Adam J. Benthem

Environmental signatures and effects of an oil and gas wastewater spill in the Williston Basin, North Dakota.

Wastewaters from oil and gas development pose largely unknown risks to environmental resources. In January 2015, 11.4ML (million liters) of wastewater (300g/L TDS) from oil production in the Williston Basin was reported to have leaked from a pipeline, spilling into Blacktail Creek, North Dakota. Geochemical and biological samples were collected in February and June 2015 to identify geochemical signatures of spilled wastewaters as well as biological responses along a 44-km river reach. February water samples had elevated chloride (1030mg/L) and bromide (7.8mg/L) downstream from the spill, compared to upstream levels (11mg/L and <0.4mg/L, respectively). Lithium (0.25mg/L), boron (1.75mg/L) and strontium (7.1mg/L) were present downstream at 5-10 times upstream concentrations. Light hydrocarbon measurements indicated a persistent thermogenic source of methane in the stream. Semi-volatile hydrocarbons indicative of oil were not detected in filtered samples but low levels, including tetramethylbenzenes and di-methylnaphthalenes, were detected in unfiltered water samples downstream from the spill. Labile sediment-bound barium and strontium concentrations (June 2015) were higher downstream from the Spill Site. Radium activities in sediment downstream from the Spill Site were up to 15 times the upstream activities and, combined with Sr isotope ratios, suggest contributions from the pipeline fluid and support the conclusion that elevated concentrations in Blacktail Creek water are from the leaking pipeline. Results from June 2015 demonstrate the persistence of wastewater effects in Blacktail Creek several months after remediation efforts started. Aquatic health effects were observed in June 2015; fish bioassays showed only 2.5% survival at 7.1km downstream from the spill compared to 89% at the upstream reference site. Additional potential biological impacts were indicated by estrogenic inhibition in downstream waters. Our findings demonstrate that environmental signatures from wastewater spills are persistent and create the potential for long-term environmental health effects.

Large wood distribution, mobility, and recruitment in an inter-dam river reach: A comparison with geomorphic process on the Garrison Reach of the Missouri River pre and post the historical 2011 flood: Large wood distribution in an inter-dam river reach

This study assessed the effect of the largest flood since dam regulation on geomorphic and large wood (LW) trends using LW distributions at three time periods on the 150 km long Garrison Reach of the Missouri River. In 2011, a flood exceeded 4390m/s for a two-week period (705% above mean flow; 500 year flood). LW was measured using high resolution satellite imagery in summer 2010 and 2012. Ancillary data including forest character, vegetation cover, lateral bank retreat, and channel capacity. Lateral bank erosion removed approximately 7400 standing trees during the flood. Other mechanisms, that could account for the other two-thirds of the measured in-channel LW, include overland flow through floodplains and islands. LW transport was commonly near or over 100 km as indicated by longitudinal forest and bank loss and post-flood LW distribution. LW concentrations shift at several locations along the river, both preand post-flood, and correspond to geomorphic river regions created by the interaction of the Garrison Dam upstream and the Oahe Dam downstream. Areas near the upstream dam experienced proportionally higher rates of bank erosion and forest loss but in-channel LW decreased, likely due to scouring. A large amount of LW moved during this flood, the chief anchoring mechanism was not bridges or narrow channel reaches but the channel complexity of the river delta created by the downstream reservoir. Areas near the downstream dam experienced bank accretion and large amounts of LW deposition. This study confirms the results of similar work in the Reach: despite a historic flood longitudinal LWand channel trends remain the same. Dam regulation has created a geomorphic and LW pattern that is largely uninterrupted by an unprecedented dam regulation era flood. River managers may require other tools than infrequent high intensity floods to restore geomorphic and LW patterns. Copyright