A. Ladstätter-Weißenmayer

The Global Ozone Monitoring Experiment (GOME): Mission Concept and First Scientific Results

The Global Ozone Monitoring Experiment (GOME) is a new instrument aboard the European Space Agencys (ESA) Second European Remote Sensing Satellite(ERS-2), which was launched in April 1995. The main scientific objective of the GOME mission is to determine the global distribution of ozone and several other trace gases, which play an important role in the ozone chemistry of the earths stratosphere and troposphere. GOME measures the sunlight scattered from the earths atmosphere and/or reflected by the surface in nadir viewing mode in the spectral region 240-790 nm at a moderate spectral resolution of between 0.2 and 0.4 nm. Using the maximum 960-km across-track swath width, the spatial resolution of a GOME ground pixel is 40 3 320 km2 for the majority of the orbit and global coverage is achieved in three days after 43 orbits. Operational data products of GOME as generated by DLR-DFD, the German Data Processing and Archiving Facility (D-PAF) for GOME, comprise absolute radiometrically calibrated earthshine radiance and solar irradiance spectra (level 1 products) and global distributions of total column amounts of ozone and NO 2 (level 2 products), which are derived using the DOAS approach (Differential Optical Absorption Spectroscopy). (Under certain conditions and some restrictions, the operational data products are publically available from the European Space Agency via the ERS Helpdesk.) In addition to the operational data products, GOME has delivered important information about other minor trace gases such as OClO, volcanic SO2 ,H 2CO from biomass burning, and tropospheric BrO. Using an iterative optimal estimation retrieval scheme, ozone vertical profiles can be derived from the inversion of the UV/VIS spectra. This paper reports on the GOME instrument, its operation mode, and the retrieval techniques, the latter with particular emphasis on DOAS (total column retrieval) and advanced optimal estimation (ozone profile retrieval). Observation of ozone depletion in the recent polar spring seasons in both hemispheres are presented. OClO observed by GOME under twilight conditions provides valuable information on the chlorine activation inside the polar vortex, which is believed to be responsible for the rapid catalytic destruction of ozone. Episodes of enhanced BrO in the Arctic, most likely contained in the marine boundary layer, were observed in early and late spring. Excess tropospheric nitrogen dioxide and ozone have been observed during the recent Indonesian fire in fall 1997. Formaldehyde could also clearly be identified by GOME and is known to be a by-product resulting from biomass burning.

GOME MEASUREMENTS OF STRATOSPHERIC AND TROPOSPHERIC BrO

Measurements from the Global Ozone Monitoring Experiment (GOME) have been analysed for BrC absorption using the Differential Optical Absorption (DOAS) method. By introducing a correction for a small angle dependency of the diffisor used for the direct sun measurements in the GOME instrument, the overall consistency of the BrO data set could be improved significantly. Evidence is found for large tropospheric contributions to the BrO columns measured by GOME, both from BrO in the polar boundary layer in spring and a global BrO background, probably located in the free troposphere and present throughout the year. The latter has been further investigated by comparing BrO and 0, columns above the remote Pacific, resulting in an estimate of 0.5 - 2ppt of uniformly mixed BrO in the troposphere, in agreement with previous studies. 0 2002 COSPAR. Published by Elsevier Science Ltd. All rights reserved.

DOAS Zenith Sky Observations: 2. Seasonal Variation of BrO Over Bremen (53°N) 1994-1995

Zenith sky observations of BrO over Bremen (53°N) are reported for the period of September 1994 to January 1996. BrO differential slant columns between 90° and 80° solar zenith angle showed a strong seasonal variation between a winter maximum of 1.9·1014 molec/cm2 and a summer minimum of 0.6·1014 molec/cm2. The seasonal variation in BrO twilight values is shown to be inversely correlated with NO2 columns in agreement with current knowledge of gas phase chemistry of bromine. In contrast to model predictions, no significant difference between morning and evening BrO measurements was observed. During a 6 day polar vortex excursion to mid-latitudes OClO could be measured above Bremen indicating chlorine activation in the vortex air. No significant increase in BrO differential slant columns was detected during this time.

DOAS Zenith Sky Observations: 1. BrO Measurements over Bremen (53°N) 1993–1994

Abstract Observations of stratospheric BrO over Bremen (53°N) are reported for winter and early spring periods of 1993 and 1993/94. The BrO was observed by ground-based near-UV absorption spectroscopy of sunlight scattered in the zenith. Differential slant column densities for solar zenith angles 90°/80° in the range of9× 1013 (detection limit) to 4.5×1014 molecules/cm2 having a high day-to-day variability were found. For the majority of the measurements no significant difference was observed between the morning and evening behaviour of BrO. Exceptions are the morning measurements from the winter of 1992/93 where an accelerated production of BrO was observed. We believe the latter best to be explained by the early morning rapid photolysis of elevated amounts of photo-labile Br-reservoirs formed during the night. The largest differential slant column densities of BrO were measured in December 1993 when the temperatures at 30 hPa dropped below 205 K. This might be an indication of heterogeneous conversion of bromine compounds on sulfate and other aerosols.

A study of the trace gas columns of O3, NO2 and HCHO over Africa in September 1997

Retrievals of trace gas columns from the measurements of backscattered radiation by GOME (Global Ozone Monitoring Experiment) show that enhanced tropospheric columns of ozone (O3), nitrogen dioxide (NO2) and formaldehyde (HCHO), over the African continent occur frequently. This study focuses on the behaviour of trace gases over Africa in September 1997, a period impacted by the strongest known El Niño phase of the ENSO. It investigates our qualitative and quantitative understanding of the retrieved tropospheric trace gas column densities. The emissions of NOx and volatile organic compounds (VOC) from biomass burning, biogenic sources and lightning and their photochemical transformation have been investigated. By performing a trajectory analysis, the transport of air masses from the different emission regions was analysed and the potential atmospheric spatial distribution determined. BRemens Atmospheric PHOtochemical model (BRAPHO) was applied to compute the chemistry along a large number of trajectories. From these results, tropospheric column amounts of O3, NO2 and HCHO were derived. Tropospheric trace gas columns retrieved from GOME measurements and those calculated are in reasonable agreement. Their general spatial extent was similar in the lower troposphere but the modeled trace gas columns in the upper troposphere were located south of the retrieved columns. We attribute this behaviour to uncertainties in the ERA-40 meteorological data in the upper troposphere. The significance of biomass burning and of biogenic emissions with respect to HCHO columns over Africa was investigated. The analysis reveals that the total amounts of HCHO generated over Africa during September 1997 as a result of biomass burning and biogenic emissions are similar. However the HCHO from biogenic sources has the highest specific columns and these are located close to their source. In comparison the HCHO from biomass burning is predicted to be produced and transported over a much wider area. Overall all the emission processes mix together to produce the plume of O3.

The Structural and Educational Concept in an Interdisciplinary Research School for Earth System Science

Post-graduate education in Germany has changed a lot over the past decades. Formerly, PhD students generally did not have the option to attend formal classes and lectures and were expected to conduct their independent research, including occasionally teaching courses for students. Since the introduction of bachelor and masters studies with the Bologna Process in the late 90th, the higher education in Europe has been harmonized, leading to more structured and focused studies at the expense of a broad and universal disciplinary education. At this same time, special fields such as Earth System Science became more interdisciplinary. In consequence, universities and research institutes have established so-called research schools and/or graduate schools, offering specific courses and training alongside the doctorate. Especially, Earth System Science has developed from an interesting concept in Earth Sciences education to a fully integrative Science focussed on understanding the complex system Earth. This evolution is partially due to the radical and far reaching anthropogenic changes and the general feeling of helplessness with regards to the possible consequences and future impacts on the Earth System. The Helmholtz “Earth System Science Research School” (ESSReS) is a small unit of PhD students co-organized by three educational and research institutions in the city state Bremen: University of Bremen (Institute for Environmental Physics, IUP), Jacobs University (School of Engineering and Science (JU)), and Alfred Wegener Institute, Helmholtz Centre for Polar and Marine Research in Bremerhaven (AWI). ESSReS aims at the integration of research at the interface of Geology, Biology, Physics, Geophysics, Mathematics and Informatics. It is therefore multi- and interdisciplinary in every aspect. The training, curriculum, and PhD research subjects are closely located at the interfaces between the participating disciplines. This is guaranteed by interdisciplinary supervision of the PhD project. The long-term goal of ESSReS is not only to enhance exchange and interaction between these disciplines, but to enforce a newly integrated concept, where separation between disciplines becomes more and more obsolete. Now, at the end of two three-years terms of PhD student education it can be stated that ESSReS provide a solid base for a new generation of excellent scientists in Earth and Environmental Sciences.Information about past environmental conditions is preserved in the elemental signature of biogenic marine carbonates. Thus, trace element to calcium ratios (Me/Ca) of biogenic calcium carbonates, such as bivalve shells, are often used to reconstruct past environmental conditions at the time of carbonate formation (Foster et al., 2008). In this study, we examine the suitability of the long-lived (> 400 years) bivalve Arctica islandica as a high-resolution bioarchive by measuring Me/Ca ratios in the shell carbonate. Pb/Ca concentrations in A. islandica shells reflect anthropogenic gasoline lead consumption and further provide a centennial record of lead pollution for the collection site off the coast of Virginia, USA. With A. islandica shells from the North Sea we test the hypothesis that Ba/Ca and Mn/Ca ratios are indicators of the diatom abundance. Our results indicate that statistically both ratios correlate well with the diatom abundance, and yet, on a year-to-year base, there is no consistent reflection of diatom abundance patterns in the Ba/Ca and Mn/Ca annual profiles. These findings indicate that primary production affects Ba/Ca and Mn/Ca shell ratios, though we suggest that both elements are coupled to primary production through different processes and are affected by further, yet unknown processes.To date, the software package SCIATRAN (Rozanov et al. 2002; Rozanov et al., 2005, 2008) has been used for modelling radiative processes in the atmosphere for the retrieval of trace gases from satellite data from the satellite sensor SCIAMACHY (Scanning Imaging Absorption Spectrometer for Atmospheric CHartographY onboard the satellite ENVISAT). This SCIATRAN version only accounted for radiative transfer within the atmosphere and reflection of light at the earth surface. However, radiation also passes the air-water interface, proceeds within the water and is modified by the water itself and the water constituents. Therefore, SCIATRAN has been extended by oceanic radiative transfer and coupling it to the atmospheric radiative transfer model under the terms of established models for radiative transfer underwater (Kopelevich 1983; Morel et al. 1974, 2001; Shifrin 1988; Buitevald et al. 1994; Cox and Munk 1954a, 1954b; Breon and Henriot 2006; Mobley 1994) and extending the data bases to include the specific properties of the water constituents (Pope and Fry 1997; Haltrin 2006; Prieur and Sathyendranath 1981).

Towards a Better Tropospheric Ozone Data Product from SCIAMACHY: Improvements in High Latitude Stratospheric Ozone

Tropospheric ozone is a photochemically produced secondary pollutant and a main component of summer smog. Measurements from the space borne spectrometer SCIAMACHY are well suited to investigate sources and transport mechanisms of tropospheric ozone in a global view. Exploiting alternating observations in limb and nadir modes, the Limb-Nadir Matching technique (LNM) is used to retrieve global distributions of tropospheric ozone for the entire duration of the SCIAMACHY mission (Aug. 2002–Apr. 2012). The LNM technique is rather unique since SCIAMACHY observes the same air mass within 7 min first in the limb and then in the nadir viewing modes. As 90 % of atmospheric ozone is located in the stratosphere, the LNM technique applied to satellite measurements requires very high accuracy of the input limb and nadir data. Accurate ozone data bases are not only benefitting LNM tropospheric ozone retrieval, but also requirements for ozone trends study as well as the establishment of a long-term essential climate variable (ecv) data record. This study contributes to the improvement of the quality of SCIAMACHY limb stratospheric ozone profiles retrieved over the high latitudes of the Northern Hemisphere, hence improving the accuracy of the tropospheric ozone retrieval. Furthermore we provide comparisons of partial stratospheric ozone columns (from 15 to 30 km, referred to as SPO) resulting from SCIAMACHY limb measurements with ozone sonde data.

Earth System Science—Past Experiences and Future Trends

Earth System Science has developed over the last two decades from an interesting concept in Earth sciences education to a fully integrative science focussed on understanding the complex system Earth. This evolution is partially due to the radical and far reaching anthropogenic changes and the general feeling of helplessness with regards to the possible consequences and future impacts on the Earth System. This paper proposes that a paradigm shift in undergraduate and graduate education is needed to further develop Earth System Science. Graduate programs such as the Earth System Science Research School (ESSReS), which are intrinsically trans- and interdisciplinary will help to change rigid subject specific mind-set among faculty and students. The health and sustainability of our planet is at stake.

Earth System Science: Bridging the Gaps between Disciplines: Perspectives from a Multi-disciplinary Helmholtz Research School

Post-graduate education in Germany has changed a lot over the past decades. Formerly, PhD students generally did not have the option to attend formal classes and lectures and were expected to conduct their independent research, including occasionally teaching courses for students. Since the introduction of bachelor and masters studies with the Bologna Process in the late 90th, the higher education in Europe has been harmonized, leading to more structured and focused studies at the expense of a broad and universal disciplinary education. At this same time, special fields such as Earth System Science became more interdisciplinary. In consequence, universities and research institutes have established so-called research schools and/or graduate schools, offering specific courses and training alongside the doctorate. Especially, Earth System Science has developed from an interesting concept in Earth Sciences education to a fully integrative Science focussed on understanding the complex system Earth. This evolution is partially due to the radical and far reaching anthropogenic changes and the general feeling of helplessness with regards to the possible consequences and future impacts on the Earth System. The Helmholtz “Earth System Science Research School” (ESSReS) is a small unit of PhD students co-organized by three educational and research institutions in the city state Bremen: University of Bremen (Institute for Environmental Physics, IUP), Jacobs University (School of Engineering and Science (JU)), and Alfred Wegener Institute, Helmholtz Centre for Polar and Marine Research in Bremerhaven (AWI). ESSReS aims at the integration of research at the interface of Geology, Biology, Physics, Geophysics, Mathematics and Informatics. It is therefore multi- and interdisciplinary in every aspect. The training, curriculum, and PhD research subjects are closely located at the interfaces between the participating disciplines. This is guaranteed by interdisciplinary supervision of the PhD project. The long-term goal of ESSReS is not only to enhance exchange and interaction between these disciplines, but to enforce a newly integrated concept, where separation between disciplines becomes more and more obsolete. Now, at the end of two three-years terms of PhD student education it can be stated that ESSReS provide a solid base for a new generation of excellent scientists in Earth and Environmental Sciences.Information about past environmental conditions is preserved in the elemental signature of biogenic marine carbonates. Thus, trace element to calcium ratios (Me/Ca) of biogenic calcium carbonates, such as bivalve shells, are often used to reconstruct past environmental conditions at the time of carbonate formation (Foster et al., 2008). In this study, we examine the suitability of the long-lived (> 400 years) bivalve Arctica islandica as a high-resolution bioarchive by measuring Me/Ca ratios in the shell carbonate. Pb/Ca concentrations in A. islandica shells reflect anthropogenic gasoline lead consumption and further provide a centennial record of lead pollution for the collection site off the coast of Virginia, USA. With A. islandica shells from the North Sea we test the hypothesis that Ba/Ca and Mn/Ca ratios are indicators of the diatom abundance. Our results indicate that statistically both ratios correlate well with the diatom abundance, and yet, on a year-to-year base, there is no consistent reflection of diatom abundance patterns in the Ba/Ca and Mn/Ca annual profiles. These findings indicate that primary production affects Ba/Ca and Mn/Ca shell ratios, though we suggest that both elements are coupled to primary production through different processes and are affected by further, yet unknown processes.To date, the software package SCIATRAN (Rozanov et al. 2002; Rozanov et al., 2005, 2008) has been used for modelling radiative processes in the atmosphere for the retrieval of trace gases from satellite data from the satellite sensor SCIAMACHY (Scanning Imaging Absorption Spectrometer for Atmospheric CHartographY onboard the satellite ENVISAT). This SCIATRAN version only accounted for radiative transfer within the atmosphere and reflection of light at the earth surface. However, radiation also passes the air-water interface, proceeds within the water and is modified by the water itself and the water constituents. Therefore, SCIATRAN has been extended by oceanic radiative transfer and coupling it to the atmospheric radiative transfer model under the terms of established models for radiative transfer underwater (Kopelevich 1983; Morel et al. 1974, 2001; Shifrin 1988; Buitevald et al. 1994; Cox and Munk 1954a, 1954b; Breon and Henriot 2006; Mobley 1994) and extending the data bases to include the specific properties of the water constituents (Pope and Fry 1997; Haltrin 2006; Prieur and Sathyendranath 1981).