with an error of 2.35% in visible spectrum and 1.82% in 3-12 µm infrared spectrum. To verify the applicability of this model, aluminum-black absorbers with different thicknesses were fabricated, and the absorption error between simulation and experimental results was 3.96%. This cluster model can be a good tool to design ultrabroadband absorbers based on metal-black porous structures.