A. Fraile Rodríguez

Dipolar energy states in clusters of perpendicular magnetic nanoislands

We investigated the energy states in compact clusters of ferromagnetic islands with perpendicular anisotropy arranged on a triangular lattice. Due to their finite nature, we were able to determine the energies of all possible cluster states using dipolar energy calculations. We employed photoemission electron microscopy to observe the magnetic states in arrays of clusters of monodomain Co/Pt multilayer islands and following demagnetization, we observed a shift in the energy distribution to lower energies as the dipolar coupling increased. These multistate island clusters not only provide model arrangements of frustrated Ising-type nanomagnets but are also interesting for data storage applications.

Formation of magnetic domains and domain walls in epitaxial Fe3O4(100) elements (invited)

Magnetic domains and domain walls in epitaxial Fe3O4(100) elements (rings and wires) are imaged using magnetic force microscopy and photoemission electron microscopy. We show that the interplay between the four-fold magnetocrystalline anisotropy and the shape determines the equilibrium domain structure. Domain walls with a characteristic zig-zag structure are observed in Fe3O4(100) elements initially magnetized along one of the magnetocrystalline hard axes. We attribute the formation of zig-zag domain walls to the competition of the four-fold magnetocrystalline anisotropy, the exchange and dipolar coupling. A direct correlation between the wire width and the spin structure of zig-zag domain walls is found.

Emergent magnetic monopoles, disorder, and avalanches in artificial kagome spin ice (invited)

We study artificial spin ice with isolated elongated nanoscale islands arranged in a kagome lattice and solely interacting via long range dipolar fields. The artificial kagome spin ice displays a phenomenology similar to the microscopic pyrochlore system, where excitations at sub-Kelvin temperatures consist of emergent monopole quasiparticles that are connected via a solenoidal flux line, a classical and observable version of the Dirac string. We show that magnetization reversal in kagome spin ice is fundamentally different from the nucleation and extensive domain growth scenario expected for a generic 2D system. Here, the magnetization reverses in a strictly 1D fashion: After nucleation, a monopole-antimonopole dissociates along a 1D path, leaving a (Dirac) string of islands with reversed magnetization in its wake. Since the 2D artificial spin ice spontaneously decays into a 1D subsystem, magnetization reversal in kagome spin ice provides an example of dimensional reduction via frustration.

Direct imaging of current-induced domain wall motion in CoFeB structures

By direct x-ray photoemission electron microscopy imaging, we probe current-induced domain wall motion in 20nm thick CoFeB wires. We observe transverse walls for all wire widths up to 1500nm as a consequence of the small saturation magnetization of the material. High critical current densities above 1×1012A∕m2 for wall displacement due to the spin transfer torque effect are found. The critical current densities jc increase further with decreasing wire width indicating that jc is governed by extrinsic pinning due to edge defects. In addition to wall displacements, we observe wall transformations to energetically favorable wall types due to heating. Owing to the high Curie temperature though, the sample temperature stays below the Curie temperature even for the highest current densities where structural damage sets in.

Permalloy thin films exchange coupled to arrays of cobalt islands

Periodic arrays of elongated cobalt islands exchange coupled to continuous Permalloy thin films were fabricated using silicon nitride stencil masks and the magnetic spin configurations during magnetization reversal were studied with photoemission electron microscopy. The presence of cobalt islands results in a spatial modulation of the magnetic properties of the Permalloy films and domain walls positioned at the island boundaries. While magneto-optical Kerr effect measurements indicate differences depending on film thickness, the direct observations reveal two reversal mechanisms: formation of domains running between the islands and coherent rotation followed by propagation of a large domain.

Spin configuration of cylindrical bamboo-like magnetic nanowires

The surface and the internal magnetic structure of bamboo-like cylindrical nanowires with tailored diameter modulations have been determined exploiting the direct photoemission and transmission contrasts using photoemission electron microscopy combined with X-ray magnetic circular dichroism, as well as complementary magnetic force microscopy and micromagnetic simulations. Bamboo-like cylindrical nanowires with diameters of 130 and 140 nm, and a modulation periodicity of 400 nm were electrochemically grown into the pores of alumina templates. FeCoCu and Co nanowires were selected to offer parallel and perpendicular magnetization easy axis, respectively. For FeCoCu nanowires, a main longitudinal magnetization configuration is found consistent with the predominant shape anisotropy. In addition, a weaker modulated contrast along the wires’ axis is observed that matches the position of each diameter modulation: vortex-like structures are observed at the ends of the wires and at the surface around the modulations. In Co nanowires, a multi-segmented vortex-like structure with alternating opposite chirality is found not matching the periodicity of the diameter modulations. Such a spin configuration is interpreted considering that Co nanowires exhibit hexagonal symmetry with c axis nearly perpendicular to the nanowires defining strong uniaxial transverse magnetocrystalline anisotropy.

Probing single magnetic nanoparticles by polarization-dependent soft x-ray absorption spectromicroscopy

Using photoemission electron microscopy, we have measured x-ray absorption (XAS) and x-ray magnetic circular dichroism (XMCD) spectra of single, three-dimensional iron nanoparticles in the size range 6?25?nm. We discuss the feasibility and limits of single-particle XAS and XMCD spectroscopy, in particular the influence of the experimental conditions such as nanofocusing effects, and analytical methods on the resulting spectra. While care must be taken in interpreting peak intensities, the overall line shape is less affected, which allows relative comparisons between different single particles in the ensemble and with reference spectra. Our work reveals that the spectral shape of both the isotropic absorption and the XMCD of single particles is retained for particles down to 6?nm and is in reasonable agreement with that of metallic bulk iron.

On the interface magnetism of thin oxidized Co films: orbital and spin moments

An x-ray magnetic circular dichroism study of a polycrystalline Co/CoO bilayer is presented. Using both the chemical specificity and surface sensitivity in the core level techniques, we find that uncompensated Co(2+) spin moments participate in the remanent ferromagnetic response of the bilayer that has oxygen nearest neighbors. These are likely located at the Co/CoO interface. As intermixing of magnetic species is not present in Co/CoO, it is concluded that the observed interface moments are due to interface roughness. Given their direction, these moments appear to not directly correlate to the exchange bias in these bilayers.

Effect of substrate interface on the magnetism of supported iron nanoparticles

In situ X-ray photo-emission electron microscopy is used to investigate the magnetic properties of iron nanoparticles deposited on different single crystalline substrates, including Si(001), Cu(001), W(110), and NiO(001). We find that, in our room temperature experiments, Fe nanoparticles deposited on Si(001) and Cu(001) show both superparamagnetic and magnetically stable (blocked) ferromagnetic states, while Fe nanoparticles deposited on W(110) and NiO(001) show only superparamagnetic behaviour. The dependence of the magnetic behaviour of the Fe nanoparticles on the contact surface is ascribed to the different interfacial bonding energies, higher for W and NiO, and to a possible relaxation of point defects within the core of the nanoparticles on these substrates, that have been suggested to stabilise the ferromagnetic state at room temperature when deposited on more inert surfaces such as Si and Cu.

Probing the variability in oxidation states of magnetite nanoparticles by single-particle spectroscopy

We have studied the electronic and chemical properties of a variety of ensembles of size- and shape-selected Fe3O4 nanoparticles with single-particle sensitivity by means of synchrotron-based X-ray photoemission electron microscopy. The local X-ray absorption spectra reveal that the oxidation states and the amount and type of cations within the individual nanoparticles can show a striking local variability even when the average structural and magnetic parameters of the monodisperse ensembles appear to be compatible with those of conventional homogeneous magnetite nanoparticles. Our results show the key role played by oleic acid concentration in the reaction mixture on the formation and compositional homogeneity within individual nanoparticles. When the concentration of oleic acid is high enough, the nanoparticles are composed of a Fe3O4 core surrounded by a thin γ-Fe2O3 shell. However, at a low concentration of the fatty acid, the Fe3O4 nanoparticles are likely inhomogeneous with small inclusions of FeO and Fe phases, as a result of an uncontrolled reduction of Fe3+ cations. All the foregoing underlines the importance of combining both advanced synthesis techniques and complementary single-particle investigations performed on a statistically significant number of particles so as to improve the understanding and control over electronic and magnetic phenomena at the nanoscale.