With the rapid increase in global demand for clean energy, proton exchange membrane fuel cells (PEMFC) have gradually attracted attention. This technology not only has high hopes for transportation applications, but also includes stationary and portable fuel cells. Its unique low-temperature operating range and specialized proton-conducting polymer electrolyte make PEMFC show great potential to replace aging alkaline fuel cell technology. So, what is so special about this technology that it can lead the future transportation revolution?
The core of the proton exchange membrane fuel cell is its membrane electrode assembly (MEA), which consists of electrodes, electrolytes, catalysts and gas diffusion layers. During operation, hydrogen enters the anode and is decomposed into protons and electrons under the action of a catalyst. The electrons travel through an external circuit to create an electric current, while the protons travel through the polymer electrolyte membrane to the cathode, where they eventually react with oxygen to produce water.
Proton exchange membrane fuel cells are designed to make full use of the chemical energy of hydrogen and oxygen to generate electricity through changes in electron flow, a process that is completely different from traditional combustion reactions.
The main advantages of PEMFC include easy sealing, low operating temperature, and high power density, which make them very attractive for transportation applications. For cold start and high energy density requirements, PEMFC shows its superior performance and can start normally in a -20°C environment. Despite this, PEMFC still faces numerous challenges, such as water management, catalyst fragility, and operating temperature limitations.
Water management is critical in the performance of PEM systems. Too much or too little water can affect the stability and power output of the fuel cell.
Although platinum catalysts can effectively overcome the reaction of hydrogen and oxygen, they are easily affected by carbon monoxide and metal ion contamination, challenging their efficiency. In response to these problems, many researchers are looking for efficient catalyst materials and alternative polymer electrolytes to overcome bottlenecks in current technologies.
The current market mostly uses Nafion materials as membranes, but its sensitivity to high temperatures and moisture limits its application in extreme environments.
As an emerging technology, metal-organic framework materials (MOFs) have attracted attention due to their superior physical and chemical properties. MOFs allow the design of electrolytes to be extremely flexible, maintain good conductive properties in low to high temperature ranges, and have the potential to replace traditional polymer membranes. Therefore, they may play an important role in fuel cell applications.
The tunability of MOFs and their tolerance in a variety of operating environments have opened up new paths for the advancement of fuel cell technology.
The development of proton exchange membrane fuel cells is undoubtedly one of the key technologies in future transportation applications. As technology advances, the challenges faced are gradually being solved. With the development of new materials, will PEMFC become a mainstream clean energy technology?