Adam C. Maloof

Toward a Neoproterozoic composite carbon-isotope record

Glacial deposits of Sturtian and Marinoan age occur in the well-studied Neoproterozoic successions of northern Namibia, South Australia, and northwestern Canada. In all three regions, the Marinoan glaciation is presaged by a large negative δ 13 C anomaly, and the cap carbonates to both glacial units share a suite of unique sedimentological, stratigraphic, and geochemical features. These global chronostratigraphic markers are the bases of a new correlation scheme for the Neoproterozoic that corroborates radiometric data that indicate that there were three glacial epochs between ca. 750 and 580 Ma. Intraregional correlation of Neoproterozoic successions in the present-day North Atlantic region suggests that glacial diamictite pairs in the Polarisbreen Group in northeastern Svalbard and the Tillite Group in eastern Greenland were deposited during the Marinoan glaciation, whereas the younger of a pair of glacials (Mortensnes Formation) in the Vestertana Group of northern Norway was deposited during the third (Gaskiers) Neoproterozoic glaciation. Gaskiers-aged glacial deposits are neither globally distributed nor overlain by a widespread cap carbonate but are associated with an extremely negative δ 13 C anomaly. framework for a new, high-resolution model carbon-isotope record for the Neoproterozoic comprising new δ 13 C (carbonate) data from Svalbard (Akademikerbreen Group) and Namibia (Otavi Group) and data in the literature from Svalbard, Namibia, and Oman. A new U-Pb zircon age of 760 ± 1 Ma from an ash bed in the Ombombo Subgroup in Namibia provides the oldest direct time-calibration point in the compilation, but the time scale of this preliminary δ 13 C record remains

Probabilistic assessment of sea level during the last interglacial stage

With polar temperatures ∼3–5 °C warmer than today, the last interglacial stage (∼125 kyr ago) serves as a partial analogue for 1–2 °C global warming scenarios. Geological records from several sites indicate that local sea levels during the last interglacial were higher than today, but because local sea levels differ from global sea level, accurately reconstructing past global sea level requires an integrated analysis of globally distributed data sets. Here we present an extensive compilation of local sea level indicators and a statistical approach for estimating global sea level, local sea levels, ice sheet volumes and their associated uncertainties. We find a 95% probability that global sea level peaked at least 6.6 m higher than today during the last interglacial; it is likely (67% probability) to have exceeded 8.0 m but is unlikely (33% probability) to have exceeded 9.4 m. When global sea level was close to its current level (≥-10 m), the millennial average rate of global sea level rise is very likely to have exceeded 5.6 m kyr-1 but is unlikely to have exceeded 9.2 m kyr-1. Our analysis extends previous last interglacial sea level studies by integrating literature observations within a probabilistic framework that accounts for the physics of sea level change. The results highlight the long-term vulnerability of ice sheets to even relatively low levels of sustained global warming.The Last Interglacial (LIG) stage (ca. 130 115 ka), with polar temperatures likely 3 5◦C warmer than today, serves as a partial analogue for low-end future warming scenarios. Multiple indicators suggest that LIG global sea level (GSL) was higher than at present; based upon a small set of local sea level indicators, the Intergovernmental Panel on Climate Change (IPCC)s Fourth Assessment Report inferred an elevation of approximately 4 6 m. While this estimate may be correct, it is based upon overly simplistic assumptions about the relationship between local sea level and global sea level. Sea level is often viewed as a simple function of changing global ice volume. This perspective neglects local variability, which arises from several factors, including the distortion of the geoid and the elastic and isostatic deformation of the solid Earth by shifting ice masses. Accurate reconstruction of past global and local sea levels, as well as ice sheet volumes, therefore requires integrating globally distributed data sets of local sea level indicators. To assess the robustness of the IPCCs global estimate and search for patterns in local sea level that are diagnostic of meltwater sources, we have compiled a comprehensive database that includes a variety of local sea level indicators from 47 localities, as well as a global sea level record derived from oxygen isotopes. We generate a global synthesis from these data using a novel statistical approach that couples Gaussian process regression to Markov Chain Monte Carlo simulation of geochronological errors. Our analysis strongly supports the hypothesis that global sea level during the Last Interglacial was higher than today, probably peaking between 6 9 m above the present level. This level is close to that expected from the complete melting of the Greenland Ice Sheet, or from major melting of both the Greenland and West Antarctic Ice Sheets. In the period when sea level was within 10 m of the modern value, the fastest rate of sea level rise sustained for a 1 ky period was likely about 80 110 cm per century. Combined with the evidence for mildly higher temperatures during the LIG, our results highlight the vulnerability of ice sheets to even relatively low levels of sustained global warming.

Calibrating the Cryogenian

Aging Snowball Earth Earths glacial cycles have varied dramatically over time; at one point glaciers may have covered nearly the entire planet. Correlating various paleoclimate proxies such as fossil and isotope records from that time hinges on the ability to acquire precise age estimates of rocks deposited around the time of this so-called “Snowball Earth.” Macdonald et al. (p. 1241) report new high-precision U-Pb dates of Neoproterozoic strata in the Yukon and Northwest Territories, Canada, to calibrate the timing of carbon isotope variation in rocks from other locations around the globe. Based on the estimated past positions of where these rocks were deposited, glaciers probably extended to equatorial latitudes. The overlap with the survival and, indeed, diversification of some eukaryotes in the fossil record suggests that life survived in localized ecological niches during this global glaciation. A volcanic tuff dated to 716.5 million years ago calibrates the timing of a global glaciation event and eukaryotic survival. The Neoproterozoic was an era of great environmental and biological change, but a paucity of direct and precise age constraints on strata from this time has prevented the complete integration of these records. We present four high-precision U-Pb ages for Neoproterozoic rocks in northwestern Canada that constrain large perturbations in the carbon cycle, a major diversification and depletion in the microfossil record, and the onset of the Sturtian glaciation. A volcanic tuff interbedded with Sturtian glacial deposits, dated at 716.5 million years ago, is synchronous with the age of the Franklin large igneous province and paleomagnetic poles that pin Laurentia to an equatorial position. Ice was therefore grounded below sea level at very low paleolatitudes, which implies that the Sturtian glaciation was global in extent.

The earliest Cambrian record of animals and ocean geochemical change

The Cambrian diversification of animals was long thought to have begun with an explosive phase at the start of the Tommotian Age. Recent stratigraphic discoveries, however, suggest that many taxa appeared in the older Nemakit-Daldynian Age, and that the diversification was more gradual. We map lowest Cambrian (Nemakit-Daldynian through Tommotian) records of δ 13 C CaCO 3 variability from Siberia, Mongolia, and China onto a Moroccan U/Pb–δ 13 C CaCO 3 age model constrained by five U/Pb ages from interbedded volcanic ashes. The δ 13 C CaCO 3 correlations ignore fossil tie points, so we assume synchroneity in δ 13 C trends rather than synchroneity in first appearances of animal taxa. We present new δ 13 C org , 87 Sr/ 86 Sr, uranium, and vanadium data from the same carbonate samples that define the Moroccan δ 13 C CaCO 3 curve. The result is a new absolute time line for first appearances of skeletal animals and for changes in the carbon, strontium, and redox chemistry of the ocean during the Nemakit-Daldynian and Tommotian ages at the beginning of the Cambrian. The time line suggests that the diversification of skeletal animals began early in the Nemakit-Daldynian, with much of the diversity appearing by the middle of the age. Fossil first appearances occurred in three pulses, with a small pulse in the earliest Nemakit-Daldynian (ca. 540–538 Ma), a larger pulse in the mid- to late Nemakit-Daldynian (ca. 534–530 Ma), and a moderate pulse in the Tommotian (ca. 524–522 Ma). These pulses are associated with rapid reorganizations of the carbon cycle, and are superimposed on long-term increases in sea level and the hydrothermal flux of Sr.

Combined paleomagnetic, isotopic, and stratigraphic evidence for true polar wander from the Neoproterozoic Akademikerbreen Group, Svalbard, Norway

We present new paleomagnetic data from three Middle Neoproterozoic carbonate units of East Svalbard, Norway. The paleomagnetic record is gleaned from 50 to 650 m of continuous, platformal carbonate sediment, is reproduced at three locations distributed over >100 km on a single craton, and scores a 5‐6 (out of 7) on the Van der Voo (1990) reliability scale. Two >50° shifts in paleomagnetic direction are coincident with equally abrupt shifts in ! 13 C and transient changes in relative sea level. We explore four possible explanations for these coincidental changes: rapid plate tectonic rotation during depositional hiatus, magnetic excursions, nongeocentric axial-dipole fi elds, and true polar wander. We conclude that the observations are explained most readily by rapid shifts in paleogeography associated with a pair of true polar wander events. Future work in sediments of equivalent age from other basins can test directly the true polar wander hypothesis because this type of event would affect every continent in a predictable manner, depending on the continent’s changing position relative to Earth’s spin axis.

Cryogenian Glaciation and the Onset of Carbon-Isotope Decoupling

A Dip in the Carbon Pool Before the diversity of animal life exploded in the Cambrian, Earths carbon cycle was apparently strongly altered by multiple glaciation events across the globe. Carbon isotope signatures from rocks in Australia measured by Swanson-Hysell et al. (p. 608) suggest that an organic carbon reservoir formed between two global glaciations, or “snowball Earth,” several hundred million years earlier than expected. Anoxic sulfate-limited waters, caused by increased river outputs from melting glaciers, may have prohibited bacterial respiration, allowing for the accumulation of organic carbon. As organic carbon levels dropped, CO2 was released, allowing the atmosphere to warm, preventing further glaciations, and permitting the eventual accumulation of oxygen in the oceans that led to the Cambrian explosion. A large oceanic organic carbon reservoir developed in the period between two global glaciations. Global carbon cycle perturbations throughout Earth history are frequently linked to changing paleogeography, glaciation, ocean oxygenation, and biological innovation. A pronounced carbonate carbon-isotope excursion during the Ediacaran Period (635 to 542 million years ago), accompanied by invariant or decoupled organic carbon-isotope values, has been explained with a model that relies on a large oceanic reservoir of organic carbon. We present carbonate and organic matter carbon-isotope data that demonstrate no decoupling from approximately 820 to 760 million years ago and complete decoupling between the Sturtian and Marinoan glacial events of the Cryogenian Period (approximately 720 to 635 million years ago). Growth of the organic carbon pool may be related to iron-rich and sulfate-poor deep-ocean conditions facilitated by an increase in the Fe:S ratio of the riverine flux after Sturtian glacial removal of a long-lived continental regolith.

An Appalachian Amazon? Magnetofossil evidence for the development of a tropical river‐like system in the mid‐Atlantic United States during the Paleocene‐Eocene thermal maximum

On the mid-Atlantic Coastal Plain of the United States, Paleocene sands and silts are replaced during the Paleocene-Eocene Thermal Maximum (PETM) by the kaolinite-rich Marlboro Clay. The clay preserves abundant magnetite produced by magnetotactic bacteria and novel, presumptively eukaryotic, iron-biomineralizing microorganisms. Using ferromagnetic resonance spectroscopy and electron microscopy, we map the magnetofossil distribution in the context of stratigraphy and carbon isotope data and identify three magnetic facies in the clay: one characterized by a mix of detrital particles and magnetofossils, a second with a higher magnetofossil-to-detrital ratio, and a third with only transient magnetofossils. The distribution of these facies suggests that suboxic conditions promoting magnetofossil production and preservation occurred throughout inner middle neritic sediments of the Salisbury Embayment but extended only transiently to outer neritic sediments and the flanks of the embayment. Such a distribution is consistent with the development of a system resembling a modern tropical river-dominated shelf.

Constraints on early Cambrian carbon cycling from the duration of the Nemakit-Daldynian–Tommotian boundary δ13C shift, Morocco

The Nemakit-Daldynian–Tommotian (ND-T) boundary marks the first appearance of metazoan reefs and calcite biomineralizers and is associated with the largest δ 13 C shift during the Phanerozoic Eon. Biological transitions in Earth history are often accompanied by excursions in the carbon isotopic composition (δ 13 C) of the ocean, where δ 13 C variability is interpreted to reflect changes in the global carbon cycle. The duration and thus rate of these δ 13 C anomalies are rarely known, making it difficult to constrain their possible causes and their relationship, if any, to biologic transitions. We report sedimentological and δ 13 C data from a new 2.5-km-thick section that spans the early Cambrian evolutionary “explosion” in the Moroccan Anti-Atlas Mountains. Three new zircon 206 Pb- 238 U ages from tuffs within the stratigraphy constrain the timing of the ND-T boundary to 524.84 ± 0.09 Ma. Two of the tuffs exactly bracket the ND-T transition and constrain the duration of the −8‰ δ 13 C shift to 506 ± 126 k.y. With a simple box model, we explore a range of geochemical processes that could account for such a rapid ND-T δ 13 C shift, and conclude that metamorphic and/or volcanic fluxes of carbon may have been sustained at levels 4–16 times higher than today for millions of years.

Neoproterozoic sand wedges: crack formation in frozen soils under diurnal forcing during a snowball Earth

Thermal contraction cracking of permafrost produced sand-wedge polygons at sea level on the paleo-equator during late Neoproterozoic glacial episodes. These sand wedges have been used as evidence for high (v 54‡) paleoobliquity of the Earth’s ecliptic, because cracks that form wedges are hypothesized to require deep seasonal cooling so the depth of the stressed layer in the ground reaches v 1 m, similar to the measured depths of cracks that form wedges. To test the counter hypothesis that equatorial cracks opened under a climate characterized by a strong diurnal cycle and low mean annual temperature (snowball Earth conditions), we examine crack formation in frozen ground subject to periodic temperature variations. We derive analytical expressions relating the Newtonian viscosity to the potential crack depth, concluding that cracks will form only in frozen soils with viscosities greater than V10 14 Pa s. We also show numerical calculations of crack growth in frozen soils with stress- and temperature-dependent rheologies and find that fractures may propagate to depths 3^25 times the depth of the thermally stressed layer in equatorial permafrost during a snowball Earth because the mean annual temperature is low enough to keep the ground cold and brittle to relatively great depths. 9 2002 Elsevier Science B.V. All rights reserved.

Geology of Lonar Crater, India

Lonar Crater, India, is one of the youngest and best preserved impact structures on Earth. The 1.88-km-diameter simple crater formed entirely within the Deccan traps, making it a useful analogue for small craters on the basaltic surfaces of the other terrestrial planets and the Moon. In this study, we present a meter-scale–resolution digital elevation model, geological map of Lonar Crater and the surrounding area, and radiocarbon ages for histosols beneath the distal ejecta. Impact-related deformation of the target rock consists of upturned basalt fl ows in the upper crater walls and recumbent folding around rim concentric, subhorizontal, noncylindrical fold axes at the crater rim. The rim-fold hinge is preserved around 10%– 15% of the crater. Although tearing in the rim-fold is inferred from fi eld and paleomagnetic observations, no tear faults are identifi ed, indicating that large displacements in the crater walls are not characteristic of small craters in basalt. One signifi cant normal fault structure is observed in the crater wall that offsets slightly older layer-parallel slip faults. There is little fl uvial erosion of the continuous ejecta blanket. Portions of the ejecta blanket are overlain by aerodynamically and rotationally sculpted glassy impact spherules, in particular in the eastern and western rim, as well as in the depression north of the crater known as Little Lonar. The emplacement of the continuous ejecta blanket can be likened to a radial groundhugging debris fl ow, based on the preserved thickness distribution of the ejecta, the effi cient exchange of clasts between the ejecta fl ow and the underlying histosol, and the lack of sorting and stratifi cation in the bulk of the ejecta. The ejecta profi le is thickened at the distal edge and similar to fl ejecta structures observed on Mars.