A. Romani

First evidence of pep solar neutrinos by direct detection in Borexino.

G. Bellini, J. Benziger, D. Bick, S. Bonetti, G. Bonfini, D. Bravo, M. Buizza Avanzini, B. Caccianiga, L. Cadonati, F. Calaprice, C. Carraro, P. Cavalcante, A. Chavarria, D. D’Angelo, S. Davini, A. Derbin, A. Etenko, K. Fomenko, 4 D. Franco, C. Galbiati, S. Gazzana, C. Ghiano, M. Giammarchi, M. Goeger-Neff, A. Goretti, L. Grandi, E. Guardincerri, S. Hardy, Aldo Ianni, Andrea Ianni, D. Korablev, G. Korga, Y. Koshio, D. Kryn, M. Laubenstein, T. Lewke, E. Litvinovich, B. Loer, F. Lombardi, P. Lombardi, L. Ludhova, I. Machulin, S. Manecki, W. Maneschg, G. Manuzio, Q. Meindl, E. Meroni, L. Miramonti, M. Misiaszek, 4 D. Montanari, 7 P. Mosteiro, V. Muratova, L. Oberauer, M. Obolensky, F. Ortica, K. Otis, M. Pallavicini, L. Papp, L. Perasso, S. Perasso, A. Pocar, J. Quirk, R.S. Raghavan, G. Ranucci, A. Razeto, A. Re, A. Romani, A. Sabelnikov, R. Saldanha, C. Salvo, S. Schönert, H. Simgen, M. Skorokhvatov, O. Smirnov, A. Sotnikov, S. Sukhotin, Y. Suvorov, R. Tartaglia, G. Testera, D. Vignaud, R.B. Vogelaar, F. von Feilitzsch, J. Winter, M. Wojcik, A. Wright, M. Wurm, J. Xu, O. Zaimidoroga, S. Zavatarelli, and G. Zuzel

Measurement of the solar 8B neutrino rate with a liquid scintillator target and 3 MeV energy threshold in the Borexino detector

G. Bellini, J. Benziger, S. Bonetti, M. Buizza Avanzini, B. Caccianiga, L. Cadonati, F. Calaprice, C. Carraro, A. Chavarria, A. Chepurnov, F. Dalnoki-Veress, D. D’Angelo, S. Davini, H. de Kerret, A. Derbin, A. Etenko, K. Fomenko, D. Franco, C. Galbiati, S. Gazzana, C. Ghiano, M. Giammarchi, M. Goeger-Neff, A. Goretti, E. Guardincerri, S. Hardy, Aldo Ianni, Andrea Ianni, M. Joyce, G. Korga, D. Kryn, M. Laubenstein, M. Leung, T. Lewke, E. Litvinovich, B. Loer, P. Lombardi, L. Ludhova, I. Machulin, S. Manecki, W. Maneschg, G. Manuzio, Q. Meindl, E. Meroni, L. Miramonti, M. Misiaszek, 11 D. Montanari, V. Muratova, L. Oberauer, M. Obolensky, F. Ortica, M. Pallavicini, L. Papp, L. Perasso, S. Perasso, A. Pocar, R.S. Raghavan, G. Ranucci, A. Razeto, A. Re, P. Risso, A. Romani, D. Rountree, A. Sabelnikov, R. Saldanha, C. Salvo, S. Schönert, H. Simgen, M. Skorokhvatov, O. Smirnov, A. Sotnikov, S. Sukhotin, Y. Suvorov, 9 R. Tartaglia, G. Testera, D. Vignaud, R.B. Vogelaar, F. von Feilitzsch, J. Winter, M. Wojcik, A. Wright, M. Wurm, J. Xu, O. Zaimidoroga, S. Zavatarelli, and G. Zuzel

Observation of Geo{Neutrinos

Geo–neutrinos, electron anti–neutrinos produced in β decays of naturally occurring radioactive isotopes in the Earth, are a unique direct probe of our planet’s interior. We report the first observation at more than 3σ C.L. of geo–neutrinos, performed with the Borexino detector at Laboratori Nazionali del Gran Sasso. Anti–neutrinos are detected through the neutron inverse β decay reaction. With a 252.6 ton·yr fiducial exposure after all selection cuts, we detected 9.9 −3.4( +14.6 −8.2 ) geo–neutrino events, with errors corresponding to a 68.3% (99.73%) C.L. From the lnL profile, the statistical significance of the Borexino geo-neutrino observation corresponds to a 99.997% C.L. Our measurement of the geo–neutrinos rate is 3.9 −1.3( +5.8 −3.2) events/(100 ton·yr). The observed prompt positron spectrum above 2.6 MeV is compatible with that expected from european nuclear reactors (mean base line of approximately 1000 km). Our measurement of reactor anti–neutrinos excludes the non-oscillation hypothesis at 99.60% C.L. This measurement rejects the hypothesis of an active geo-reactor in the Earth’s core with a power above 3 TW at 95% C.L.

A spectrophotometric and fluorimetric study of some anthraquinoid and indigoid colorants used in artistic paintings

Abstract The present study was undertaken to investigate the potential of spectrophotometric and fluorimetric techniques for identifying the materials used in artistic paintings. Two classes of organic colorants were examined, anthraquinoid and indigoid dyes, in their naturally occurring and synthetic forms. Absorption and fluorescence spectra were recorded in both solution and solid layer using linseed oil as a binder. Fluorescence quantum yields were determined. A non-destructive, instrumental set-up to record fluorescence spectra on painted surfaces was successfully tested. The solvent effects on the spectra of the dyes are interpreted in terms of intra- and inter-molecular hydrogen-bonding interactions. Molecular aggregation of indigo was investigated in dichloroethane solution and assigned to a dimer. The spectra recorded from the painted surfaces are broader than in solution. However, the emission spectra are still suitable to identify the colorants.

Acidichromic effects in 1,2‐di‐ and 1,2,4‐tri‐ hydroxyanthraquinones. A spectrophotometric and fluorimetric study

Absorption and fluorescence spectra of alizarin (1,2-dihydroxyanthraquinone) and purpurin (1,2,4-trihydroxyanthraquinone) were investigated as a function of pH in water–dioxane (2:1, v/v) in the pH range 2–14. Absorbance changes with pH are accompanied by color changes; by increasing the pH, the spectra shift to the red. These molecules exhibit fluorescence emissions over the whole pH range explored; fluorescence quantum yields increase with increasing pH and are greater for purpurin (ΦF = 10−3–10−2) than for alizarin (ΦF = 10−4–10−3). The fluorescence lifetimes were measured by the phase-shift technique for the three species derived from purpurin (neutral, τ = 150 ps; mono-anion, τ = 2600 ps and di-anion, τ = 380 ps), and only for the di-anion of alizarin (τ = 80 ps). Both spectrophotometric and fluorimetric titrations gave pKs of the first and second dissociation steps in the ground state. Excited-state pK*s were calculated by the Forster cycle. In the ground state, purpurin (pK1 = 4.7; pK2 = 9.5) is a stronger acid than alizarin (pK1 = 6.6; pK2 = 12.4) in both the first and second dissociation steps; in the excited state, purpurin is a weaker acid in both dissociation steps. Copyright

The exceptional near-infrared luminescence properties of cuprorivaite (Egyptian blue)

Cuprorivaite (CaCuSi(4)O(10), also known as Egyptian blue) exhibits an exceptionally high emission quantum efficiency in the near-infrared region (lambda(max) = 910 nm, Phi(EM) = 10.5%) and a long excited state lifetime (107 mus); these properties make it appealing for several applications in the fields of biomedical analysis, telecommunications and lasers.

Measurement of geo-neutrinos from 1353 days of Borexino

Abstract We present a measurement of the geo-neutrino signal obtained from 1353 days of data with the Borexino detector at Laboratori Nazionali del Gran Sasso in Italy. With a fiducial exposure of ( 3.69 ± 0.16 ) × 10 31 proton × year after all selection cuts and background subtraction, we detected ( 14.3 ± 4.4 ) geo-neutrino events assuming a fixed chondritic mass Th/U ratio of 3.9. This corresponds to a geo-neutrino signal S geo = ( 38.8 ± 12.0 ) TNU with just a 6 × 10 − 6 probability for a null geo-neutrino measurement. With U and Th left as free parameters in the fit, the relative signals are S Th = ( 10.6 ± 12.7 ) TNU and S U = ( 26.5 ± 19.5 ) TNU . Borexino data alone are compatible with a mantle geo-neutrino signal of ( 15.4 ± 12.3 ) TNU , while a combined analysis with the KamLAND data allows to extract a mantle signal of ( 14.1 ± 8.1 ) TNU . Our measurement of 31.2 − 6.1 + 7.0 reactor anti-neutrino events is in agreement with expectations in the presence of neutrino oscillations.

Thermally reversible photoconversion of spiroindoline-naphtho-oxazines to photomerocyanines: a photochemical and kinetic study

Abstract In this paper, a treatment of the spectroscopic data from thermoreversible photochromic systems is described which allows the molar absorption coefficient of the metastable photomerocyanine, the quantum yield of the colour-forming reaction and the kinetic parameters of the thermal bleaching to be determined. The results obtained for five spiroindoline-oxazines indicate that “colourability” on steady state irradiation depends on the photomerocyanine molar absorption coefficient, quantum field and bleaching rate coefficient. For the molecules investigated, the “colourability” markedly depends on temperature, due to the temperature dependence of the bleaching reaction. The results obtained are compared with literature “colourability scales”, determined empirically by comparison of different systems excited by pulsed light.

SOX: Short distance neutrino Oscillations with BoreXino

A bstractThe very low radioactive background of the Borexino detector, its large size, and the well proved capability to detect both low energy electron neutrinos and antineutrinos make an ideal case for the study of short distance neutrino oscillations with artificial sources at Gran Sasso.This paper describes the possible layouts of 51Cr (νe) and 144Ce-144Pr