Adi Salomon

Bio-inspired Photocatalytic Ruthenium Complexes: Synthesis, Optical Properties, and Solvatochromic Effect

We report the synthesis, characterization, and photo-physical properties of two new rutheniumII -phenol-imidazole complexes. These bio-mimetic complexes have potential as photocatalysts for water splitting. Owing to their multiple phenol-imidazole groups, they have a higher probability of light-induced radical formation than existing complexes. The newly synthesized complexes show improved overlap with the solar spectrum compared to other rutheniumII -phenol-imidazole complexes, and their measured lifetimes are suitable for light-induced radical formation. In addition, we conducted solvatochromic absorption measurements, which elegantly follow Marcus theory, and demonstrate the symmetry differences between the two complexes. The solvatochromic measurements further imply electron localization onto one of the ligands. The new complexes may find applications in photocatalysis, dye-sensitized solar cells, biomedicine, and sensing. Moreover, their multiple chelating units make them promising candidates for light-activated metal organic radical frameworks, i.e. metal-organic frameworks that contain organic radicals activated by light.

Nanoporous Metallic Networks: Fabrication, Optical Properties, and Applications

Nanoporous metallic networks are a group of porous materials made of solid metals with suboptical wavelength sizes of both particles and voids. They are characterized by unique optical properties, as well as high surface area and permeability of guest materials. As such, they attract a great focus as novel materials for photonics, catalysis, sensing, and renewable energy. Their properties together with the ability for scaling-up evoke an increased interest also in the industrial field. Here, fabrication techniques of large-scale metallic networks are discussed, and their interesting optical properties as well as their applications are considered. In particular, the focus is on disordered systems, which may facilitate the fabrication technique, yet, endow the three-dimensional (3D) network with distinct optical properties. These metallic networks bridge the nanoworld into the macroscopic world, and therefore pave the way to the fabrication of innovative materials with unique optoelectronic properties.

Secondary Electron Cloaking with Broadband Plasmonic Resonant Absorbers

Scanning electron microscopy (SEM) is one of the most powerful tools for nanoscale inspection and imaging. It is broadly used for biomedicine, materials science, and nanotechnology, enabling spatial resolution beyond the optical diffraction limit. In SEM, a high-energy electron beam illuminates a specimen, and the emitted secondary electrons are routed to a positively biased, synchronized detector for image creation. Here, for the first time, we experimentally demonstrate a cloaking of metallic objects from a secondary electron image. We make a metallic disc with a diameter of 300 nm almost invisible to a secondary electron detector with <5 nm spatial resolution. The secondary electron cloaking is based on broadband optical radiation absorption in the near field. Our secondary electron images are in good agreement with full-wave numerical solution of Maxwells equations at optical frequencies, confirming the concept of secondary electron cloaking based on broadband optical radiation absorption.