A. Bollati

High-precision 87Sr/86Sr analyses in wines and their use as a geological fingerprint for tracing geographic provenance.

The radiogenic isotopic compositions of inorganic heavy elements such as Sr, Nd, and Pb of the food chain may constitute a reliable geographic fingerprint, their isotopic ratios being inherited by the geological substratum of the territory of production. The Sr isotope composition of geomaterials (i.e., rocks and soils) is largely variable, and it depends upon the age of the rocks and their nature (e.g., genesis, composition). In this study we developed a high-precision analytical procedure for determining Sr isotopes in wines at comparable uncertainty levels of geological data. With the aim of verifying the possibility of using Sr isotope in wine as a reliable tracer for geographic provenance, we performed Sr isotope analyses of 45 bottled wines from four different geographical localities of the Italian peninsula. Their Sr isotope composition has been compared with that of rocks from the substrata (i.e., rocks) of their vineyards. In addition wines from the same winemaker but different vintage years have been analyzed to verify the constancy with time of the (87)Sr/(86)Sr. Sr isotope compositions have been determined by solid source thermal ionization mass spectrometry following purification of Sr in a clean laboratory. (87)Sr/(86)Sr of the analyzed wines is correlated with the isotopic values of the geological substratum of the vineyards, showing little or no variation within the same vineyard and among different vintages. Large (87)Sr/(86)Sr variation is observed among wines from the different geographical areas, reinforcing the link with the geological substratum of the production territory. This makes Sr isotopes a robust geochemical tool for tracing the geographic authenticity and provenance of wine.

Inheritance of Jurassic rifted margin architecture into the Apennines Neogene mountain building: a case history from the Lucretili Mts. (Latium, Central Italy)

The western Lucretili Mts. in the central Apennines (Latium, Italy) have been recently re-mapped in great detail and are the subject of combined stratigraphic, sedimentological and structural investigations. In this paper, we present a new stratigraphic interpretation of the Jurassic paleogeography of western Lucretili Mts., where a rift-derived intrabasinal paleo-high of the Alpine Tethys has been identified for the first time by means of facies analysis and biostratigraphic dating. Recognised facies associations, combined with dated stratigraphic sections, allow to define the morphology of the structural paleo-high and to identify the associated gravity-driven deposits (olistoliths) accumulated in the surrounding basin. Furthermore, we investigated the modes of interaction between Jurassic extensional structures and the subsequent contractional patterns developed during the Tertiary mountain building. In detail, the role played during Apennines tectonics by the paleo-escarpments bounding the paleo-high and by the surrounding olistoliths has been analysed. The paleo-escarpments either acted as focussing features for ENE-directed frontal thrust ramp localisation and were offset with small shortening amounts or reactivated as NNE striking high angle transpressional faults or preserved the original geometries as a result of variable orientation of paleo-escarpments with respect to the Neogene compressive stress field (with ENE oriented sigma1). Newly formed ENE striking tear faults connect these either inherited or neo-formed discontinuities. This complex stratigraphic and structural pattern is substantially different from the previous interpretations of this portion of the central Apennines based on a hypothesised layer-cake stratigraphy deformed by neo-formed Neogene thrusts. This contribution strengthens the importance of integrating facies analyses and structural investigations to detect the influence of pre-orogenic structures on compressive structural patterns, in an area where commercial seismic lines are not available and cannot help in reconstructing the subsurface geometries.

An integrated methodology of viticultural zoning to evaluate terrains suitable for viticulture: the test area of Cesanese DOC (Latium, central Italy)

The increase in the world wine market has required continued improvements in viticultural zoning in both old and young production regions. The many proposed zoning methods vary according to the study area in which they are applied as well as to the perspective of the authors. Thus, there is little agreement on which factors (climate, landscape, geology, soil and human intervention) should be taken into account. The aim of this work is to provide a methodology to optimize and possibly increase the development of wine production regions, identifying the zones with different potential suitability. We coupled the computation of bioclimatic indices based on Géoviticulture Multicriteria Climatic Classification System with a GIS (geographic information system) analysis based on the integration of easily accessible geological, morphometric and geomorphological data, in addition to viticulture land use. The final result of this methodology is a suitability map distinguishing sectors of different suitability for wine production in a vine cropping area. We tested the methodology on the Cesanese DOC (Denomination of Origin Verified) zone (Latium, central Italy). The resulting suitability map indicates that the areas more favourable for viticulture are only partially exploited, encouraging the possibility of increasing the production of high-quality wine in the Cesanese DOC area. This result underlines the applicability of our methodology in land-use planning and management.

Schema strutturale della catena a pieghe e sovrascorrimenti Umbro-Sabina (Italia Centrale) derivato dal rilevamento dei fogli 366 “Palombara Sabina” e 375 “Tivoli” (Progetto CARG)

Structural Scheme of the Umbria-Sabina fold-and-thrust belt (Central Italy) derived from the geological mapping of 366 Palombara Sabina and 375 Tivoli sheets (CARG Project).The geological mapping of the sheets 366 Palombara Sabina and 375 Tivoli (1: 50.000 scale; CARG Project; in preparation) allowed the revision of the structural setting of the westernmost portion of this part of the Neogene fold-and-thrust belt of the Central Apennines.The area comprises the Cornicolani, Lucretili, eastern Sabini, Tiburtini, Ruffi and Prenestini Mts (Latium region). Most of the area (Cornicolani, Lucretili and Tiburtini Mts) is made of the pre-orogenic deposits (Upper Triassic-Serravallian) referred to the calcareous-marly-siliceous Sabina Succession, that were accumulated in the southern part of the Umbria-Marche-Sabina Pelagic Basin (Sabina Domain), proximal to the Latium-Abruzzi Carbonate Platform. In general, in the eastern areas, more proximal to the platform, coarser lithofacies crop out. Moreover, in the Cornicolani and western Lucretili Mts (Castelvecchio Mt) areally restricted outcrops of condensed pelagic carbonates (Bugarone Group and calcari dolomitici di S. Angelo Romano) document the occurrence of Jurassic intrabasinal structural highs evolved into Pelagic Carbonate Platforms. These structural highs were generated after the Early Jurassic rifting, that broke-up the pre-existing carbonate platform (Calcare Massiccio).In the mapped area, the Latium - Abruzzi Platform is represented in the hangingwall of the Olevano-Antrodoco line only in the southern Prenestini Mts (Rocca di Cave), by upper Cretaceous shelf carbonates. Whereas in the footwall of the Olevano-Antrodoco line it crops out along the Aniene River valley. Both Sabina and Latium - Abruzzi successions are overlain by upper Tortonian - lower Messinian marls and siliciclastic syn-orogenic deposits, best observed in the easternmost areas and inbetween the Ruffi and Prenestini Mts.In their turn, the syn-orogenic deposits are unconformably overlain by post-orogenic Plio-Pleistocene marine clastic deposits and Quaternary volcanic and alluvial sediments. From a structural point of view, the Sabina Domain is arranged into several thrust sheets verging toward the east, developed in middle-late Miocene-early Pliocene times. The early Pliocene Olevano-Antrodoco out-of-sequence thrust marks the eastern tectonic boundary of this structural domain where the pelagic and slope sediments overthrust the Latium - Abruzzi Carbonate Platform and its associated syn-orogenic deposits. In late Miocene-early Pliocene extensional tectonics down-threw the western border of this imbricated structure enhancing the marine ingression along the peri-Tyrrhenian margin. The western border of the region was also reactivated by N-S right-lateral strike-slip fault dissecting the earlier structures in Pleistocene times.From top of the orogenic edifice three main tectonic units have been identified:- Unit 1 (Morra Mt) made up of Upper Triassic to Lower Jurassic dolomite limestones (Dolomia Principale) and Calcare Massiccio, overthrust onto unit 2.- Unit 2 (comprising Cornicolani Mts, western Lucretili Mts) made up of Dolomia Principale, Calcare Massiccio, Corniola detritica and, in the Cornicolani and western Lucretili Mts, Bugarone Group. Long wavelength upright folds mainly characterize this unit and faults with high angle cuts-offs prevail, and Jurassic structural highs occur (Cornicolani Mts, Castelvecchio Mt).- Unit 3 (comprising Elci Mt, eastern Lucretili Mts and Tiburtini Mts) made up of most of the Sabina basin stratigraphic succession - from Corniola detritica Fm. to the Guadagnolo Member (marly lithofacies); the unit is characterized by NW to NE verging overturned to recumbent folds.- Unit 4 (comprising Prenestini Mts, Ruffi Mts and eastern Sabini Mts) made up of the upper portion of the basin succession between the Marne a Fucoidi and Upper Miocene siliciclastics and the Rocca di Cave carbonate platform succession.This unit is made up by two sub-units, based on the deformation-style and stratigraphy: the sub-unit 4A (Granaro Mt, Colle Serviano and Arzillo Mt in the western Prenestini Mts), is mainly characterized by east-verging packed asymmetrical folds with sub-vertical axial-planes, and N-S striking dextral-transpressive faults. The sub-unit 4B (Castel Madama area, eastern and central Prenestini Mts, Ruffi Mts and eastern Sabini Mts) is characterized by a wide symmetrical anticline in the western portion, and by folds with very steep axial planes, and N-S to NNW-striking dextral transpressional faults.The units are separated by low-angle thrusts or by high-angle transpressive faults: the stratigraphic successions characterizing each unit rejuvenate eastward. The innermost unit 1 and unit 2, where massive or poorly stratified deposits are exposed, are mainly deformed by high angle faults. Whereas the more external unit 3 and unit 4 are composed by alternating carbonate, marls and siliciclastics, and are mostly characterized by east-verging slightly to strongly asymmetrical and overturned folds.A new geometric and kinematic scenario for the Neogene evolution of the units preserved in the hangingwall of the Olevano-Antrodoco thrust is here outlined.The revision of the stratigraphy and structural data put in evidence the presence of paleo-structures of the Tethyan passive margin not evidenced in the past cartography, their influence on Neogene compressive structures and the coexistence of non-coaxial structural trends in areas of limited extension.