The effect of the selected remediation medium on the cadmium bioavailability in the selected ecosystem in the Southwestern locality of Slovakia

Abstract

Abstract Soil is a sensitive ecological factor. Biodegradable materials from the environment can also be used to deal with serious ecological problems. Soil affecting by remediation medium - garden compost - was analysed for toxic cadmium (Cd) in terms of environmental protection. The objective of this research was to analyse soil and compost at foothill locality of the Tribeč Mountains (Southwestern Slovakia) in the years 2015−2017 to determine Cd contents in soil and compost, pH and to assess Cd bioavailability. The analyses were carried out using the Atomic Absorption Spectrometry with seven-step Selective Sequential Extraction methods. The results obtained were evaluated statistically using the SAS 9.4 software method by Spearman’s correlation coefficient. The results showed that Cd contents in soil had reached 2.96 mg kg−1 and soil with compost (the ratio 1:1) 2.71 mg kg−1 dry matter. Cd contents in the soil exceeded maximum allowed limit of 196%. And deceased by 25% after adding compost. The pH in soil with compost varied from 6.78 to 7.98. The pH prevented the mobility of Cd about 8.3% in average. Statistical dependence was high, which was demonstrated for relationship between Cd in soil, pH and compost. Available Cd forms in soil were 53.3% and soil with compost were 45% in average. The garden compost as a remediation medium reduced Cd bioavailability.