Adio Miliozzi

Effect of nanoparticles on heat capacity of nanofluids based on molten salts as PCM for thermal energy storage

In this study, different nanofluids with phase change behavior were developed by mixing a molten salt base fluid (selected as phase change material) with nanoparticles using the direct-synthesis method. The thermal properties of the nanofluids obtained were investigated. These nanofluids can be used in concentrating solar plants with a reduction of storage material if an improvement in the specific heat is achieved. The base salt mixture was a NaNO3-KNO3 (60:40 ratio) binary salt. The nanoparticles used were silica (SiO2), alumina (Al2O3), titania (TiO2), and a mix of silica-alumina (SiO2-Al2O3). Three weight fractions were evaluated: 0.5, 1.0, and 1.5 wt.%. Each nanofluid was prepared in water solution, sonicated, and evaporated. Measurements on thermophysical properties were performed by differential scanning calorimetry analysis and the dispersion of the nanoparticles was analyzed by scanning electron microscopy (SEM). The results obtained show that the addition of 1.0 wt.% of nanoparticles to the base salt increases the specific heat of 15% to 57% in the solid phase and of 1% to 22% in the liquid phase. In particular, this research shows that the addition of silica-alumina nanoparticles has a significant potential for enhancing the thermal storage characteristics of the NaNO3-KNO3 binary salt. These results deviated from the predictions of the theoretical model used. SEM suggests a greater interaction between these nanoparticles and the salt.

Thermal‐fluid flow within innovative heat storage concrete systems for solar power plants

Purpose – The purpose of this paper is to describe an experience of R&D in the field of new technologies for solar energy exploitation within the Italian context. Concentrated solar power systems operating in the field of medium temperatures are the main research objectives, directed towards the development of a new and low‐cost technology to concentrate the direct radiation and efficiently convert solar energy into high‐temperature heat.Design/methodology/approach – A multi‐tank sensible‐heat storage system is proposed for storing thermal energy, with a two‐tanks molten salt system. In the present paper, the typology of a below‐grade cone shape storage is taken up, in combination with nitrate molten salts at 565°C maximum temperature, using an innovative high‐performance concrete for structures absolving functions of containment and foundation.Findings – Concrete durability in terms of prolonged thermal loads is assessed. The interaction between the hot tank and the surrounding environment (ground) is co...

New Trends in Designing Parabolic trough Solar Concentrators and Heat Storage Concrete Systems in Solar Power Plants

Energy availability has always been an essential component of human civilization and the energetic consumption is directly linked to the produced wealth. In many depressed countries the level of solar radiation is considerably high and it could be the primary energy source under conditions that low cost, simple-to-be-used technologies are employed. Then, it is responsibility of the most advanced countries to develop new equipments to allow this progress for taking place. A large part of the energetic forecast, based on economic projection for the next decades, ensure us that fossil fuel supplies will be largely enough to cover the demand. The predicted and consistent increase in the energetic demand will be more and more covered by a larger use of fossil fuels, without great technology innovations. A series of worrying consequences are involved in the above scenario: important climatic changes are linked to strong CO2 emissions; sustainable development is hindered by some problems linked to certainty of oil and natural gas supply; problems of global poverty are not solved but amplified by the unavoidable increase in fossil fuel prices caused by an increase in demand. These negative aspects can be avoided only if a really innovative and more acceptable technology will be available in the next decades at a suitable level to impress a substantial effect on the society. Solar energy is the ideal candidate to break this vicious circle between economic progress and consequent greenhouse effect. The low penetration on the market shown today by the existent renewable technologies, solar energy included, is explained by well-known reasons: the still high costs of the produced energy and the “discontinuity” of both solar and wind energies. These limitations must be removed in reasonable short times, with the support of innovative technologies, in view of such an urgent scenario. On this purpose ENEA, on the basis of the Italian law n. 388/2000, has started an R&D program addressed to the development of CSP (Concentrated Solar Power) systems able to take advantage of solar energy as heat source at high temperature. One of the most relevant objectives of this research program (Rubbia, 2001) is the study of CSP systems operating in the field of medium temperatures (about 550°C), directed towards the development of a new and low-cost technology to concentrate the direct radiation and efficiently convert solar

Hybrid solar-biomass combined Brayton/organic Rankine-cycle plants integrated with thermal storage: Techno-economic feasibility in selected Mediterranean areas

This paper presents the thermodynamic analysis and techno-economic assessment of a novel hybrid biomass-solar combined-cycle system configuration composed of an externally fired gas-turbine (EFGT) fuelled by biomass (wood chips) and a bottoming organic Rankine cycle (ORC) plant. The main novelty arises from the consideration of heat recovery from the exhaust gases of the EFGT via the use of thermal energy storage (TES), with the thermal energy store also receiving heat from a field of parabolic-trough collectors (PTCs) with molten salts used as a heat-transfer fluid (HTF), adopting the ENEA technology of the Archimede project. The presence of TES between the topping and bottoming cycles facilitates the flexible operation of the system, allows the system to compensate for solar energy input fluctuations, and increases capacity factor and dispatchability. A TES with two molten salt tanks (one cold at 200 °C and one hot at 370 °C) is chosen. The selected bottoming ORC is a superheated recuperative cycle suitable for heat conversion in the operating temperature range of the TES with good cycle efficiency. The whole system is modelled by means of a Python-based software code, and three locations in the Mediterranean area are used in order to perform energy-yield analyses: Marseille in France, Priolo Gargallo in Italy and Rabat in Morocco. In each case, the thermal store that minimizes the levelized cost of energy (LCE) is selected on the basis of the estimated solar radiation and CSP size. The results of the thermodynamic simulations, capital and operational costs assessments and subsidies (feed-in tariffs for biomass and solar electricity available in the Italian framework), allow estimates of the global energy conversion efficiency and investment profitability in the three locations. Sensitivity analyses on the biomass costs, size of PTCs, feed-in tariff and share of cogenerated heat delivered to the load are also performed. The results show that the high investment costs of CSP in the proposed size range and hybridization configuration allow investment profitability only in the presence of a dedicated subsidy framework such as the one available in the Italian energy market. In particular, the LCE of the proposed system is around 140 Eur/MWh (with the option to discharge the cogenerated heat) and the IRR is around 15%, based on the Italian electricity subsidy tariffs. The recovery of otherwise discharged heat to match thermal energy demand can significantly increase the investment profitability and compensate the high investment costs of the proposed technology.