A. Castets

The hot core around the low-mass protostar IRAS 16293-2422 : Scoundrels rule!

While warm dense gas is prevalent around low-mass protostars, the presence of complex saturated molecules—the chemical inventory characteristic of hot cores—has remained elusive in such environments. Here we report the results of an IRAM 30 m study of the molecular composition associated with the low-mass protostar IRAS 16293-2422. Our observations highlight an extremely rich organic inventory in this source with abundant amounts of complex O- and N-bearing molecules such as formic acid, HCOOH, acetaldehyde, CH3CHO, methyl formate, CH3OCHO, dimethyl ether, CH3OCH3, acetic acid, CH3COOH, methyl cyanide, CH3CN, ethyl cyanide, C2H5CN, and propyne, CH3CCH. We compare the composition of the hot core around this low-mass young stellar object with those around massive protostars and address the chemical processes involved in molecular complexity in regions of star formation.

First detection of triply-deuterated methanol

We report the first detection of triply-deuterated methanol, with 12 observed transitions, towards the low-mass protostar IRAS 16293−2422, as well as multifrequency observations of 13 CH3OH, used to derive the column density of the main isotopomer CH3OH. The derived fractionation ratio (CD3OH)/(CH3OH) averaged on a 10 �� beam is 1.4%. Together with previous CH2DOH and CHD2OH observations, the present CD3OH observations are consistent with a formation of methanol on grain surfaces, if the atomic D/H ratio is 0.1 to 0.3 in the accreting gas. Such a high atomic ratio can be reached in the framework of gas-phase chemical models including all deuterated isotopomers of H + .

Complex Molecules in the Hot Core of the Low-Mass Protostar NGC 1333 IRAS 4A

We report the detection of complex molecules (HCOOCH3, HCOOH, and CH3CN), signposts of a hot core-like region, toward the low-mass Class 0 source NGC 1333 IRAS 4A. This is the second low-mass protostar in which such complex molecules have been searched for and reported, the other source being IRAS 16293-2422. It is therefore likely that compact (a few tens of AU) regions of dense and warm gas, where the chemistry is dominated by the evaporation of grain mantles and where complex molecules are found, are common in low-mass Class 0 sources. Given that the chemical formation timescale is much shorter than the gas hot-core crossing time, it is not clear whether the reported complex molecules are formed on the grain surfaces (first-generation molecules) or in the warm gas by reactions involving the evaporated mantle constituents (second-generation molecules). We do not find evidence for large differences in the molecular abundances, normalized to the formaldehyde abundance, between the two solar-type protostars, suggesting perhaps a common origin.

Detection of doubly-deuterated methanol in the solar-type protostar IRAS 16293-2422

We report the first detection of doubly-deuterated methanol (CHD2OH), as well as firm detections of the two singly-deuterated isotopomers of methanol (CH2DOH and CH3OD), towards the solar-type protostar IRAS 16293 2422. From the present multifrequency observations, we derive the following abundance ratios: (CHD 2OH)=(CH3OH)= 0:2 0:1, (CH2DOH)=(CH3OH)= 0:9 0:3, (CH3OD)=(CH3OH)= 0:04 0:02. The total abundance of the deuterated forms of methanol is greater than that of its normal hydrogenated counterpart in the circumstellar material of IRAS 16293 2422, a circumstance not previously encountered. Formaldehyde, which is thought to be the chemical precursor of methanol, possesses a much lower fraction of deuterated isotopomers (20%) with respect to the main isotopic form in IRAS 16293 2422. The observed frac- tionation of methanol and formaldehyde provides a severe challenge to both gas-phase and grain-surface models of deuteration. Two examples of the latter model are roughly in agreement with our observations of CHD2OH and CH2DOH if the accreting gas has a large (0.2-0.3) atomic D/H ratio. However, no gas-phase model predicts such a high atomic D/H ratio, and hence some key ingredient seems to be missing.

The degree of CO depletion in pre-stellar cores ?

We present new results on CO depletion in a sample of nearby pre-stellar cores, based on observations of the millimeter C 17 O and C 18 O lines and the 1.3 mm dust emission with the IRAM 30 m telescope. In most cases, the distribution of CO is much flatter than that of the dust, whereas other tracers, like

CO Depletion and Deuterium Fractionation in Prestellar Cores

\rm N_2H^{+}

The H2CO abundance in the inner warm regions of low mass protostellar envelopes

, still probe the latter. In the centre of these objects, we estimate CO to be underabundant by a factor 4–15 depending on the cores. The CO underabundance is more pronounced in the central regions and appears to decrease with increasing distance from the core centre. This underabundance is most likely due to the freezing out of CO onto the dust grains in the cold, dense parts of the cores. We find evidence for an increase of the CO depletion degree with the core density.

Testing grain surface chemistry : a survey of deuterated formaldehyde and methanol in low-mass Class 0 protostars

We report the detection of D2CO in a sample of starless dense cores, in which we previously measured the degree of CO depletion. The deuterium fractionation is found to be extremely high, [D2CO]/[H2CO] ~ 1%-10%, similar to that reported in low-mass protostars. This provides convincing evidence that D2CO is formed in the cold prestellar cores and later desorbed when the gas warms up in protostars. We find that the cores with the highest CO depletions have also the largest [D2CO]/[H2CO] ratios, supporting the theoretical prediction that deuteration increases with increasing CO depletion.

Resetting chemical clocks of hot cores based on S-bearing molecules

We present a survey of the formaldehyde emission in a sample of eight Class 0 protostars obtained with the IRAM and JCMT telescopes. The data have been analyzed with three different methods with increasing level of sophistication. We first analyze the observed emission in the LTE approximation, and derive rotational temperatures between 11 and 40 K, and column densities between 1 and 20 x 10^13 cm^-2. Second, we use a LVG code and derive larger kinetic temperatures, between 30 and 90 K, consistent with subthermally populated levels and densities from 1 to 6 x 10^5 cm^-3. The column densities from the LVG modeling are within a factor of 10 with respect to those derived in the LTE approximation. Finally, we analyze the observations based upon detailed models for the envelopes surrounding the protostars, using temperature and density profiles previously derived from continuum observations. We approximate the formaldehyde abundance across the envelope with a jump function, the jump occurring when the dust temperature reaches 100 K, the evaporation temperature of the grain mantles. The observed formaldehyde emission is well reproduced only if there is a jump, more than two orders of magnitude, in four sources. In the remaining four sources the data are consistent with a formaldehyde abundance jump, but the evidence is more marginal (~2 sigma). The inferred inner H2CO abundance varies between 1 x 10^-8 and 6 x 10^-6. We discuss the implications of these jumps for our understanding of the origin and evolution of ices in low mass star forming regions. Finally, we give predictions for the submillimeter H2CO lines, which are particularly sensitive to the abundance jumps.

CH3OH abundance in low mass protostars

Context. Despite the low cosmic abundance of deuterium (D/H ∼ 10 −5 ), high degrees of deuterium fractionation in molecules are observed in star-forming regions with enhancements that can reach 13 orders of magnitude, a level that current models have difficulty accounting for. Aims. Multi-isotopologue observations are a very powerful constraint for chemical models. The aim of our observations is to understand the processes that form the observed high abundances of methanol and formaldehyde in low-mass protostellar envelopes (gas-phase processes? chemistry on the grain surfaces?), as well as to better constrain the chemical models. Methods. With the IRAM 30 m single-dish telescope, we observed deuterated formaldehyde (HDCO and D2CO) and methanol (CH2DOH, CH3OD, and CHD2OH) towards a sample of seven low-mass class 0 protostars. Using population diagrams, we then derived the fractionation ratios of these species (abundance ratio between the deuterated molecule and its main isotopologue) and compared them to the predictions of grain chemistry models. Results. These protostars show a similar level of deuteration as in IRAS 16293−2422, where doubly-deuterated methanol – and even triply-deuterated methanol – were first detected. Our observations point to the formation of methanol on the grain surfaces, while formaldehyde formation cannot be fully pinned down. While none of the scenarii can be excluded (gas-phase or grain chemistry formation), they both seem to require abstraction reactions to reproduce the observed fractionations.