A. Burl Donaldson

Some Perspectives on Alcohol Utilization in a Compression Ignition Engine

This paper addresses some of the practical problems encountered in attempts to use the simple alcohols as alternate fuels in compression ignition (Cl) engines for transportation. It is comprised of six sections: 1) the motivations for pursuit of the alcohols for transportation, 2) a brief review of several municipal buses trials in North American cities, 3) relevant literature which is cited to support a hypothesis, 4) the presentation of a hypothesis and solution, 5) some engine performance data to address an issue attendant to the proposed solution, and 6) conclusion. The solution proposes auto ignition of the fuel via intake air heating as a means to overcome the part load engine efficiency problems. However, in implementing this strategy for a direct injection engine, elevated noise has been observed for alcohol operation. This was concluded to be due to a very rapid pressure rise on ignition attendant to air preheating and the high compression ratio of this engine. A different engine with prechamber and glow plug was tested; the purpose was to determine if a continuously operating glow plug would encourage prompt ignition of the alcohol during injection and reduce the observed noise problem. The conclusion reached was that the prechamber itself appears to have solved the noise problem without an energized glow plug.

Thermocouple Response in Fires, Part 1: Considerations in Flame Temperature Measurements by a Thermocouple

This PIRT exercise identifies a number of factors which can influence thermocouple readings made in fires. Identified factors are: (a) the fuel/oxidizer equivalence ratio and its effect on readings, (b) the influence of the state of oxidation and variation with time for the thermocouple sheath, (c) the convection coefficient models and how experimental readings are influenced by thermocouple diameter and yaw angle, (d) response time of a MIMS thermocouple, and (e) thermocouple end effects.

Problems Encountered in Fluctuating Flame Temperature Measurements by Thermocouple

Some thermocouple experiments were carried out in order to obtain sensitivity of thermocouple readings to fluctuations in flames and to determine if the average thermocouple reading was representative of the local volume temperature for fluctuating flames. The thermocouples considered were an exposed junction thermocouple and a fully sheathed thermocouple with comparable time constants. Either the voltage signal or indicated temperature for each test was recorded at sampling rates between 300-4,096 Hz. The trace was then plotted with respect to time or sample number so that time variation in voltage or temperature could be visualized and the average indicated temperature could be determined. For experiments where high sampling rates were used, the signal was analyzed using Fast Fourier Transforms (FFT) to determine the frequencies present in the thermocouple signal. This provided a basic observable as to whether or not the probe was able to follow flame oscillations. To enhance oscillations, for some experiments, the flame was forced. An analysis based on thermocouple time constant, coupled with the transfer function for a sinusoidal input was tested against the experimental results.

Modeling of Chemical Processes in a Diesel Engine With Alcohol Fuels

Methanol utilization in a compression ignition engine has held tentative promise for a number of years, and, in fact, the concept has seen large scale field trials intended to demonstrate this option as a precursor to commercial implementation. However, results from those tests have identified some of the practical problems encountered with this fuel, namely, (1) its difficulty of vaporization and (2) its high autoignition temperature. Luminosity promoting additives, which facilitate radiative transport as a component of flame spread (because pure alcohol burns with little luminosity, continuum radiation as a reaction transport mechanism is essentially absent), intake air heating, active and passive heat sources, etc., represent some of the attempts to overcome limitations of these two factors. Except for intake air preheat, these augmentation methods have been noted to result in poor off-load thermal cycle efficiency. Focusing on the case of intake air preheat (which can be achieved by elevated compression ratio), and to model the chemical reaction kinetics, the partially stirred reactor model in CHEMKIN was used. This approach provided examination of the chemistry and reaction rates associated with an actual trial in which methanol was the fuel under study. To initiate this simulation, literature available reaction mechanisms were obtained, and then the experimental cylinder pressure history was matched by control of heat release rate via the partially stirred reactor model. This is represented within the reactor model by changing the turbulent mixing intensity factor. The overall reaction sequence, which models cylinder pressure, and attendant extent of reaction were the major focus. The minor focus included production of emission gases, e.g., the aldehydes and unburned fuel. Not only are the model results consistent with actual findings, they also support a method for addressing causes of off-load inefficiency and engine failures due to engine oil dilution with fuel.

A joint computational and experimental study to evaluate Inconel-sheathed thermocouple performance in flames.

A joint experimental and computational study was performed to evaluate the capability of the Sandia Fire Code VULCAN to predict thermocouple response temperature. Thermocouple temperatures recorded by an Inconel-sheathed thermocouple inserted into a near-adiabatic flat flame were predicted by companion VULCAN simulations. The predicted thermocouple temperatures were within 6% of the measured values, with the error primarily attributable to uncertainty in Inconel 600 emissivity and axial conduction losses along the length of the thermocouple assembly. Hence, it is recommended that future thermocouple models (for Inconel-sheathed designs) include a correction for axial conduction. Given the remarkable agreement between experiment and simulation, it is recommended that the analysis be repeated for thermocouples in flames with pollutants such as soot.

Thermocouple Response in Fires, Part 2: Validation of Virtual Thermocouple Model for Fire Codes

A virtual thermocouple model for high fidelity multiphysics computer simulation is introduced in this article. Detailed thermocouple and gas temperature (Coherent Anti-Stokes Raman Scattering) measurements were performed using a well-controlled, adiabatic, flat-flame Hencken burner, which provided data for validating the thermocouple model in a Sandia National Laboratories fire code. Comparison of simulation results to test data indicated a mean error of 6% between the thermocouple reading and predicted temperature.

Computational Fluid Dynamics and Particle Image Velocimetry Supported Examination of Bidirectional Velocity Probes for Measurements in Flames

The bidirectional velocity probe has been used in various flames to measure local velocity. The device is based on the pressure difference between a closed forward facing cavity and a closed rearward facing cavity. The probes have been noted to indicate a pressure difference greater than that which would be predicted based on Bernoullis equation. Each device must be experimentally calibrated in a wind tunnel at similar Reynolds number to determine its “amplification factor.” This study uses PIV, flow visualization and CFD to examine the flow field around the probe, as well as an experimental study which compares various probe configurations for measurement of velocity by pressure differential. The conclusion is that the amplification factor is indeed greater than unity but use of the wind tunnel for calibration is questionable.

Effect of oxide layer formation on deformation of aluminum alloys under fire conditions

The purpose of this paper is to investigate the structural behavior of aluminum alloys used in the aerospace industry when exposed to conditions similar to those of an accident scenario, such as a fuel fire. This study focuses on the role that the aluminum oxide layer plays in the deformation and the strength of the alloy above melting temperature. To replicate some of the thermal and atmospheric conditions that the alloys might experience in an accident scenario, aluminum rod specimens were subjected to temperatures near to or above their melting temperature in air, nitrogen, and vacuum environments. The characteristics of their deformation, such as geometry and rate of deformation, were observed. Tests were conducted by suspending aluminum rods vertically from an enclosure. This type of experiment was performed in two different environments: air and nitrogen. The change in environments allowed the effects of the oxide layer on the material strength to be analyzed by inhibiting the growth of the oxide layer. Observations were reported from imaging taken during the experiment showing creep behavior of aluminum alloys at elevated temperatures and time to failure. In addition, an example of tensile load–displacement data obtained in air and vacuum was reported to understand the effect of oxide layer on aluminum deformation and strength.

Evaluation of a new device for simultaneous measurement of heat flux and gas velocity in a diffusion flame

This article examines potential use of a new device called multi-directional heat flux and velocity probe for simultaneous measurement of heat flux and flame speed in a diffusion flame. The probe consists of a thin-wall spherical shell with internal insulation to mitigate internal convection. Both pressure and temperature distributions around the sphere are used to indicate local velocity and heat flux. The multi-directional heat flux and velocity probe appears to be a more promising device than the bidirectional velocity probe in the sense that the sphere is a regular geometry with minimum flow separation and should lead to more predictable behavior. However, an outcome of this study is that the device must be used in conjunction with a fire code computational fluid dynamics model because the boundary layer is not isothermal so that the conventional pressure coefficient for a sphere leads to erroneous results.

INVESTIGATION OF MOLTEN/OXIDIZED ALUMINUM POWDER DEPOSITION ON STAINLESS STEEL 304.

Accidents involving solid propellants containing aluminum can be difficult to model due to the additional heat transfer from molten aluminum or aluminum combustion and impingement/deposition of oxide on target objects. A series of tests has been carried out using a commercially available oxy-acetylene torch and powder feeder to investigate the effects of molten/oxidized aluminum on stainless steel 304 substrates. SEM and EDS have been used to determine diffusion/interaction of aluminum with the stainless steel and characterize the constituents of the resulting interfacial layers. These techniques indicated that at the test conditions, aluminum was undetectably oxidized before it deposited on the substrate surface. However, temperature data from thermocouples attached to backside of each substrate detected an increased heat flux to the substrate when aluminum is introduced into the flame spray. Results also indicate that the boundary layers of the aluminum and stainless steel were well defined implying that little diffusion or solution of the aluminum with the stainless steel occurred.Copyright