A. Paduan-Filho

Bose-Einstein condensation of S = 1 nickel spin degrees of freedom in NiCl2-4SC(NH2)2.

It has recently been suggested that the organic compound NiCl2-4SC(NH2)2 (DTN) undergoes field-induced Bose-Einstein condensation (BEC) of the Ni spin degrees of freedom. The Ni S = 1 spins exhibit three-dimensional XY antiferromagnetism above a critical field H(c1) approximately 2 T. The spin fluid can be described as a gas of hard-core bosons where the field-induced antiferromagnetic transition corresponds to Bose-Einstein condensation. We have determined the spin Hamiltonian of DTN using inelastic neutron diffraction measurements, and we have studied the high-field phase diagram by means of specific heat and magnetocaloric effect measurements. Our results show that the field-temperature phase boundary approaches a power-law H - H(c1) proportional variant T(alpha)(c) near the quantum critical point, with an exponent that is consistent with the 3D BEC universal value of alpha = 1.5.

Magnetic excitations in the spin-1 anisotropic Heisenberg antiferromagnetic chain system NiCl(2)-4SC(NH(2))(2).

NiCl(2)-4SC(NH(2))(2) (DTN) is a quantum S=1 chain system with strong easy-pane anisotropy and a new candidate for the Bose-Einstein condensation of the spin degrees of freedom. ESR studies of magnetic excitations in DTN in fields up to 25 T are presented. Based on analysis of the single-magnon excitation mode in the high-field spin-polarized phase and previous experimental results [Phys. Rev. Lett. 96, 077204 (2006)10.1103/PhysRevLett.96.077204], a revised set of spin-Hamiltonian parameters is obtained. Our results yield D=8.9 K, J(c) = 2.2 K, and J(a,b) = 0.18 K for the anisotropy, intrachain, and interchain exchange interactions, respectively. These values are used to calculate the antiferromagnetic phase boundary, magnetization, and the frequency-field dependence of two-magnon bound-state excitations predicted by theory and observed in DTN for the first time. Excellent quantitative agreement with experimental data is obtained.

Correction to “2-(4,5,6,7-Tetrafluorobenzimidazol-2-yl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl, A Hydrogen-Bonded Organic Quasi-1D Ferromagnet”

The title radical (F4BImNN) is a stable nitronylnitroxide that forms hydrogen-bonded NH... ON chains in the solid state. The chains assemble the F4BImNN molecules to form stacked contacts between the radical groups, in a geometry that is expected to exhibit ferromagnetic (FM) exchange based on spin polarization (SP) models. The experimental magnetic susceptibility of F4BImNN confirms the expectation, showing 1-D Heisenberg chain FM exchange behavior over 1.8-300 K with an intrachain exchange constant of Jchain/k = +22 K. At lower temperatures, ac magnetic susceptibility and variable field heat capacity measurements show that F4BImNN acts as a quasi-1-D ferromagnet. The dominant ferromagnetic exchange interaction is attributable to overlap between spin orbitals of molecules within the hydrogen-bonded chains, consistent with the SP model expectations. The chains appear to be antiferromagnetically exchange coupled, giving cusps in the ac susceptibility and zero field heat capacity at lower temperatures. The results indicate that the sample orders magnetically at about 0.7 K. The magnetic heat capacity ordering cusp shifts to lower temperatures as external magnetic field increases, consistent with forming a bulk antiferromagnetic phase below a Neel temperature of TN(0) = 0.72 K, with a critical field of Hc approximately 1800 Oe. The interchain exchange is estimated to be zJ/k congruent with (-)0.1 K.

Direct measurement of the Bose-Einstein condensation universality class in NiCl2-4SC(NH2)2 at ultralow temperatures.

In this work, we demonstrate field-induced Bose-Einstein condensation (BEC) in the organic compound NiCl2-4SC(NH2)_{2} using ac susceptibility measurements down to 1 mK. The Ni S=1 spins exhibit 3D XY antiferromagnetism between a lower critical field H_{c1} approximately 2 T and a upper critical field H_{c2} approximately 12 T. The results show a power-law temperature dependence of the phase transition line H_{c1}(T)-H_{c1}(0)=aT;{alpha} with alpha=1.47+/-0.10 and H_{c1}(0)=2.053 T, consistent with the 3D BEC universality class. Near H_{c2}, a kink was found in the phase boundary at approximately 150 mK.

Bose glass and Mott glass of quasiparticles in a doped quantum magnet.

The low-temperature states of bosonic fluids exhibit fundamental quantum effects at the macroscopic scale: the best-known examples are Bose–Einstein condensation and superfluidity, which have been tested experimentally in a variety of different systems. When bosons interact, disorder can destroy condensation, leading to a ‘Bose glass’. This phase has been very elusive in experiments owing to the absence of any broken symmetry and to the simultaneous absence of a finite energy gap in the spectrum. Here we report the observation of a Bose glass of field-induced magnetic quasiparticles in a doped quantum magnet (bromine-doped dichloro-tetrakis-thiourea-nickel, DTN). The physics of DTN in a magnetic field is equivalent to that of a lattice gas of bosons in the grand canonical ensemble; bromine doping introduces disorder into the hopping and interaction strength of the bosons, leading to their localization into a Bose glass down to zero field, where it becomes an incompressible Mott glass. The transition from the Bose glass (corresponding to a gapless spin liquid) to the Bose–Einstein condensate (corresponding to a magnetically ordered phase) is marked by a universal exponent that governs the scaling of the critical temperature with the applied field, in excellent agreement with theoretical predictions. Our study represents a quantitative experimental account of the universal features of disordered bosons in the grand canonical ensemble.

Bose-Einstein condensation in antiferromagnets close to the saturation field

At zero temperature and strong applied magnetic fields the ground state of an anisotropic antiferromagnet is a saturated paramagnet with fully aligned spins. We study the quantum phase transition as the field is reduced below an upper critical

Field‐induced magnetic ordering in uniaxial nickel systems: A second example

{H}_{c2}

Magnetic tuning of all-organic binary alloys between two stable radicals

and the system enters a

Thermal Transport and Strong Mass Renormalization in NiCl(2)-4SC(NH(2))(2)

XY

Loops, chains, sheets, and networks from variable coordination of Cu(hfac)2 with a flexibly hinged aminoxyl radical ligand.

-antiferromagnetic phase. Using a bond operator representation we consider a model spin-1 Heisenberg antiferromagnetic with single-ion anisotropy in hypercubic lattices under strong magnetic fields. We show that the transition at