A. Belloche

Complex organic molecules in the interstellar medium: IRAM 30 m line survey of Sagittarius B2(N) and (M)

The discovery of amino acids in meteorites and the detection of glycine in samples returned from a comet to Earth suggest that the interstellar chemistry is capable of producing such complex organic molecules. Our goal is to investigate the degree of chemical complexity that can be reached in the ISM. We performed an unbiased, spectral line survey toward Sgr B2(N) and (M) with the IRAM 30m telescope in the 3mm window. The spectra were analyzed with a simple radiative transfer model that assumes LTE but takes optical depth effects into account. About 3675 and 945 spectral lines with a peak signal-to-noise ratio higher than 4 are detected toward N and M, i.e. about 102 and 26 lines per GHz, respectively. This represents an increase by about a factor of 2 over previous surveys of Sgr B2. About 70% and 47% of the lines detected toward N and M are identified and assigned to 56 and 46 distinct molecules as well as to 66 and 54 less abundant isotopologues of these molecules, respectively. We also report the detection of transitions from 59 and 24 catalog entries corresponding to vibrationally or torsionally excited states of some of these molecules, respectively. Excitation temperatures and column densities were derived for each species but should be used with caution. Among the detected molecules, aminoacetonitrile, n-propyl cyanide, and ethyl formate were reported for the first time in space based on this survey, as were 5 rare isotopologues of vinyl cyanide, cyanoacetylene, and hydrogen cyanide. We also report the detection of transitions from within 12 new vib. or tors. excited states of known molecules. Although the large number of unidentified lines may still allow future identification of new molecules, we expect most of these lines to belong to vib. or tors. excited states or to rare isotopologues of known molecules for which spectroscopic predictions are currently missing. (abridged)

Toward understanding the formation of multiple systems - A pilot IRAM-PdBI survey of Class 0 objects

Context. The formation process of binary stars and multiple systems is poorly understood. The multiplicity rate of Class II premain-sequence stars and Class I protostars is well documented and known to be high (∼ 30% to 50% between ∼100 and 4000 AU). However, optical / near-infrared observations of Class I/Class II YSOs barely constrain the pristine properties of multiple systems, since dynamical evolution can quickly alter these properties during the protostellar phase. Aims. Here, we seek to determine the typical outcome of protostellar collapse and to constrain models of binary formation by core fragmentation during collapse, using high-resolution millimeter continuum imaging of very young (Class 0) protostars observed at the beginning of the main accretion phase. Methods. We carried out a pilot high-resolution study of 5 Class 0 objects, including 3 Taurus sources and 2 Perseus sources, using the most extended (A) configuration of the IRAM Plateau de Bure Interferometer (PdBI) at 1.3 mm. Our PdBI observations have a typical HPBW resolution ∼0.3 �� −0.5 �� and rms continuum sensitivity ∼0.1− 1m Jy/beam, which allow us to probe the multiplicity of Class 0 protostars down to separations a ∼ 50 AU and circumstellar mass ratios q ∼ 0.07. Results. We detected all 5 primary Class 0 sources in the 1.3 mm dust continuum. A single component associated with the primary Class 0 object was detected in the case of the three Taurus sources, while robust evidence of secondary components was found toward the two Perseus sources: L1448-C and NGC1333-IR2A. We show that the secondary 1.3 mm continuum component detected ∼600 AU south-east of L1448-C, at a position angle close to that of the CO(2−1) jet axis traced by our data, is an outflow feature directly associated with the powerful jet driven by L1448-C. The secondary 1.3 mm continuum component detected ∼1900 AU southeast of NGC1333-IR2A may either be a genuine protostellar companion or trace the edge of an outflow cavity. Therefore, our PdBI observations revealed only wide (>1500 AU) protobinary systems and/or outflow-generated features. Conclusions. When combined with previous millimeter interferometric observations of Class 0 protostars, our pilot PdBI study tentatively suggests that the binary fraction in the ∼75−1000 AU range increases from the Class 0 to the Class I stage. It also seems to argue against purely hydrodynamic models of binary star formation. We briefly discuss possible alternative scenarios to reconcile the low multiplicity rate of Class 0 protostars on small scales with the higher binary fraction observed at later (e.g. Class I) evolutionary stages.

Spectral imaging of the Central Molecular Zone in multiple 3-mm molecular lines

We have mapped 20 spectral lines in the Central Molecular Zone (CMZ) around the Galactic Centre, emitting from 85.3 to 93.3 GHz. This work used the 22-m Mopra radio telescope in Australia, equipped with the 8-GHz bandwidth University of New South Wales-Mopra Spectrometer (UNSW-MOPS) digital filter bank, obtaining ∼2 km s−1 spectral and ∼40 arcsec spatial resolution. The lines measured include emission from the c-C3H2, CH3CCH, HOCO+, SO, H13CN, H13CO+, SO, H13NC, C2H, HNCO, HCN, HCO+, HNC, HC3N, 13CS and N2H+ molecules. The area covered is Galactic longitude −0bsl000647 to 1bsl000648 and latitude −0bsl000643 to 0bsl000642, including the bright dust cores around Sgr A, Sgr B2, Sgr C and G1.6−0.025. We present images from this study and conduct a principal component analysis on the integrated emission from the brightest eight lines. This is dominated by the first component, showing that the large-scale distribution of all molecules is very similar. We examine the line ratios and optical depths in selected apertures around the bright dust cores, as well as for the complete mapped region of the CMZ. We highlight the behaviour of the bright HCN, HNC and HCO+ line emission, together with that from the 13C isotopologues of these species, and compare the behaviour with that found in extragalactic sources where the emission is unresolved spatially. We also find that the isotopologue line ratios (e.g. HCO+/H13CO+) rise significantly with increasing redshifted velocity in some locations. Line luminosities are also calculated and compared to that of CO, as well as to line luminosities determined for external galaxies.

Detection of a branched alkyl molecule in the interstellar medium: iso-propyl cyanide

Carbon chains branch out on space dust Meteorites found on Earth contain a wide range of complex constituent molecules, including amino acids. Astrochemists proposed the existence of these molecules in interstellar space in the 1980s, but detections have been elusive. Belloche et al. used the ALMA telescope array in Chile to observe the massive star-forming region Sgr B2. There, the vast quantities of gas enabled detection of even sparsely distributed species such as iso-propyl cyanide. Despite being difficult to detect, such nonlinear organic molecules may be common. The formation of branched molecules is important, given the analogous structure of familiar amino acids — some of the building blocks for life. Science, this issue p. 1584 Millimeter-wave emission is detected from branched carbon-chain molecules that may form on interstellar dust-grain surfaces. The largest noncyclic molecules detected in the interstellar medium (ISM) are organic with a straight-chain carbon backbone. We report an interstellar detection of a branched alkyl molecule, iso-propyl cyanide (i-C3H7CN), with an abundance 0.4 times that of its straight-chain structural isomer. This detection suggests that branched carbon-chain molecules may be generally abundant in the ISM. Our astrochemical model indicates that both isomers are produced within or upon dust grain ice mantles through the addition of molecular radicals, albeit via differing reaction pathways. The production of iso-propyl cyanide appears to require the addition of a functional group to a nonterminal carbon in the chain. Its detection therefore bodes well for the presence in the ISM of amino acids, for which such side-chain structure is a key characteristic.

Submillimeter absorption from SH+, a new widespread interstellar radical, 13CH+ and HCl

We have used the Atacama Pathfinder Experiment 12 m telescope (APEX) to carry out an absorption study of submillimeter wavelength rotational ground-state lines of H 35 Cl, H 37 Cl, 13 CH + , and, for the first time, of the SH + radical (sulfoniumylidene or sulfanylium). We detected the quartet of ground-state hyperfine structure lines of SH + near 683 GHz with the CHAMP+ array receiver against the strong continuum source Sagittarius B2, which is located close to the center of our Galaxy. In addition to absorption from various kinematic components of Galactic center gas, we also see absorption at the radial velocities belonging to intervening spiral arms. This demonstrates that SH + is a ubiquitous component of the diffuse interstellar medium. We do not find clear evidence for other SH + lines we searched for, which is partially due to blending with lines from other molecules. In addition to SH + , we observed absorption from H 35 Cl, H 37 Cl, and 13 CH + . The observed submillimeter absorption is compared in detail with absorption in 3 mm transitions of H 13 CO + and c-C3H2 and the CO J = 1− 0a nd 3−2 transitions.

The end of star formation in Chamaeleon I ? A LABOCA census of starless and protostellar cores

Chamaeleon I is the most active region in terms of star formation in the Chamaeleon molecular cloud complex. Its population of prestellar and protostellar cores is not known and a controversy exists concerning its history of star formation. Our goal is to characterize the earliest stages of star formation in this cloud. We used the bolometer array LABOCA at APEX to map the cloud in dust continuum emission at 870 micron. The detected sources are analysed by carefully taking into account the spatial filtering inherent in the data reduction process. A search for associations with YSOs is performed using Spitzer data and the SIMBAD database. Most of the detected 870 micron emission is distributed in 5 filaments. We identify 59 starless cores, one candidate first hydrostatic core, and 21 sources associated with more evolved YSOs. The starless cores are only found above a visual extinction threshold of 5 mag. They are less dense than those detected in other nearby molecular clouds by a factor of a few on average. The core mass distribution is consistent with the IMF at the high-mass end but is overpopulated at the low-mass end. In addition, at most 17% of the cores have a mass larger than the critical Bonnor-Ebert mass. Both results suggest that a large fraction of the starless cores may not be prestellar. Based on the census of prestellar cores, Class 0 protostars, and more evolved YSOs, we conclude that the star formation rate has decreased with time in this cloud. The low fraction of candidate prestellar cores among the population of starless cores, the small number of Class 0 protostars, the high global star formation efficiency, the decrease of the star formation rate with time, and the low mass per unit length of the detected filaments all suggest that we may be witnessing the end of the star formation process in Cha I {abridged}.

First results from the CALYPSO IRAM-PdBI survey - II. Resolving the hot corino in the Class 0 protostar NGC 1333-IRAS2A

We investigate the origin of complex organic molecules (COMs) in the gas phase around the low-mass Class~0 protostar NGC1333-IRAS2A, to determine if the COM emission lines trace an embedded disk, shocks from the protostellar jet, or the warm inner parts of the protostellar envelope. In the framework of the CALYPSO (Continuum And Lines in Young ProtoStellar Objects) IRAM Plateau de Bure survey, we obtained large bandwidth spectra at sub-arcsecond resolution towards NGC 1333-IRAS2A. We identify the emission lines towards the central protostar and perform Gaussian fits to constrain the size of the emitting region for each of these lines, tracing various physical conditions and scales. The emission of numerous COMs such as methanol, ethylene glycol, and methyl formate is spatially resolved by our observations. This allows us to measure, for the first time, the size of the COM emission inside the protostellar envelope, finding that it originates from a region of radius 40-100 AU, centered on the NGC 1333-IRAS2A protostellar object. Our analysis shows no preferential elongation of the COM emission along the jet axis, and therefore does not support the hypothesis that COM emission arises from shocked envelope material at the base of the jet. Down to similar sizes, the dust continuum emission is well reproduced with a single envelope model, and therefore does not favor the hypothesis that COM emission arises from the thermal sublimation of grains embedded in a circumstellar disk. Finally, the typical scale

Observations of warm molecular gas and kinematics in the disc around HD 100546

\sim

Volatile-carbon locking and release in protoplanetary disks - A study of TW Hya and HD 100546

60 AU observed for COM emission is consistent with the size of the inner envelope where

APECS - The Atacama Pathfinder Experiment Control System

T_{\rm{dust}} > 100