A. Hofman

Sputtering of solids by heavy ions and temperature effects in electronic and lattice subsystems

The results of sputtering coefficient measurements for pure metals, alloys, amorphous alloys, semiconductors, and highly oriented pyrolytic graphite under irradiation by high energy ions are considered. The possible mechanisms of strong sputtering of materials with high defect concentrations are discussed. The three-dimensional thermal spike model (“hot ion track”) with the temperature dependence of thermodynamic parameters (specific heat thermal conductivity) is formulated for single-layer mono-and polycrystals and multilayer systems (materials). The results of a numerical solution to the introduced system of partial differential equations are considered for the lattice and electronic subsystem temperatures around and along the fast heavy ion trajectory as a function of the time t, as well as radial r and longitudinal z coordinates, taking into account possible phase transitions such as melting and evaporation. The results obtained are discussed.

Thermal processes in multilayer second-generation HTSC under swift heavy-ion irradiation

On the basis of the thermal spike model, the estimations with regard to tapes of the second-generation Ag/YBaCuO/MgO/Hastelloy HTSC under irradiation with Ar, Kr, and Xe ions of an energy of about 1.2 MeV/amu have been carried out. The results have been compared with the available experimental data. In addition, the possibility of processes such as melting, recrystallization, amorphization, and other phase transitions in multilayer structures under ion irradiation has been studied.

DEPTH CONCENTRATIONS OF DEUTERIUM IONS IMPLANTED INTO SOME PURE METALS AND ALLOYS

Pure metals (Cu, Ti, Zr, V, Pd) and diluted Pd alloys (Pd-Ag, Pd-Pt, Pd-Ru, Pd-Rh) were implanted by 25-keV deuterium ions at fluences in the range (1.2–2.3) × 1022 m−2. The post-treatment depth distributions of deuterium ions were measured 10 days and three months after the implantation by using Elastic Recoil Detection Analysis (ERDA) and Rutherford Backscattering (RBS). Comparison of the obtained results allowed us to make conclusions about relative stability of deuterium and hydrogen gases in pure metals and diluted Pd alloys. Very high diffusion rates of implanted deuterium ions in V and Pd pure metals and Pd alloys were observed. Small-angle X-ray scattering revealed formation of nanosized defects in implanted corundum and titanium.

Deuterium and hydrogen distribution in a stack of Ta|(CD2)n|Ta foils under the action of high-temperature pulsed nitrogen plasma

Using the method of the elastic recoil detection (ERD) of hydrogen nuclei and a Plasma Focus setup (PF-4), we study the processes of the storage and redistribution of hydrogen and deuterium atoms in a stack of two tantalum foils and a deuterated polyethylene film sandwiched between them under pulsed irradiation with hot nitrogen plasma. It is established that the redistribution of implanted deuterium and hydrogen occurs at greater depths in both tantalum foils after 30 pulses of nitrogen plasma. The maximum concentrations of hydrogen and deuterium, namely 7 and 45 at % are observed on the surface of the second tantalum foil which is more distant from the PF-4 setup. The redistribution of deuterium from deuterated polyethylene onto the surface and volume of both Ta foils is observed. The observed phenomenon can be explained by the breaking of chemical bonds in the deuterated polyethylene and the transfer of freed deuterium into the Ta foils under the action of strong shock waves formed in the structure, as well as the accelerated diffusion of hydrogen and deuterium in the stress field caused by the shock wave.

Numerical investigation of temperature effects in materials irradiated by high-energy heavy ions in the framework of heat conduction equation for electrons and lattice

A system of equations for electron gas and lattice around and along the trajectory of a heavy uranium ion with an energy of 700 MeV in nickel at constant heat capacity and heat conduction taken at room temperature is solved numerically in an axially symmetric cylindrical coordinate system. On the basis of the lattice temperature obtained as a function of radius around the ion trajectory and depth, a conclusion is made that the ionization energy losses of a uranium ion in nickel are sufficient for melting and evaporating the material from the surface. The maximum radius and depth of the region in which melting and evaporation take place are estimated.

ERD STUDIES OF D-ION DEPTH DISTRIBUTIONS AFTER IMPLANTATION INTO SOME PURE METALS AND ALLOYS

This paper presents a report on experimental results of depth distributions of deuterium ions implanted with 25 keV energy at a fluence interval of (1.2–2.3) × 1022 m−2 into samples of pure metals (Cu, Ti, Zr, V, Pd) and diluted Pd alloys (Pd-Ag, Pd-Pt, Pd-Ru, Pd-Rh). The post-treatment depth distributions of deuterium and hydrogen atoms were measured within a few hours after implantation with the use of elastic recoil detection (ERD) analysis. After three months the measurements were repeated. The comparison of the obtained results in both series of studies allowed us to make an important observation of the desorption rates of implanted deuterium atoms from pure metals and diluted Pd alloys. The maximum measured concentrations of deuterium atoms in pure Zr and Ti foils with relatively small desorption rate of deuterium atoms within three months after implantation were observed. Also a very high spreading of deuterium atom distributions was observed in all the measured pure metals and alloys. It can be explained by the large diffusion coefficients of deuterium and extremely fast kinetics.

The Use of a Thermal Spike Model for Temperature Calculation in Two-Layer Structures along the Projective Track of a High-Energy Heavy Ion

A thermal spike model in a three-dimensional case is used for the calculation of temperatures in a structure consisting of two layers of different materials. The systems of equations for electron gas and lattice temperatures are solved numerically in the axial-symmetric coordinate system at constant values of specific capacities and thermal conductivities for the Ni(2 μm)/W two-layer system. One can conclude on the basis of the obtained results that the phase transitions can take place when there is irradiation of the Ni(2 μm)/W two-layer structure with 209Bi ions with an energy of 710 MeV: melting, in both layers; and evaporation, only in the Ni layer (first layer). The maximum radii and depths where the melting (Ni and W layers) and evaporation (Ni layer) processes occur are calculated.