Effect of oxygen and bismuth impurities on the structural and physicochemical properties of nickel melts

Abstract

There are practically no data in the literature on the combined effect of oxygen and bismuth impurities on the structural and physicochemical properties of nickel melts or heat-resistant alloys based on it. In the presented work, the state of pure nickel and nickel melts containing (0.005-0.01) bismuth and oxygen is considered in the process of refining from oxygen and bismuth impurities. The influence of these impurities on the structural and physicochemical properties was studied, which was evaluated by the parameters of the density and surface tension of the melts. In nickel melts with bismuth and oxygen, a compression effect and a negative deviation from Raoult’s law were observed. The effect of an increase in the surface tension of a nickel melt containing oxygen with an increase in the concentration of bismuth is found, which corresponds to the isotherm of desorption of excess substance from the surface into the bulk.