A. A. Polokhin

Development of matrix photoreceivers based on carbon nanotubes array

The technology of production of matrix photoreceivers based on carbon nanotubes (CNTs) consisting of 16 sensitive elements was developed. Working wavelength range, performance and sensitivity were studied.

Laser nanocomposites based on proteins and carbon nanotubes for restoration of biological tissues

The study of structural properties of nanocomposites, based on different types of single walled carbon nanotubes (SWCNTs) and proteins (albumin, collagen), was carried out. The binding of protein molecules to the carbon component was described by Raman spectroscopy. Complex analysis of the structure and microporosity of nanocomposites was performed by the X-ray microtomography. The nanoporosity study was carried out using the low-temperature nitrogen porosimetry method. Samples based on SWCNTs with smaller size had the most homogeneity. With an increase in the concentration from 0.01 to 0.1 %, the mean micropore size increased from 45 to 93 μm, porosity in general increased from 16 to 28 %. The percentage of open pores was the same for all samples and was 0.02. As it was shown by Raman spectroscopy the protein component in nanocomposites has undergone irreversible denaturation and can act as a biocompatible binder and serve as a source of amino acids for biological tissues. These nanocomposites are bioresorbable and can be used to repair cartilage and bone tissue. This is especially important in the treatment of diseases of hyaline cartilage and subchondral bone.

Study of laser radiation detection by matrix sensor based on carbon nanotubes array

Presently laser radiation is widely used in the variety of fields. This indicates the necessity of the control the intensity of laser radiation. In this case use the sensors - devices that convert laser radiation into an electronic signal. Using carbon nanotubes (CNTs) in sensor design is perspective direction, which can lead to of creating devices with impressive parameters.

Optimization of the synthesis of carbon nanotubes to improve the efficiency of chemical posttreatments of the prepared material

We report the experimental results that allow optimizing the synthesis of multiwalled carbon nanotubes by chemical vapor deposition. The optimal composition of a catalyst and technique for its fabrication are found. The role of the hydrogen contained in the gas mixture is studied. The poured density of the synthesized material was decreased by 25% and the efficiency of the process almost doubled.

Development of the device prototype based on the semiconductor–carbon nanotubes structure for optical radiation detection and study of its parameters

A light-receiving device prototype based on the semiconductor–carbon nanotubes (CNTs) structure consisting of 16 cellular structured sensitive elements grown on the same substrate is developed. The topology of sensitive cells represents holes through metallization and insulator layers to the semiconductor from which the CNT array grows to the top metallization layer. The device prototype parameters are determined as follows: the effective wavelength range is within 400–1100 nm, the operational speed is no longer than 30 μs, the coefficients of peak sensitivity reached at wavelengths of 640 and 950 nm are 197 and 193 μA/W, respectively.

Creation of advanced optical limiters based on J-type phthalocyanine dimers and their conjugates with single-walled carbon nanotubes

Creation of effective means of protection from laser radiation of high power requires the development of optical materials (working substance), with their transparence being decreased sharply above a certain critical value of the laser intensity due to the appearance of non-linear optical properties (limiting threshold). Based on the threshold model, the working substance of the optical limiter was characterized. Experimental data of z-scan with open aperture are used to determine the nonlinear optical parameters of solutions of dimeric phthalocyanine complexes of Mg and Zn of J-type in tetrahydrofuran (THF) and thin films of their conjugates with single-walled carbon nanotubes (SWCNTs). The output characteristic (output (peak) fluence vs input (peak) fluence), that describes the basic properties of optical limiters, was obtained with the fixed location of the optical limiter. Dimeric phthalocyanine complexes were found to have low limiting threshold ~ 2 MW·cm-2 and high value of the nonlinear absorption coefficient ~ 330 and 370 cm GW-1, respectively. Conjugates of these dimeric phthalocyanines with SWCNTs have been produced for the improving of the limiting parameters and increasing of the optical nonlinearity. Size of J-type dimeric phthalocyanine complexes of Mg and Zn were determined by the scanning electron microscopy (SEM). The atomic force microscopy (AFM) allowed to determine the dimensions of nanotubes. The structure parameters, such as diameter and defects as well as the strength of aggregates were estimated with the Raman spectroscopy. For our experiments, the lens with a focal length of 20 cm was used. As the laser radiation source, the Nd:YAG laser was used to generate pulses of 16 ns duration at a wavelength of 532 nm with the linearly polarized laser beam in the horizontal plane and a shape closed to Gaussian type.