A. Rühm

Measuring the nematic order of suspensions of colloidal fd virus by x-ray diffraction and optical birefringence

The orientational distribution function of the nematic phase of the semi-flexible rod-like virus fd is measured by x-ray diffraction as a function of concentration and ionic strength. The angular distribution of the scattered intensity from a single-domain nematic phase of fd arises from only the single particle orientational distribution function at high angle but it also includes spatial and orientational correlations at low angle. Experimental measurements of the orientational distribution function from both the interparticle and intraparticle scattering were made to test whether the correlations present in interparticle scatter influence the measurement of the single particle orientational distribution function. It was found that the two types of scatter yield consistent values for the nematic order parameter. It was also found that x-ray diffraction is insensitive to the orientational distribution functions precise form, and the measured angular intensity distribution is described equally well by both Onsagers trial function and a Gaussian. At high ionic strength the order parameter S of the nematic phase coexisting with the isotropic phase approaches theoretical predictions for long semi-flexible rods S=0.55, but deviations from theory increase with decreasing ionic strength. The concentration dependence of the nematic order parameter was also found to better agree with theoretical predictions at high ionic strength, indicating that electrostatic interactions have a measurable effect on the nematic order parameter. The measured x-ray order parameters are also shown to be proportional to the measured birefringence and the saturation birefringence of fd is measured, enabling a simple, inexpensive way to measure the order parameter.

Dedicated Max-Planck beamline for the in situ investigation of interfaces and thin films

A dedicated beamline for the Max-Planck-Institut fur Metallforschung was recently taken into operation at the Angstro/mquelle Karlsruhe (ANKA). Here we describe the layout of the beamline optics and the experimental end-station, consisting of a heavy duty multiple circle diffractometer. For both a new design was realized, combining a maximum flexibility in the beam properties [white, pink, (focused) monochromatic, energy range 6–20 keV] with a special diffractometer for heavy sample environments up to 500 kg, that can be run in different geometrical modes. In addition the angular-reciprocal space transformations for the diffractometer in use are derived, which allows an operation of the instrument in the convenient six circle mode. As an example, results from surface x-ray diffraction on a Cu3Au(111) single crystal are presented.

Magnetic proximity effect in YBa2Cu3O7 / La2/3Ca1/3MnO3 and YBa2Cu3O7 / LaMnO3+δ superlattices

Using neutron reflectometry and resonant x-ray techniques we studied the magnetic proximity effect (MPE) in superlattices composed of superconducting YBa2Cu3O7 and ferromagnetic-metallic La0.67Ca0.33MnO3 or ferromagnetic-insulating LaMnO(3+δ). We find that the MPE strongly depends on the electronic state of the manganite layers, being pronounced for the ferromagnetic-metallic La0.67Ca0.33MnO3 and almost absent for ferromagnetic-insulating LaMnO(3+δ). We also detail the change of the magnetic depth profile due to the MPE and provide evidence for its intrinsic nature.

Spin-resolved off-specular neutron scattering maps from magnetic multilayers using a polarized 3He gas spin filter

We report on the application of the polarized 3He gas spin filter technique for the measurement of spin-polarized diffuse neutron reflectivity with spin analysis. The spin filter together with a one-dimensional position-sensitive detector enables the simultaneous investigation of sections in reciprocal space while exploiting spin sensitivity. An example of diffuse neutron scattering from a Fe/Cr superlattice demonstrates the potential of the method. In addition we present a first step towards the interpretation of diffuse scattering from magnetic multilayers by exploiting the supermatrix formalism.

Depht Profile of the ferromagnetic order in a YBa2Cu3O7/La2/3Ca1/3MnO3 superlattice on a LSAT Substrate :A polarized Neutron reflectometry study

Using polarized neutron reflectometry (PNR) we have investigated a YBa2Cu3O7(10nm)/La2/3Ca1/3MnO3(9nm)]10 (YBCO/LCMO) superlattice grown by pulsed laser deposition on a La0.3Sr0.7Al0.65Ta0.35O3 (LSAT) substrate. Due to the high structural quality of the superlattice and the substrate, the specular reflectivity signal extends with a high signal-to-background ratio beyond the fourth order superlattice Bragg peak. This allows us to obtain more detailed and reliable information about the magnetic depth profile than in previous PNR studies on similar superlattices that were partially impeded by problems related to the low temperature structural transitions of the SrTiO3 substrates. In agreement with the previous reports, our PNR data reveal a strong magnetic proximity effect showing that the depth profile of the magnetic potential differs significantly from the one of the nuclear potential that is given by the YBCO and LCMO layer thickness. We present fits of the PNR data using different simple block-like models for which either a ferromagnetic moment is induced on the YBCO side of the interfaces or the ferromagnetic order is suppressed on the LCMO side. We show that a good agreement with the PNR data and with the average magnetization as obtained from dc magnetization data can only be obtained with the latter model where a so-called depleted layer with a strongly suppressed ferromagnetic moment develops on the LCMO side of the interfaces. The models with an induced ferromagnetic moment on the YBCO side fail to reproduce the details of the higher order superlattice Bragg peaks and yield a wrong magnitude of the average magnetization. We also show that the PNR data are still consistent with the small, ferromagnetic Cu moment of 0.25muB that was previously identified with x-ray magnetic circular dichroism and x-ray resonant magnetic reflectometry measurements on the same superlattice.

Combination of a reflectometer and a nonmagnetic waveguide for experiments with polarized neutron microbeams

Neutron waveguides are three-layer thin-film structures which transform part of a collimated (with an angular divergence of 0.01°) and relatively wide (0.1 mm) incident neutron beam into a narrow (0.1 μm wide) and divergent (0.1°) beam at the output. This submicron beam (which cannot be obtained using conventional focusing elements) is promising for studying nanostructures. We propose a combination of a polarized-neutron reflectometer and a nonmagnetic (independent of the neutron spin) waveguide for experiments employing polarized neutron beams with a submicron spatial resolution. This scheme can be applied, for example, for position-sensitive studies of magnetic nanostructures.

Highly hydrated deformable polyethylene glycol-tethered lipid bilayers.

The realization of a solid-supported lipid bilayer acting as a workbench for the study of membrane processes is a difficult task. For robustness, the bilayer has to be tethered to the substrate. At the same time, diffusion of the lipids and plastic deformations of the membrane should not be obstructed. Furthermore, a highly hydrated surrounding is mandatory. Here, we show that grafting of a polyethylene glycol-lipid construct (PEG2000-DSPE) to a silicon oxide surface via multiple-step silane chemistry and subsequent deposition of lipids by spin-coating result in a cushioned membrane that has the desired properties. Neutron and X-ray reflectometry measurements are combined to access thickness, density, and hydration of the bilayer and the PEG cushion. We observe a spacer of 55 Å thickness between lipid bilayer and silicon-oxide surface with a rather high hydration of up to 90 ± 3% water. While 11.5 ± 3% of the lipids are grafted to the surface, as determined from the neutron data, the diffusion constant of the lipids, as probed by diffusion of 0.5% Texas Red labeled lipids, remains rather large (D = 2.1 ± 0.1 μm(2)/s), which is a reduction of only 12% compared to a supported lipid bilayer reference without immobilized lipids. Finally, AFM indentation confirms the plastic behavior of the membrane against deformation. We show that rupture of the bilayer does not occur before the deformation exceeds 40 Å. Altogether, the presented PEG-tethered lipid bilayer mimics the deformability of natural cell membranes much better than standard solid-supported lipid bilayers.

Experimental determination of the neutron channeling length in a planar waveguide

In neutron waveguides, the neutron wave is confined inside the guiding layer of the structure and can escape from the layer edge as a microbeam. The channeling within the guiding layer is accompanied by an exponential decay of the neutron wave function density inside the waveguide. Here, we report direct determination of the corresponding decay constant, termed the neutron channeling length. For this, we measured the microbeam intensity as a function of the length of a neutron absorbing layer of variable length placed onto the surface of a waveguide structure. Such planar neutron waveguides transform a conventional neutron beam into an extremely narrow but slightly divergent microbeam, which can be used for the investigation of nanostructures with submicron spatial resolution.

A spin-echo resolved grazing incidence scattering setup for the neutron interrogation of buried nanostructures

We present a dedicated experimental spin-echo resolved grazing incidence scattering (SERGIS) setup for the investigation of surfaces and thin films exhibiting large lateral length scales. This technique uses the neutron spin to encode one in-plane component of the wave-vector transfer in a grazing angle scattering experiment. Instead of the scattering angle, the depolarization of the scattered beam is measured. This allows one to achieve a very high in-plane momentum resolution without collimation of the incident neutron beam in the corresponding direction. SERGIS can therefore offer an alternative or complementary method to conventional grazing incidence neutron scattering experiments. We describe the experimental setup installed at the neutron sources ILL (Grenoble) and FRM II (Garching) and present data obtained with this setup on various samples exhibiting characteristic mesoscopic length scales in the range of several hundred nanometers. We also derive general formulas and error margins for the analysis and interpretation of SERGIS data and apply them to the cases of a one-dimensional structure and of an island morphology.

Polarized neutron grazing angle birefrigent diffraction from magnetic stratified media

Abstract Polarized neutron diffraction in multilayers is considered in the framework of the Supermatrix formulation of the distorted wave born approximation (DWBA). The general equations for the polarized neutron scattering cross sections are derived and illustrated by the example of diffraction from the regular ferromagnetic multilayered structure. It is shown that, due to the resonance enhancement of the neutron wave field inside the films, the intensity of birefrigent spin-flip and non-spin-flip diffraction is significantly amplified, if the wavelength is matched with the multilayers period.