Interlaminar aligned carbon nanotubes spraying process and fracture toughness of CFRP

Abstract

Co-precipitation method was applied for grafting magnetic Fe3O4 particles on carbon nanotubes. In order to improve the interlayer properties of carbon fiber reinforced polymer (CFRP), the magnetic carbon nanotubes (Fe3O4-MWCNTs) were aligned on the surface of carbon fiber by spraying process after exposure to magnetic field to form ‘carbon fiber-aligned carbon nanotubes-resin’ interface, and were fixed by spraying the resin. Aligned Fe3O4-MWCNTs-reinforced CFRP with excellent interlaminar properties was prepared by vacuum assisted resin infusion (VARI) molding. The test results show spraying resin plays an important role in consolidating and improving aligned spraying process. Compared with non-magnetic spraying process, when the mass fraction of Fe3O4-MWCNTs is 0.3wt%, the mode I interlaminar fracture toughness (GIC) increases by up to 37.7%. The main toughening mechanisms, which are pull-out and rupture of Fe3O4-MWCNTs aggregates, plastic deformation and plastic void growth of resin, are revealed by the fracture surface morphology. The research provides a new idea and method for interface modification of CFRP by adding Fe3O4-MWCNTs with controlled aligned behavior.