Adedeji A. Adelodun

Engineered nano particles: Nature, behavior, and effect on the environment

Increased application of engineered nano particles (ENPs) in production of various appliances and consumer items is increasing their presence in the natural environment. Although a wide variety of nano particles (NPs) are ubiquitously dispersed in ecosystems, risk assessment guidelines to describe their ageing, direct exposure, and long-term accumulation characteristics are poorly developed. In this review, we describe what is known about the life cycle of ENPs and their impact on natural systems and examine if there is a cohesive relationship between their transformation processes and bio-accessibility in various food chains. Different environmental stressors influence the fate of these particles in the environment. Composition of solid media, pore size, solution chemistry, mineral composition, presence of natural organic matter, and fluid velocity are some environmental stressors that influence the transformation, transport, and mobility of nano particles. Transformed nano particles can reduce cell viability, growth and morphology, enhance oxidative stress, and damage DNA in living organisms.

Toward a better understanding of the impact of mass transit air pollutants on human health

Globally, modern mass transport systems whether by road, rail, water, or air generate airborne pollutants in both developing and developed nations. Air pollution is the primary human health concern originating from modern transportation, particularly in densely-populated urban areas. This review will specifically focus on the origin and the health impacts of carbonaceous traffic-related air pollutants (TRAP), including particulate matter (PM), volatile organic compounds (VOCs), and elemental carbon (EC). We conclude that the greatest current challenge regarding urban TRAP is understanding and evaluating the human health impacts well enough to set appropriate pollution control measures. Furthermore, we provide a detailed discussion regarding the effects of TRAP on local environments and pedestrian health in low and high traffic-density environments.

Air ionization as a control technology for off-gas emissions of volatile organic compounds

High energy electron-impact ionizers have found applications mainly in industry to reduce off-gas emissions from waste gas streams at low cost and high efficiency because of their ability to oxidize many airborne organic pollutants (e.g., volatile organic compounds (VOCs)) to CO2 and H2O. Applications of air ionizers in indoor air quality management are limited due to poor removal efficiency and production of noxious side products, e.g., ozone (O3). In this paper, we provide a critical evaluation of the pollutant removal performance of air ionizing system through comprehensive review of the literature. In particular, we focus on removal of VOCs and odorants. We also discuss the generation of unwanted air ionization byproducts such as O3, NOx, and VOC oxidation intermediates that limit the use of air-ionizers in indoor air quality management.

Long-term trends in airborne SO2 in an air quality monitoring station in Seoul, Korea, from 1987 to 2013

ABSTRACT Atmospheric concentration of sulfur dioxide (SO2) was intermittently measured at an air quality monitoring (AQM) station in the Yong-san district of Seoul, Korea, between 1987 and 2013. The SO2 level was compared with other important pollutants concurrently measured, including methane (CH4), carbon monoxide (CO), nitric oxide (NO), nitrogen dioxide (NO2), ozone (O3), and particulate matter (PM10). If split into three different periods (period 1, 1987–1988, period 2, 1999–2000, and period 3, 2004–2013), the respective mean [SO2] values (6.57 ± 4.29, 6.30 ± 2.44, and 5.29 ± 0.63 ppb) showed a slight reduction across the entire study period. The concentrations of SO2 are found to be strongly correlated with other pollutants such as CO (r = 0.614, p = 0.02), which tracked reductions in reported emissions due to tighter emissions standards enacted by the South Korean government. There was also a clear seasonal trend in the SO2 level, especially in periods 2 and 3, reflecting the combined effects of domestic heating by coal briquettes and meteorological conditions. Although only a 16% concentration reduction was achieved during the 27-year study duration, this is significant if one considers rapid urbanization, an 83.2% increase in population, and rapid industrialization that took place during that period. Implications: Since 1970, a network of air quality monitoring (AQM) stations has been operated by the Korean Ministry of Environment (KMOE) for routine nationwide monitoring of air pollutant concentrations in urban/suburban areas. To date, the information obtained from these stations has provided a platform for analyzing long-term trends of major pollutant species. In this study, we examined the long-term trends of SO2 levels and relevant environmental parameters monitored continuously in the Yong-san district of Seoul between 1987 and 2013. The data were analyzed over various time scales (i.e., monthly, seasonal, and annual intervals). The results obtained from this study will allow us to assess the effectiveness of abatement strategy and to predict future concentrations trends in association with future abatement strategies and technologies.

Adsorption of Low-level CO 2 using Activated Carbon Pellet with Glycine Metal Salt Impregnation

Abstract The present study has evaluated the CO 2 adsorption amount of activated carbon pellets (AC). Coconut shellbased test AC were modi Þ ed with surface impregnation of glycine, glycine metal salts and monoethanolamine forlow level CO 2 (3000ppm) adsorption. Physical and chemical properties of prepared adsorbents were analyzed andthe adsorbed amount of CO 2 was investigated by using pure and 3,000ppm CO 2 levels. The impregnation of nitro-gen functionalities was veri Þ ed by XPS analysis. The adsorption capacity for pure CO 2 gas was found to reach upto3.08mmol/g by AC -LiG(Activated carbon -Lithium glycinate), which has the largest speci Þ c surface area(1026.9m 2 /g). As for low level CO 2 s ow the primary amine impregnated adsorbent showed 0.26 mmol/g of adsorptionamount, indicating the highest selectivity. An adsorbent with potassium -glycine salts(AC -KG, Activated carbon -Potassium glycinate) instead of amine presented with 0.12mmol/g of adsorption capacity, which was higher thanthat of raw activated carbon granules(0.016mmol/g). Key words : CO