A. Joshua West

Thickness of the chemical weathering zone and implications for erosional and climatic drivers of weathering and for carbon-cycle feedbacks

Quantitative understanding of variability in weathering fluxes on the modern Earth is limited because little is known about where the most important weathering reactions take place. This is partly because the locus of weathering is difficult to measure empirically. Inverse analysis of a parametric model presented here provides first-order constraints on variability in the thickness of the zone of active weathering. Results suggest that the effective thickness of the weathering zone varies relatively little across several orders of magnitude of denudation rate. At low to moderate denudation rates, reactions in soils may dominate weathering fluxes at the catchment scale, but the contribution from soil weathering decreases at higher denudation rates. Consequently, increased erosion leads to higher weathering fluxes, sustained by progressively greater contributions from weathering in bedrock. The effect of climate (temperature and runoff) on weathering fluxes is apparently weaker at low denudation rates than at high denudation rates, such that erosion, and potentially associated bedrock weathering, may be important for maintaining climate-stabilizing feedbacks in Earth’s carbon cycle.

Small-catchment perspective on Himalayan weathering fluxes

Weathering fluxes from four small catchments in the Himalayas, one forested, one agricultural, and two glacial, have been calculated by quantifying stream discharge, deposition, and biomass uptake of major ions. These fluxes were partitioned between silicate and carbonate sources by using a mineral mass-balance model. This approach provides the first well-defined estimates of Himalayan weathering fluxes from small catchments. Silicate weathering rates are highest in the favorable weathering environment of the Middle Hills catchments, despite higher dissolved fluxes in the High Himalayas attributed to high carbonate weathering. The silicate weathering fluxes for High Himalayan small catchments are similar to estimates from the chemistry of large rivers draining the same regions. Much higher silicate weathering intensity for the Ganges basin indicates that the silicate material eroded from the High Himalayas undergoes up to six times as much weathering in the Ganges Plain as in the High Himalayan mountains. Himalayan silicate weathering rates are higher than in equivalent continental settings and, on an area-normalized basis, are comparable to fluxes from weathering of basalts on ocean islands and tropical volcanic provinces.

Sulphide oxidation and carbonate dissolution as a source of CO 2 over geological timescales

The observed stability of Earth’s climate over millions of years is thought to depend on the rate of carbon dioxide (CO2) release from the solid Earth being balanced by the rate of CO2 consumption by silicate weathering. During the Cenozoic era, spanning approximately the past 66 million years, the concurrent increases in the marine isotopic ratios of strontium, osmium and lithium suggest that extensive uplift of mountain ranges may have stimulated CO2 consumption by silicate weathering, but reconstructions of sea-floor spreading do not indicate a corresponding increase in CO2 inputs from volcanic degassing. The resulting imbalance would have depleted the atmosphere of all CO2 within a few million years. As a result, reconciling Cenozoic isotopic records with the need for mass balance in the long-term carbon cycle has been a major and unresolved challenge in geochemistry and Earth history. Here we show that enhanced sulphide oxidation coupled to carbonate dissolution can provide a transient source of CO2 to Earth’s atmosphere that is relevant over geological timescales. Like drawdown by means of silicate weathering, this source is probably enhanced by tectonic uplift, and so may have contributed to the relative stability of the partial pressure of atmospheric CO2 during the Cenozoic. A variety of other hypotheses have been put forward to explain the ‘Cenozoic isotope-weathering paradox’, and the evolution of the carbon cycle probably depended on multiple processes. However, an important role for sulphide oxidation coupled to carbonate dissolution is consistent with records of radiogenic isotopes, atmospheric CO2 partial pressure and the evolution of the Cenozoic sulphur cycle, and could be accounted for by geologically reasonable changes in the global dioxygen cycle, suggesting that this CO2 source should be considered a potentially important but as yet generally unrecognized component of the long-term carbon cycle.

Seismic mountain building: Landslides associated with the 2008 Wenchuan earthquake in the context of a generalized model for earthquake volume balance

Here we assess earthquake volume balance and the growth of mountains in the context of a new landslide inventory for the Mw7.9 Wenchuan earthquake in central China. Coseismic landslides were mapped from high-resolution remote imagery using an automated algorithm and manual delineation, which allows us to distinguish clustered landslides that can bias landslide volume calculations. Employing a power-law landslide area-volume relation, we find that the volume of landslide-associated mass wasting (~2.8+0.9/-0.7 km3) is lower than previously estimated (~5.7-15.2 km3) and comparable to the volume of rock uplift (~2.6±1.2 km3) during the Wenchuan earthquake. If fluvial evacuation removes landslide debris within the earthquake cycle, then the volume addition from coseismic uplift will be effectively offset by landslide erosion. If all earthquakes in the region followed this volume budget pattern, the efficient counteraction of coseismic rock uplift raises a fundamental question about how earthquakes build mountainous topography. To provide a framework for addressing this question, we explore a group of scaling relations to assess earthquake volume balance. We predict coseismic uplift volumes for thrust-fault earthquakes based on geophysical models for coseismic surface deformation and relations between fault rupture parameters and moment magnitude, Mw. By coupling this scaling relation with landslide volume-Mw scaling, we obtain an earthquake volume balance relation in terms of moment magnitude Mw, which is consistent with the revised Wenchuan landslide volumes and observations from the 1999 Chi-Chi earthquake in Taiwan. Incorporating the Gutenburg-Richter frequency-Mw relation, we use this volume balance to derive an analytical expression for crustal thickening from coseismic deformation based on an index of seismic intensity over a defined area. This model yields reasonable rates of crustal thickening from coseismic deformation (e.g.~0.1-0.5 km Ma-1 in tectonically active convergent settings), and implies that moderate magnitude earthquakes (Mw≈6-8) are likely responsible for most of the coseismic contribution to rock uplift, because of their smaller landslide-associated volume reduction. Our first-order model does not consider a range of factors (e.g., lithology, climate conditions, epicentral depth and tectonic setting), nor does it account for viscoelastic or isostatic responses to erosion, and there remain important uncertainties on the scaling relationships used to quantify coseismic deformation. Nevertheless, our study provides a conceptual framework and invites more rigorous modeling of seismic mountain building.

Controls on fluvial evacuation of sediment from earthquake-triggered landslides

Large earthquakes in active mountain belts can trigger landslides, which mobilize large volumes of clastic sediment. Delivery of this material to river channels may result in aggradation and flooding, while sediment residing on hillslopes may increase the likelihood of subsequent landslides and debris flows. Despite recognition of these processes, the controls on the residence time of coseismic landslide sediment in river catchments remain poorly understood. Here we assess the residence time of fine-grained ( 5 mm day–1). Together with previous observations from the C.E. 1999 Chi-Chi earthquake in Taiwan, our results demonstrate the importance of landslide density and runoff intensity in setting the duration of earthquake-triggered landslide impacts on river systems.

Leaf wax biomarkers in transit record river catchment composition

Rivers carry organic molecules derived from terrestrial vegetation to sedimentary deposits in lakes and oceans, storing information about past climate and erosion, as well as representing a component of the carbon cycle. It is anticipated that sourcing of organic matter may not be uniform across catchments with substantial environmental variability in topography, vegetation zones, and climate. Here we analyze plant leaf wax biomarkers in transit in the Madre de Dios River (Peru), which drains a forested catchment across 4.5 km of elevation from the tropical montane forests of the Andes down into the rainforests of Amazonia. We find that the hydrogen isotopic composition of leaf wax molecules (specifically the C28 n-alkanoic acid) carried by this tropical mountain river largely records the elevation gradient defined by the isotopic composition of precipitation, and this supports the general interpretation of these biomarkers as proxy recorders of catchment conditions. However, we also find that leaf wax isotopic composition varies with river flow regime over storm and seasonal timescales, which could in some cases be quantitatively significant relative to changes in the isotopic composition of precipitation in the past. Our results inform on the sourcing and transport of material by a major tributary of the Amazon River and contribute to the spatial interpretation of sedimentary records of past climate using the leaf wax proxy.

Mercury anomalies and the timing of biotic recovery following the end-Triassic mass extinction.

The end-Triassic mass extinction overlapped with the eruption of the Central Atlantic Magmatic Province (CAMP), and release of CO2 and other volcanic volatiles has been implicated in the extinction. However, the timing of marine biotic recovery versus CAMP eruptions remains uncertain. Here we use Hg concentrations and isotopes as indicators of CAMP volcanism in continental shelf sediments, the primary archive of faunal data. In Triassic–Jurassic strata, Muller Canyon, Nevada, Hg levels rise in the extinction interval, peak before the appearance of the first Jurassic ammonite, remain above background in association with a depauperate fauna, and fall to pre-extinction levels during significant pelagic and benthic faunal recovery. Hg isotopes display no significant mass independent fractionation within the extinction and depauperate intervals, consistent with a volcanic origin for the Hg. The Hg and palaeontological evidence from the same archive indicate that significant biotic recovery did not begin until CAMP eruptions ceased.

Dam-triggered organic carbon sequestration makes the Changjiang (Yangtze) river basin (China) a significant carbon sink

Worldwide dam building in large river basins has substantially altered the carbon cycle by trapping much of the riverine transported particulate organic carbon (POC) in terrestrial reservoirs. Here we take the Changjiang (Yangtze) River basin, in which ~50,000 dams were built over the past 50 years, as an example to evaluate the effect of dam building on POC sequestration. We report the characteristics (elemental composition, radiocarbon and stable carbon isotopic compositions, and Raman spectra) of bulk POC in the lower Changjiang from October 2007 to September 2008, and we estimate the POC sequestration induced by dam building since the 1950s for the Changjiang Basin. Using radiocarbon measurements, we quantify the fraction of biospheric POC (POCbio) and petrogenic POC (POCpetro) in Changjiang POC. Over the study period, around 25% of the Changjiang POC is radiocarbon-dead POCpetro; the remaining is POCbio with a mean radiocarbon age of ~3.5 kyr. Studies on the East China Sea (ECS) shelf along with an oxidation experiment suggest that, prior to dam building, the Changjiang POCbio was significantly oxidized in the ECS margin. In contrast, high preservation of POC is observed in Changjiang reservoirs. Combining our POC data with hydrometric data sets, our study indicates that, over the past five decades, dam building may have largely shifted the Changjiang POC burial site from the ECS margin to terrestrial reservoirs. This shift in burial site preserved labile POCbio that would have been oxidized, suggesting a new temporary carbon sink. We estimate that dam building in the Changjiang has sequestered ~4.9 ± 1.9 megatons POCbio every year since 2003, approximately 10% of the global riverine POC burial flux to the oceans.

Connectivity of earthquake‐triggered landslides with the fluvial network: Implications for landslide sediment transport after the 2008 Wenchuan earthquake

Evaluating the influence of earthquakes on erosion, landscape evolution, and sediment-related hazards requires understanding fluvial transport of material liberated in earthquake-triggered landslides. The location of landslides relative to river channels is expected to play an important role in postearthquake sediment dynamics. In this study, we assess the position of landslides triggered by the Mw 7.9 Wenchuan earthquake, aiming to understand the relationship between landslides and the fluvial network of the steep Longmen Shan mountain range. Combining a landslide inventory map and geomorphic analysis, we quantify landslide-channel connectivity in terms of the number of landslides, landslide area, and landslide volume estimated from scaling relationships. We observe a strong spatial variability in landslide-channel connectivity, with volumetric connectivity (ξ) ranging from ~20% to ~90% for different catchments. This variability is linked to topographic effects that set local channel densities, seismic effects (including seismogenic faulting) that regulate landslide size, and substrate effects that may influence both channelization and landslide size. Altogether, we estimate that the volume of landslides connected to channels comprises 43 + 9/−7% of the total coseismic landslide volume. Following the Wenchuan earthquake, fine-grained ( 90% of the total landslide volume) may be more significantly affected by landslide locations.

Catchment-scale variation in the nitrate concentrations of groundwater seeps in the Catskill Mountains, New York, U.S.A.

Forested headwater streams in the Catskill Mountains of New York show significant among-catchment variability in mean annual nitrate (NO3-) concentrations. Large contributions from deep groundwater with high NO3-concentrations have been invoked to explain high NO3-concentrations in stream water during the growing season. To determine whether variable contributions of groundwater couldexplain among-catchment differences in streamwater, we measuredNO3- concentrations in 58 groundwater seeps distributed across six catchments known to have different annual average streamwater concentrations. Seeps were identified based on release from bedrock fractures and beddingplanes and had consistently lower temperatures than adjacentstreamwaters. Nitrate concentrations in seeps ranged from neardetection limits (0.005 mg NO3--N/L) to 0.75 mg NO3--N/L. Within individual catchments, groundwaterresidence time does not seem to strongly affect NO3-concentrations because in three out of four catchments therewere non-significant correlations between seep silica (SiO2) concentrations, a proxy for residence time, andseep NO3- concentrations. Across catchments, therewas a significant but weak negative relationship betweenNO3- and SiO2 concentrations. The large rangein NO3- concentrations of seeps across catchmentssuggests: 1) the principal process generating among-catchmentdifferences in streamwater NO3- concentrations mustinfluence water before it enters the groundwater flow system and 2) this process must act at large spatial scales becauseamong-catchment variability is much greater than intra-catchmentvariability. Differences in the quantity of groundwater contribution to stream baseflow are not sufficient to account for differences in streamwater NO3- concentrationsamong catchments in the Catskill Mountains.