A. C. A. Boogert

From Molecular Cores to Planet‐forming Disks: An SIRTF Legacy Program

Crucial steps in the formation of stars and planets can be studied only at mid‐ to far‐infrared wavelengths, where the Space Infrared Telescope (SIRTF) provides an unprecedented improvement in sensitivity. We will use all three SIRTF instruments (Infrared Array Camera [IRAC], Multiband Imaging Photometer for SIRTF [MIPS], and Infrared Spectrograph [IRS]) to observe sources that span the evolutionary sequence from molecular cores to protoplanetary disks, encompassing a wide range of cloud masses, stellar masses, and star‐forming environments. In addition to targeting about 150 known compact cores, we will survey with IRAC and MIPS (3.6–70 μm) the entire areas of five of the nearest large molecular clouds for new candidate protostars and substellar objects as faint as 0.001 solar luminosities. We will also observe with IRAC and MIPS about 190 systems likely to be in the early stages of planetary system formation (ages up to about 10 Myr), probing the evolution of the circumstellar dust, the raw material for planetary cores. Candidate planet‐forming disks as small as 0.1 lunar masses will be detectable. Spectroscopy with IRS of new objects found in the surveys and of a select group of known objects will add vital information on the changing chemical and physical conditions in the disks and envelopes. The resulting data products will include catalogs of thousands of previously unknown sources, multiwavelength maps of about 20 deg^2 of molecular clouds, photometry of about 190 known young stars, spectra of at least 170 sources, ancillary data from ground‐based telescopes, and new tools for analysis and modeling. These products will constitute the foundations for many follow‐up studies with ground‐based telescopes, as well as with SIRTF itself and other space missions such as SIM, JWST, Herschel, and TPF/Darwin.

The Spitzer Ice Legacy: Ice Evolution from Cores to Protostars

Ices regulate much of the chemistry during star formation and account for up to 80% of the available oxygen and carbon. In this paper, we use the Spitzer c2d Legacy ice survey, complimented with data sets on ices in cloud cores and high-mass protostars, to determine standard ice abundances and to present a coherent picture of the evolution of ices during low- and high-mass star formation. The median ice composition H_(2)O:CO:CO_2:CH_(3)OH:NH_3:CH_4:XCN is 100:29:29:3:5:5:0.3 and 100:13:13:4:5:2:0.6 toward low- and high-mass protostars, respectively, and 100:31:38:4:-:-:- in cloud cores. In the low-mass sample, the ice abundances with respect to H_(2)O of CH_4, NH_3, and the component of CO_2 mixed with H_(2)O typically vary by <25%, indicative of co-formation with H_(2)O. In contrast, some CO and CO_2 ice components, XCN, and CH3OH vary by factors 2-10 between the lower and upper quartile. The XCN band correlates with CO, consistent with its OCN– identification. The origin(s) of the different levels of ice abundance variations are constrained by comparing ice inventories toward different types of protostars and background stars, through ice mapping, analysis of cloud-to-cloud variations, and ice (anti-)correlations. Based on the analysis, the first ice formation phase is driven by hydrogenation of atoms, which results in an H_(2)O-dominated ice. At later prestellar times, CO freezes out and variations in CO freezeout levels and the subsequent CO-based chemistry can explain most of the observed ice abundance variations. The last important ice evolution stage is thermal and UV processing around protostars, resulting in CO desorption, ice segregation, and the formation of complex organic molecules. The distribution of cometary ice abundances is consistent with the idea that most cometary ices have a protostellar origin.

The composition and distribution of dust along the line of sight toward the Galactic center

We discuss the composition of dust and ice along the line of sight to the Galactic center (GC) based on analysis of mid-infrared spectra (2.4-13 μm) from the Short Wavelength Spectrometer on the Infrared Space Observatory (ISO). We have analyzed dust absorption features arising in the molecular cloud material and the diffuse interstellar medium along the lines of sight toward Sgr A* and the Quintuplet sources, GCS 3 and GCS 4. It is evident from the depth of the 3.0 μm H2O and the 4.27 μm CO2 ice features that there is more molecular cloud material along the line of sight toward Sgr A* than toward GCS 3 and GCS 4. In fact, Sgr A* has a rich infrared ice spectrum with evidence for the presence of solid CH4, NH3, and possibly HCOOH. Hydrocarbon dust in the diffuse interstellar medium along the line of sight to the GC is characterized by absorption features centered at 3.4, 6.85, and 7.25 μm. Ground-based studies have identified the 3.4 μm feature with aliphatic hydrocarbons, and ISO has given us the first meaningful observations of the corresponding modes at longer wavelengths. The integrated strengths of these three features suggest that hydrogenated amorphous carbon is their carrier. We attribute an absorption feature centered at 3.28 μm in the GCS 3 spectrum to the C–H stretch in aromatic hydrocarbons. This feature is not detected, and its C–C stretch counterpart appears to be weaker, in the Sgr A* spectrum. A key question now is whether or not aromatics are a widespread component of the diffuse interstellar medium, analogous to aliphatic hydrocarbons.

c2d Spitzer IRS Spectra of Disks around T Tauri Stars. I. Silicate Emission and Grain Growth

Infrared ~5-35 μm spectra for 40 solar mass T Tauri stars and 7 intermediate-mass Herbig Ae stars with circumstellar disks were obtained using the Spitzer Space Telescope as part of the c2d IRS survey. This work complements prior spectroscopic studies of silicate infrared emission from disks, which were focused on intermediate-mass stars, with observations of solar mass stars limited primarily to the 10 μm region. The observed 10 and 20 μm silicate feature strengths/shapes are consistent with source-to-source variations in grain size. A large fraction of the features are weak and flat, consistent with micron-sized grains indicating fast grain growth (from 0.1 to 1.0 μm in radius). In addition, approximately half of the T Tauri star spectra show crystalline silicate features near 28 and 33 μm, indicating significant processing when compared to interstellar grains. A few sources show large 10-to-20 μm ratios and require even larger grains emitting at 20 μm than at 10 μm. This size difference may arise from the difference in the depth into the disk probed by the two silicate emission bands in disks where dust settling has occurred. The 10 μm feature strength versus shape trend is not correlated with age or Hα equivalent width, suggesting that some amount of turbulent mixing and regeneration of small grains is occurring. The strength versus shape trend is related to spectral type, however, with M stars showing significantly flatter 10 μm features (larger grain sizes) than A/B stars. The connection between spectral type and grain size is interpreted in terms of the variation in the silicate emission radius as a function of stellar luminosity, but could also be indicative of other spectral-type-dependent factors (e.g., X-rays, UV radiation, and stellar/disk winds).

In-orbit performance of Herschel-HIFI

Aims. In this paper the calibration and in-orbit performance of the Heterodyne Instrument for the Far-Infrared (HIFI) is described. Methods. The calibration of HIFI is based on a combination of ground and in-flight tests. Dedicated ground tests to determine those instrument parameters that can only be measured accurately using controlled laboratory stimuli were carried out in the instrument level test (ILT) campaign. Special in-flight tests during the commissioning phase (CoP) and performance verification (PV) allowed the determination of the remaining instrument parameters. The various instrument observing modes, as specified in astronomical observation templates (AOTs), were validated in parallel during PV by observing selected celestial sources. Results. The initial calibration and in-orbit performance of HIFI has been established. A first estimate of the calibration budget is given. The overall in-flight instrument performance agrees with the original specification. Issues remain at only a few frequencies.

Observations of the Icy Universe

Freeze-out of the gas-phase elements onto cold grains in dense interstellar and circumstellar media builds up ice mantles consisting of molecules that are mostly formed in situ (H2O, NH3, CO2, CO, CH3OH, and more). This review summarizes the detected infrared spectroscopic ice features and compares the abundances across Galactic, extragalactic, and Solar System environments. A tremendous amount of information is contained in the ice band profiles. Laboratory experiments play a critical role in the analysis of the observations. Strong evidence is found for distinct ice formation stages, separated by CO freeze-out at high densities. The ice bands have proven to be excellent probes of the thermal history of their environment. The evidence for the long-held idea that processing of ices by energetic photons and cosmic rays produces complex molecules is weak. Recent state-of-the-art observations show promise for much progress in this area with planned infrared facilities.

C2D Spitzer-IRS spectra of disks around T Tauri stars - IV. Crystalline silicates

Aims. Dust grains in the planet-forming regions around young stars are expected to be heavily processed due to coagulation, fragmentation, and crystallization. This paper focuses on the crystalline silicate dust grains in protoplanetary disks for a statistically significant number of TTauri stars (96). Methods. As part of the cores to disks (c2d) legacy program, we obtained more than a hundred Spitzer/IRS spectra of TTauri stars, over a spectral range of 5-35 μm where many silicate amorphous and crystalline solid-state features are present. At these wavelengths, observations probe the upper layers of accretion disks up to distances of a dozen AU from the central object. Results. More than 3/4 of our objects show at least one crystalline silicate emission feature that can be essentially attributed to Mg-rich silicates. The Fe-rich crystalline silicates are largely absent in the c2d IRS spectra. The strength and detection frequency of the crystalline features seen at λ > 20 μm correlate with each other, while they are largely uncorrelated with the observational properties of the amorphous silicate 10 μm feature. This supports the idea that the IRS spectra essentially probe two independent disk regions: a warm zone (≤1 AU) emitting at ~ 10 μm and a much colder region emitting at λ > 20 μm (≤10 AU). We identify a crystallinity paradox, as the long-wavelength (λ > 20 m) crystalline silicate features are detected 3.5 times more frequently (~55% vs. ~15%) than the crystalline features arising from much warmer disk regions (λ ~ 10 μm). This suggests that the disk has an inhomogeneous dust composition within ~10 AU. The analysis of the shape and strength of both the amorphous 10 μm feature and the crystalline feature around 23 μm provides evidence for the prevalence of μm-sized (amorphous and crystalline) grains in upper layers of disks. Conclusions. The abundant crystalline silicates found far from their presumed formation regions suggest efficient outward radial transport mechanisms in the disks around TTauri stars. The presence of μm-sized grains in disk atmospheres, despite the short timescales for settling to the midplane, suggests efficient (turbulent) vertical diffusion, probably accompanied by grain-grain fragmentation to balance the expected efficient growth. In this scenario, the depletion of submicron-sized grains in the upper layers of the disks points toward removal mechanisms such as stellar winds or radiation pressure.

C2D Spitzer-IRS spectra of disks around T Tauri stars. II. PAH emission features

Aims. We search for Polycyclic Aromatic Hydrocarbon (PAH) features towards young low-mass (T Tauri) stars and compare them with surveys of intermediate mass (Herbig Ae/Be) stars. The presence and strength of the PAH features are interpreted with disk radiative transfer models exploring the PAH feature dependence on the incident UV radiation, PAH abundance and disk parameters. Methods. Spitzer Space Telescope 5-35 mu m spectra of 54 pre-main sequence stars with disks were obtained, consisting of 38 T Tauri, 7 Herbig Ae/Be and 9 stars with unknown spectral type. Results. Compact PAH emission is detected towards at least 8 sources of which 5 are Herbig Ae/Be stars. The 11.2 mu m PAH feature is detected in all of these sources, as is the 6.2 mu m PAH feature for the 4 sources for which short wavelength data are available. However, the 7.7 and 8.6 mu m features appear strongly in only 1 of these 4 sources. Based on the 11.2 mu m feature, PAH emission is observed towards at least 3 T Tauri stars, with 14 tentative detections, resulting in a lower limit to the PAH detection rate of 8%. The lowest mass source with PAH emission in our sample is T Cha with a spectral type G8. All 4 sources in our sample with evidence for dust holes in their inner disk show PAH emission, increasing the feature/continuum ratio. Typical 11.2 mu m line intensities are an order of magnitude lower than those observed for the more massive Herbig Ae/Be stars. Measured line fluxes indicate PAH abundances that are factors of 10-100 lower than standard interstellar values. Conversely, PAH features from disks exposed to stars with T(eff)

THE c2d SPITZER SPECTROSCOPIC SURVEY OF ICES AROUND LOW-MASS YOUNG STELLAR OBJECTS. IV. NH3 AND CH3OH

NH_3 and CH_3OH are key molecules in astrochemical networks leading to the formation of more complex N- and O-bearing molecules, such as CH3CN and CH3OCH3. Despite a number of recent studies, little is known about their abundances in the solid state. This is particularly the case for low-mass protostars, for which only the launch of the Spitzer Space Telescope has permitted high-sensitivity observations of the ices around these objects. In this work, we investigate the ~8–10μm region in the Spitzer IRS (InfraRed Spectrograph) spectra of 41 low-mass young stellar objects (YSOs). These data are part of a survey of interstellar ices in a sample of low-mass YSOs studied in earlier papers in this series. We used both an empirical and a local continuum method to correct for the contribution from the 10μm silicate absorption in the recorded spectra. In addition, we conducted a systematic laboratory study of NH_(3-) and CH_3OH-containing ices to help interpret the astronomical spectra. We clearly detect a feature at ~9μm in 24 low-mass YSOs. Within the uncertainty in continuum determination, we identify this feature with the NH_3 ν_2 umbrella mode and derive abundances with respect to water between ~2% and 15%. Simultaneously, we also revisited the case of CH_3OH ice by studying the ν_4 C–O stretch mode of this molecule at ~9.7μm in 16 objects, yielding abundances consistent with those derived by Boogert et al. based on a simultaneous 9.75 and 3.53μm data analysis. Our study indicates that NH_3 is present primarily in H_2O-rich ices, but that in some cases, such ices are insufficient to explain the observed narrow FWHM. The laboratory data point to CH_3OH being in an almost pure methanol ice, or mixed mainly with CO or CO_2, consistent with its formation through hydrogenation on grains. Finally, we use our derived NH_3 abundances in combination with previously published abundances of other solid N-bearing species to find that up to 10%–20% of nitrogen is locked up in known ices.

Processing of icy mantles in protostellar envelopes.

We have obtained CO absorption profiles of several young stellar objects (YSOs), spanning a range of mass and luminosity, in order to investigate their ice mantle composition. We present the first detection of CO toward the class I YSO L1489 IRS in the Taurus dark cloud. In general, the CO profiles for YSOs show evidence for both processed and pristine ices in the same line of sight, strong indirect evidence for CO, is suggested in R CrA IRS 7, L1489 IRS, Elias 18, and GL 961E. Toward other sources (R CrA IRS 1, IRS 2, W33A, NGC 7538 IRS 9, Mon R2 IRS 2) CO is present in (nearly) pure form. We propose an evolutionary scenario to explain the chemical diversity of the icy mantles toward these objects.