A. Wawro

Ablation of organic polymers by 46.9-nm-laser radiation

We report results of the exposure of poly(tetrafluoroethylene) -(PTFE), poly(methyl methacrylate) -(PMMA), and polyimide -(PI) to intense 46.9-nm-laser pulses of 1.2-ns-duration at fluences ranging from ∼0.1 to ∼10J∕cm2. The ablation rates were found to be similar for all three materials, ∼80–90nm∕pulse at 1J∕cm2. The results suggest that the ablation of organic polymers induced by intense extreme ultraviolet laser radiation differs from that corresponding to irradiation with longer wavelengths.

HREELS, STM, and STS study of CH3-terminated Si(111)-(1×1) surface

An ideally (1x1)-CH(3)(methyl)-terminated Si(111) surface was composed by Grignard reaction of photochlorinated Si(111) and the surface structure was for the first time confirmed by Auger electron spectroscopy, low energy electron diffraction, high-resolution electron energy loss spectroscopy (HREELS), scanning tunneling microscopy (STM), and scanning tunneling spectroscopy (STS). HREELS revealed the vibration modes associated to the CH(3)-group as well as the C-Si bond. STM discerned an adlattice with (1x1) periodicity on Si(111) composed of protrusions with internal features, covering all surface terraces. The surface structure was confirmed to be stable at temperatures below 600 K. STS showed that an occupied-state band exists at gap voltage of -1.57 eV, generated by the surface CH(3) adlattice. This CH(3):Si(111)-(1x1) adlayer with high stability and unique electronic property is prospective for applications such as nanoscale lithography and advanced electrochemistry.

Surface structure of 3C‐SiC(111) grown on Si(111) surface by C60 precursor

The surface structure of cubic 3C‐SiC(111) films prepared by thermal reaction of a Si(111) substrate with C60 molecules has been studied by combined in situ measurements of scanning tunneling microscopy and high resolution electron energy loss spectroscopy (HREELS‐STM). The (2×n) surface reconstructions such as (2×2), (2×3) were observed under low reaction temperatures (≤900 °C), and the Si‐terminated SiC(111)‐(3×3) was obtained by annealing the sample at higher temperatures (∼1100 °C). Optical surface phonon energies of 113±2 meV for SiC prepared at low temperatures and 116±2 meV for the films with (3×3) surface reconstruction were measured. The diffusivity of Si atoms from the substrate through the SiC film at various temperatures is suggested as the reason for the formation of different surface reconstructions of the SiC.

Drastic changes of the domain size in an ultrathin magnetic film

A general framework for the domain size in any ultrathin film with perpendicular magnetic anisotropy is here discussed. The domain structure is analyzed by using the classical theory taking into consideration the demagnetization field contribution to the domain wall energy. A sinusoidal model is considered to describe the domain structure while approaching, in two different cases, the monodomain state with in-plane magnetization. The first case is realized applying a large enough in-plane magnetic field. The second one is obtained by decreasing the perpendicular magnetic anisotropy, which is connected in many ultrathin systems with the increase of film thickness. A change in the domain size of several orders of magnitude is obtained while approaching the magnetization reorientation region. The minimal stripe domain period p=8πlex2/d is calculated from the sinusoidal model, where lex is the exchange length and d is the thickness of the film. The range of possible domain size changes in ultrathin films is p...

Irreversible modification of magnetic properties of Pt/Co/Pt ultrathin films by femtosecond laser pulses

Annealing ultrathin Pt/Co/Pt films with single femtosecond laser pulses leads to irreversible spin-reorientation transitions and an amplification of the magneto-optical Kerr rotation. The effect was studied as a function of the Co thickness and the pulse fluence, revealing two-dimensional diagrams of magnetic properties. While increasing the fluence, the creation of two branches of the out-of-plane magnetization state was found.

Magnetic ordering in ultrathin cobalt film covered by an overlayer of noble metals

The spatial distribution of magnetic properties studied by polar Kerr-effect-based magnetometry are carried out on an ultrathin cobalt wedge covered with a silver wedge whose slopes are perpendicular to each other and subsequently capped with a gold layer. The coercivity field was studied as a function of both cobalt thickness d and silver thickness h. A few monolayers of Ag were found to have a substantial influence on the coercivity field. A similar strong influence of silver coverage on the magnetic anisotropy field was observed. Domain structure evolution during magnetization reversal is investigated using an optical microscope. With an increase of the magnetic field, a magnetization reversal process occurs: first by domain nucleation and next by a domain wall movement towards the higher coercivity region of the sample. Changes of the fractal dimension of the domain wall as well as nucleation center density are investigated. A rapid increase of these parameters is observed while d increases towards the value of spin reorientation transition, which goes from easy-axis to easy-plane magnetization. Similar strong changes were observed while decreasing d to the lowest thickness available for observation. The problem discussed here, of tuning magnetic properties by silver–gold structure, is important from both a general physics and an application point of view, especially because of the possibilities for magnetic film patterning.

Observation of C60 film formation on a highly oriented pyrolitic graphite substrate via scanning tunnelling microscopy

We have investigated the early stages in the adsorption process of C60 molecules on a highly oriented pyrolitic graphite (HOPG) substrate. C60 powder was thermally evaporated in UHV of 10−8 Pa conditions onto a freshly cleaved HOPG surface. We did not observe individual fullerenes on the substrate for the case of short deposition times and low evaporation rates. However, small islands of C60 molecules with an fcc structure could be observed when the deposition rate was about 0.2 nm/min and the total thickness was above 1 nm. The islands did not grow in the vicinity of the HOPG steps. The typical lateral dimensions of these islands were of the order of a few hundred square nanometers, having thickness of up to five monolayers. We modified the shapes and positions of these islands by the STM tip, using a small (less than 1 V) bias voltage.

Preparation of an Ultraclean and Atomically Controlled Hydrogen-Terminated Si(111)-(1× 1) Surface Revealed by High Resolution Electron Energy Loss Spectroscopy, Atomic Force Microscopy, and Scanning Tunneling Microscopy: Aqueous NH4F Etching Process of Si(111)

We propose an improved wet chemical process for preparing a high-quality hydrogen-terminated Si(111)-(1× 1) surface and show an atomically ordered and ultraclean surface without carbon and oxygen contamination. The vibrational properties and surface morphology are investigated by high-resolution electron energy loss spectroscopy (HREELS), atomic force microscopy (AFM), and scanning tunneling microscopy (STM). The HREELS spectra and images of AFM and STM reveal the precise aqueous NH4F etching process of Si(111) and indicate the high controllability of steps and terraces at the atomic scale. The surface cleanliness and morphology strongly depend on the etching time. At the etching time of 10 min, we obtain an ultraclean and atomically ordered surface with wide terraces of 36±7 nm step distance. It is confirmed by AFM and STM that 1.0% ammonium sulfite is useful for removing dissolved oxygen in the 40% NH4F etching solution and for preparing a high-quality H:Si(111)-(1× 1) surface with a low density of etch pits. The onset of tunneling current and the gap of 1.39 eV are measured by scanning tunneling spectroscopy. There is no peak at -1.3 eV in comparison with the previous report [Phys. Rev. Lett. 65 (1990) 1917].

Magnetostriction and magnetic anisotropy of FeCo/Au multilayers

Abstract The saturation magnetization, magnetic anisotropy and magnetostriction have been studied in FeCo/Au multilayers prepared by molecular beam epitaxy (MBE). Attention is given to the effect of the surfaces and interfaces on the properties of the studied multilayers. On the basis of these measurements the surface anisotropy and surface magnetostriction constants have been determined.

Ion irradiation induced enhancement of out-of-plane magnetic anisotropy in ultrathin Co films

Ga+ or He+ irradiated MBE grown ultrathin films of sapphire/Pt/Co(dCo)/Pt(dPt) were studied using polar Kerr effect in wide ranges of both cobalt dCo and platinum dPt thicknesses as well as ion fluences F. Two branches of increased magnetic anisotropy and enhanced Kerr rotation angle induced by Ga+ or He+ irradiation are clearly visible in two-dimensional (dCo, LogF) diagrams. Only Ga+ irradiation induces two branches of out-of-plane magnetization state.