A. Mukherjee

Observational evidence from direct current measurements for propagation of remotely forced waves on the shelf off the west coast of India

[1]xa0We use data from six Acoustic Doppler Current Profiler (ADCP) moorings deployed during March–September 2008 on the continental shelf and slope off Bhatkal, Goa, and Jaigarh on the central west coast of India to present evidence for poleward propagation of shelf or coastal-trapped waves (CTWs). Wave propagation is seen on the shelf in the 20–40-day, 10–14-day, and 3–5-day-period bands. The lag from south to north indicates that remote forcing is important even at periods as short as 4xa0days. Using QuikSCAT wind data, we show that the contribution of remote forcing to the shelf West Indian Coastal Current (WICC) is significant even when the local alongshore wind is strong, as during the summer-monsoon onset during May–June, and forces a strong local response that masks the effect of remote forcing. Forced wave calculations using CTW theory show that remote forcing of the WICC is present at all times, but is most striking when the local winds are weak, as during March–April. The CTW calculations show that the source region for the remote forcing may extend beyond the west coast into the Gulf of Mannar between India and Sri Lanka. On the slope, propagation is seen only at the 4-day period. At higher periods, the slope WICC decorrelates rapidly along the coast, but upward phase propagation, implying downward propagation of energy associated with poleward propagation, is evident even at these higher periods.

Observed seasonal and intraseasonal variability of the East India Coastal Current on the continental slope.

We present data from three acoustic Doppler current profilers (ADCPs) moored off Cuddalore (12∘N), Kakinada (16.5∘N), and Gopalpur (19∘N) on the continental slope of the western Bay of Bengal and one mooring on the slope of the northern bay (89∘E, 19∘N; referred to as being located at Paradip). The data were collected during May 2009 to March 2013 and the observations show that the seasonal cycle, which includes the annual cycle, the semi-annual cycle, and a peak around 120 days, dominates the observed variability of the East India Coastal Current (EICC). Spectral analysis suggests that the 120-day peak dominates the seasonal variability at Paradip and is strong at Gopalpur and Kakinada. The annual cycle is coherent along the western boundary of the bay, i.e., the east coast of India, but with significant phase differences between moorings. At the semi-annual and 120-day periods, the alongshore coherence is weaker. Intraseasonal variability is weaker than the seasonal cycle, particularly at Cuddalore and Paradip, and it exhibits seasonality: the strongest intraseasonal variation is during spring (February–April). Peaks around 12 and 20–22 days are also seen at Gopalpur, Kakinada, and Cuddalore. A striking feature of the currents is the upward phase propagation, but there are also instances when phase propagates downward. The much lower vertical phase speed in the top ∼100 m at Cuddalore leads to a distinct undercurrent at this location; at other locations, the undercurrent, though it exists often, is not as striking. During spring, however, the EICC tends to flow poleward (eastward) at Cuddalore, Kakinada, and Gopalpur (Paradip) over the top ∼300 m, which is the maximum depth to which observations were made. The cross-shore component of the EICC is much weaker than the alongshore component at Cuddalore and, except for a few bursts during spring, at Kakinada and Gopalpur. It is only at Paradip, on the slope of the northern boundary, that significant cross-shore flows are seen during spring and the summer monsoon (June–August) and these flows are seen to be associated with eddy-like circulations in the altimeter data. We use the ADCP data to validate popular current data products like OSCAR (Ocean Surface Currents Analyses Real-time), ECCO2 (Estimating the Circulation and Climate of the Ocean, Phase II), and GODAS (Global Ocean Data Assimilation System). The OSCAR currents at Paradip match the observed currents well, but the correlation is much weaker at the other three locations. Both ECCO2 and GODAS fair poorly, particularly the latter because its variability in this boundary-current regime is extremely weak. Though it performs badly at Paradip, ECCO2 does capture the observed variability on occasions at the other locations.

Observed intraseasonal and seasonal variability of the West India Coastal Current on the continental slope

We present current data from acoustic Doppler current profilers (ADCPs) moored on the continental slope off the west coast of India. The data were collected at four locations (roughly at Kanyakumari, Kollam, Goa, and Mumbai) extending from ∼ 7° to ∼ 20°N during 2008–2012. The observations show that a seasonal cycle, including an annual cycle, is present in the West India Coastal Current (WICC); this seasonal cycle, which strengthens northward, shows considerable interannual variability and is not as strongly correlated along the coast as in climatologies based on ship drifts or the altimeter. The alongshore decorrelation of the WICC is much stronger at intraseasonal periods, which are evident during the winter monsoon all along the coast. This intraseasonal variability is stronger in the south. A striking feature of the WICC is upward phase propagation, which implies an undercurrent whose depth becomes shallower as the season progresses. There are also instances when the phase propagates downward. At the two southern mooring locations off Kollam and Kanyakumari, the cross-shore current, which is usually associated with eddy-like circulations, is comparable to the alongshore current on occasions. A comparison with data from the OSCAR (Ocean Surface Currents Analyses Real-time) data product shows not only similarities, but also significant differences, particularly in the phase. One possible reason for this phase mismatch between the ADCP current at 48 m and the OSCAR current, which represents the current in the 0–30 m depth range, is the vertical phase propagation. Current products based on Ocean General Circulation Models like ECCO2 (Estimating the Circulation and Climate of the Ocean, Phase II) and GODAS (Global Ocean Data Assimilation System) show a weaker correlation with the ADCP current, and ECCO2 does capture some of the observed variability.

Tidal variations in the Sundarbans Estuarine System, India

Situated in the eastern coastal state of West Bengal, the Sundarbans Estuarine System (SES) is India’s largest monsoonal, macro-tidal delta-front estuarine system. It comprises the southernmost part of the Indian portion of the Ganga–Brahmaputra delta bordering the Bay of Bengal. The Sundarbans Estuarine Programme (SEP), conducted during 18–21 March 2011 (the Equinoctial Spring Phase), was the first comprehensive observational programme undertaken for the systematic monitoring of the tides within the SES. The 30 observation stations, spread over more than 3600xa0km2, covered the seven inner estuaries of the SES (the Saptamukhi, Thakuran, Matla, Bidya, Gomdi, Harinbhanga, and Raimangal) and represented a wide range of estuarine and environmental conditions. At all stations, tidal water levels (every 15xa0minutes), salinity, water and air temperatures (hourly) were measured over the six tidal cycles. We report the observed spatio-temporal variations of the tidal water level. The predominantly semi-diurnal tides were observed to amplify northwards along each estuary, with the highest amplification observed at Canning, situated about 98xa0km north of the seaface on the Matla. The first definite sign of decay of the tide was observed only at Sahebkhali on the Raimangal, 108xa0km north of the seaface. The degree and rates of amplification of the tide over the various estuarine stretches were not uniform and followed a complex pattern. A least-squares harmonic analysis of the data performed with eight constituent bands showed that the amplitude of the semi-diurnal band was an order of magnitude higher than that of the other bands and it doubled from mouth to head. The diurnal band showed no such amplification, but the amplitude of the 6-hourly and 4-hourly bands increased headward by a factor of over 4. Tide curves for several stations displayed a tendency for the formation of double peaks at both high water (HW) and low water (LW). One reason for these double-peaks was the HW/LW stands of the tide observed at these stations. During a stand, the water level changes imperceptibly around high tide and low tide. The existence of a stand at most locations is a key new finding of the SEP. We present an objective criterion for identifying if a stand occurs at a station and show that the water level changed imperceptibly over durations ranging from 30xa0minutes to 2xa0hours during the tidal stands in the SES. The tidal duration asymmetry observed at all stations was modified by the stand. Flow-dominant asymmetry was observed at most locations, with ebb-dominant asymmetry being observed at a few locations over some tidal cycles. The tidal asymmetry and stand have implications for human activity in the Sundarbans. The longer persistence of the high water level around high tide implies that a storm surge is more likely to coincide with the high tide, leading to a greater chance of destruction. Since the stands are associated with an amplification of the 4-hourly and 6-hourly constituents, storm surges that have a similar period are also likely to amplify more during their passage through the SES.

Evidence for the existence of Persian Gulf Water and Red Sea Water in the Bay of Bengal

AbstractnThe high-salinity water masses that originate in the North Indian Ocean are Arabian Sea High-Salinity Water (ASHSW), Persian Gulf Water (PGW), and Red Sea Water (RSW). Among them, only ASHSW has been shown to exist in the Bay of Bengal. We use CTD data from recent cruises to show that PGW and RSW also exist in the bay. The presence of RSW is marked by a deviation of the salinity vertical profile from a fitted curve at depths ranging from 500 to 1000xa0m; this deviation, though small (of the order of ~0.005xa0psu and therefore comparable to the CTD accuracy of 0.003xa0psu), is an order of magnitude larger than the ~0.0003xa0psu fluctuations associated with the background turbulence or instrument noise in this depth regime, allowing us to infer the existence of RSW throughout the bay. PGW is marked by the presence of a salinity maximum at 200–450xa0m; in the southwestern bay, PGW can be distinguished from the salinity maximum due to ASHSW because of the intervening Arabian Sea Salinity Minimum. This salinity minimum and the maximum associated with ASHSW disappear east and north of the south-central bay (85°E, 8°N) owing to mixing between the fresher surface waters that are native to the bay (Bay of Bengal Water or BBW) with the high-salinity ASHSW. Hence, ASHSW is not seen as a distinct water mass in the northern and eastern bay and the maximum salinity over most of the bay is associated with PGW. The surface water over most of the bay is therefore a mixture of ASHSW and the low-salinity BBW. As a corollary, we can also infer that the weak oxygen peak seen within the oxygen-minimum zone in the bay at a depth of 250–400xa0m is associated with PGW. The hydrographic data also show that these three high-salinity water masses are advected into the bay by the Summer Monsoon Current, which is seen to be a deep current extending to 1000xa0m. These deep currents extend into the northern bay as well, providing a mechanism for spreading ASHSW, PGW, and RSW throughout the bay.n

Synthesis, spectroscopic and X-ray structure analyses of two N-[(3′-aryl) prop-2′-ynyl]-N,N′-1,2-phenylene di-p-tosylamides

Two N-substituted phenylene diamines C27H24N2S3O4 (I) and C29H25N2S2O4Cl (II), acyclic precursors leading to quinoxaline derivatives, have been synthesized, and characterized by spectroscopic and X-ray structural studies. The molecules of compounds (I) and (II) are linked through intermolecular N—H···O and C—H···O hydrogen bonds into centrosymmetric dimers, with characteristic R22(14) and R22(26) rings, which combine to form infinite polymeric chains propagating along the [001] direction. Additional intermolecular C—H···O hydrogen bonds connect the molecules of (I) into two-dimensional sheet of R44(32) rings in the ab-plane and one-dimensional C(7) chain propagating along the [100] direction in (II). The combination of two-dimensional sheets in the ab-plane (in I) and one-dimensional C(7) chains along the [100] direction (in II) with the polymeric chains along the [001] direction generates a three-dimensional supramolecular assembly in (I) and a two-dimensional framework in (II).

Numerical simulation of the observed near-surface East India Coastal Current on the continental slope

We simulate the East India Coastal Current (EICC) using two numerical models (resolution

Near-inertial currents off the east coast of India

0.1^{circ } times 0.1^{circ }),