A. I. Yanson

Formation and manipulation of a metallic wire of single gold atoms

The continuing miniaturization of microelectronics raises the prospect of nanometre-scale devices with mechanical and electrical properties that are qualitatively different from those at larger dimensions. The investigation of these properties, and particularly the increasing influence of quantum effects on electron transport, has therefore attracted much interest. Quantum properties of the conductance can be observed when ‘breaking’ a metallic contact: as two metal electrodes in contact with each other are slowly retracted, the contact area undergoes structural rearrangements until it consists in its final stages of only a few bridging atoms. Just before the abrupt transition to tunnelling occurs, the electrical conductance through a monovalent metal contact is always close to a value of 2e2/h (≈12.9 Ω−1), where e is the charge on an electron and h is Plancks constant. This value corresponds to one quantum unit of conductance, thus indicating that the ‘neck’ of the contact consists of a single atom. In contrast to previous observations of only single-atom necks, here we describe the breaking of atomic-scale gold contacts, which leads to the formation of gold chains one atom thick and at least four atoms long. Once we start to pull out a chain, the conductance never exceeds 2e2/h, confirming that it acts as a one-dimensional quantized nanowire. Given their high stability and the ability to support ballistic electron transport, these structures seem well suited for the investigation of atomic-scale electronics.

Common origin for surface reconstruction and the formation of chains of metal atoms

During the fracture of nanocontacts gold spontaneously forms freely suspended chains of atoms, which is not observed for the isoelectronic noble metals Ag and Cu. Au also differs from Ag and Cu in forming reconstructions at its low-index surfaces. Using mechanically controllable break junctions we show that all the 5d metals that show similar reconstructions (Ir, Pt, and Au) also form chains of atoms, while both properties are absent in the 4d neighbor elements (Rh, Pd, and Ag), indicating a common origin for these two phenomena. A competition between s and d bonding is proposed as an explanation.

Observation of Shell Structure in Sodium Nanowires

The quantum states of a system of particles in a finite spatial domain in general consist of a set of discrete energy eigenvalues; these are usually grouped into bunches of degenerate or close-lying levels, called shells. In fermionic systems, this gives rise to a local minimum in the total energy when all the states of a given shell are occupied. In particular, the closed-shell electronic configuration of the noble gases produces their exceptional stability. Shell effects have previously been observed for protons and neutrons in nuclei, and for clusters of metal atoms. Here we report the observation of shell effects in an open system—a sodium metal nanowire connecting two bulk sodium metal electrodes, which are progressively pulled apart. We measure oscillations in the statistical distribution of conductance values, for contact cross-sections containing up to a hundred atoms or more. The period follows the law expected from shell-closure effects, similar to the abundance peaks at ‘magic’ numbers of atoms in metal clusters,.

Calibration of the length of a chain of single gold atoms

In the last few years, there has been a significant advance in the understanding of the electronic properties of atomicsized contacts. This has been possible thanks to the use of two techniques: scanning tunnelling microscopy ~STM! ~Refs. 1 and 2! and the mechanically controllable break junction ~MCBJ!. 3 In both cases the distance between two electrodes is controlled by means of a piezoelectric transducer which allows for relative displacements of the electrodes down to a resolution in the range of picometers. In these experiments the current that traverses the contact between two electrodes, at a given bias voltage, is measured as a function of the relative displacement of these electrodes. As the contact is broken, the current changes smoothly during elastic elongation stages, decreasing suddenly in plastic deformations stages. 4,5 In the last stage before breaking the contact, just a few atoms determine the electronic transport and the conductance is given by the Landauer formula G5 2e 2

Supershell Structure in Alkali Metal Nanowires

Nanowires are formed by indenting and subsequently retracting two pieces of sodium metal. Their cross section gradually reduces upon retraction and the diameters can be obtained from the conductance. In previous work we have demonstrated that when one constructs a histogram of diameters from large numbers of indentation-retraction cycles such histograms show a periodic pattern of stable nanowire diameters due to shell structure in the conductance modes. Here, we report the observation of a modulation of this periodic pattern, in agreement with predictions of a supershell structure.

Atomic size oscillations in conductance histograms for gold nanowires and the influence of work hardening

Nanowires of different natures have been shown to self-assemble as a function of stress at the contact between two macroscopic metallic leads. Here we demonstrate for Au wires that the balance between various metastable nanowire configurations is influenced by the microstructure of the starting materials, and we discover a new set of periodic structures, which we interpret as due to the atomic discreteness of the contact size for the three principal crystal orientations.

Effect of disorder on the conductance of a Cu atomic point contact

We present a systematic study of the effect of the disorder in copper point contacts. We show that peaks in the conductance histogram of copper point contacts shift upon addition of nickel impurities. The shift increases initially linearly with the nickel concentration, thus confirming that it is due to disorder in the nanowire, in accordance with predictions. In general, this shift is modeled as a resistance Rs which is placed in series with the contact resistance Rc . However, we obtain different Rs values for the two peaks in the histogram, Rs being larger for the peak at higher conductance.

Crossover from Electronic to Atomic Shell Structure in Alkali Metal Nanowires

After making a cold weld by pressing two clean metal surfaces together, upon gradually separating the two pieces a metallic nanowire is formed, which progressively thins down to a single atom before contact is lost. In previous experiments we have observed that the stability of such nanowires is influenced by electronic shell filling effects, in analogy to shell effects in metal clusters. For sodium and potassium at larger diameters there is a crossover to crystalline wires with shell closings corresponding to the completion of additional atomic layers. This observation completes the analogy between shell effects observed for clusters and nanowires.

Characterization of individual conductance steps in metallic quantum point contacts

The properties of a large number of individual steps in the conductance of atom-size contacts as a function of cross-section have been investigated. The results confirm that the steps are the result of atomic structural rearrangements, without exception for all individual steps in the survey. Furthermore, we report the first direct observation of the transformation of a hysteresis cycle around a conductance step in a two-level fluctuation.

Conductance of single-atom platinum contacts: Voltage dependence of the conductance histogram

The conductance of a single-atom contact is sensitive to the coupling of this contact atom to the atoms in the leads. Notably for the transition metals this gives rise to a considerable spread in the observed conductance values. The mean conductance value and spread can be obtained from the first peak in conductance histograms recorded from a large set of contact-breaking cycles. In contrast to the monovalent metals, this mean value for Pt depends strongly on the applied voltage bias and other experimental conditions and values ranging from about 1