Archive | 2021
Letter of Reply to Referee 2
Abstract
Triple-wavelength lidar profiles of the depolarization ratio and the backscatter coefficient of marine aerosol as a function of relative humidity (RH) are presented with a 5-min time resolution. The measurements were performed at Barbados (13°N, 59°W) during the Saharan Aerosol Long-range Transport and Aerosol-Cloud interaction Experiment (SALTRACE) winter campaign in February 2014. The phase transition from spherical sea salt particles to cubic-like sea salt crystals was observed under atmospheric conditions with a polarization lidar. The radiosonde and water-vapor 5 Raman lidar observations show a drop in RH below 50% in the marine aerosol layer simultaneously with a strong increase in particle linear depolarization ratio, which reaches values up to 0.12±0.08 (at 355 nm), 0.15±0.03 (at 532 nm), and 0.10±0.01 (at 1064 nm). The lidar ratio (extinction-to-backscatter ratio) increased from 19 sr and 23 sr for spherical sea salt particles to 27 sr and 25 sr (at 355 and 532 nm, respectively) for cubic-like particle ensembles. Furthermore the scattering enhancement due to hygroscopic growth of the marine aerosol particles under atmospheric conditions 10 was measured. Extinction enhancement factors from 40% to 80% RH of 1.94±0.94 at 355 nm, 3.70±1.14 at 532 nm, and 5.37±1.66 at 1064 nm were found. The enhanced depolarization ratios and lidar ratios were compared to modeling studies of cubic sea salt particles.