Ais Kemp

Episodic growth of the Gondwana supercontinent from hafnium and oxygen isotopes in zircon

It is thought that continental crust existed as early as 150 million years after planetary accretion, but assessing the rates and processes of subsequent crustal growth requires linking the apparently contradictory information from the igneous and sedimentary rock records. For example, the striking global peaks in juvenile igneous activity 2.7, 1.9 and 1.2 Gyr ago imply rapid crustal generation in response to the emplacement of mantle ‘super-plumes’, rather than by the continuous process of subduction. Yet uncertainties persist over whether these age peaks are artefacts of selective preservation, and over how to reconcile episodic crust formation with the smooth crustal evolution curves inferred from neodymium isotope variations of sedimentary rocks. Detrital zircons encapsulate a more representative record of igneous events than the exposed geology and their hafnium isotope ratios reflect the time since the source of the parental magmas separated from the mantle. These ‘model’ ages are only meaningful if the host magma lacked a mixed or sedimentary source component, but the latter can be diagnosed by oxygen isotopes, which are strongly fractionated by rock-hydrosphere interactions. Here we report the first study that integrates hafnium and oxygen isotopes, all measured in situ on the same, precisely dated detrital zircon grains. The data reveal that crust generation in part of Gondwana was limited to major pulses at 1.9 and 3.3 Gyr ago, and that the zircons crystallized during repeated reworking of crust formed at these times. The implication is that the mechanisms of crust formation differed from those of crustal differentiation in ancient orogenic belts.

The generation and evolution of the continental crust

Abstract: The continental crust is the archive of the geological history of the Earth. Only 7% of the crust is older than 2.5 Ga, and yet significantly more crust was generated before 2.5 Ga than subsequently. Zircons offer robust records of the magmatic and crust-forming events preserved in the continental crust. They yield marked peaks of ages of crystallization and of crust formation. The latter might reflect periods of high rates of crust generation, and as such be due to magmatism associated with deep-seated mantle plumes. Alternatively the peaks are artefacts of preservation, they mark the times of supercontinent formation, and magmas generated in some tectonic settings may be preferentially preserved. There is increasing evidence that depletion of the upper mantle was in response to early planetary differentiation events. Arguments in favour of large volumes of continental crust before the end of the Archaean, and the thickness of felsic and mafic crust, therefore rely on thermal models for the progressively cooling Earth. They are consistent with recent estimates that the rates of crust generation and destruction along modern subduction zones are strikingly similar. The implication is that the present volume of continental crust was established 2–3 Ga ago.

Evolution of the continental crust

The continental crust covers nearly a third of the Earth’s surface. It is buoyant—being less dense than the crust under the surrounding oceans—and is compositionally evolved, dominating the Earth’s budget for those elements that preferentially partition into silicate liquid during mantle melting. Models for the differentiation of the continental crust can provide insights into how and when it was formed, and can be used to show that the composition of the basaltic protolith to the continental crust is similar to that of the average lower crust. From the late Archaean to late Proterozoic eras (some 3–1 billion years ago), much of the continental crust appears to have been generated in pulses of relatively rapid growth. Reconciling the sedimentary and igneous records for crustal evolution indicates that it may take up to one billion years for new crust to dominate the sedimentary record. Combining models for the differentiation of the crust and the residence time of elements in the upper crust indicates that the average rate of crust formation is some 2–3 times higher than most previous estimates.

Granitic perspectives on the generation and secular evolution of the continental crust

Every geologist is acquainted with the principle of “uniformitarianism,” which holds that present-day processes are the key to those that operated in the past. But the extent this applies to the processes driving the growth and differentiation of the Earths continental crust remains a matter of debate. Unlike its dense oceanic counterpart, which is recycled back into the mantle by subduction within 200 Ma, the continental crust comprises buoyant quartzofeldspathic materials and is difficult to destroy by subduction. The continental crust is, therefore, the principal record of how conditions on the Earth have changed, and how processes of crust generation have evolved through geological time. It preserves evidence of secular variation in crustal compositions, and thus the way in which the crust has formed throughout Earths history. Exploring the nature and origin of these variations is the focus of this chapter.

The chemical analysis of rock powders by automatic X-ray fluorescence

Abstract This account presents detailed calibrations which can be used in other laboratories for the ultra-rapid X-ray chemical analysis of rock powders for 38 major and trace elements. The major element calibrations are based on 16,000 measurements on about 400 previously analysed rocks and working equations are given for rhyolites, granodiorites, granites etc., amphibolites, basalts, dolerites, pelites, semipelites, carbonate-rocks, and psammites. Trace elements have been calibrated by spiking nine carefully analysed rocks with 1,500 different amounts of added spectrographically pure chemicals. All the calibrations have been computer-calculated and are given in terms of ratios of counts relative to one rock, an amphibolite, which is available for general distribution and thus enables other laboratories to use the calibrations. By this ratio technique very high precision has been obtained. The results of extensive investigations into the optimum conditions for the determination of the 38 elements as regards X-ray tubes (Cr, W or Mo); kV and mA; analysing crystals; peak and background positions; counters etc. are summarised in tables. A new specimen preparation technique enables all elements above F to be determined on one permanent rock pellet which is 86% rock, 14% binder. Detection limits are generally low for an X-ray technique, being 0.02% for MgO, 0.05% for Na 2 O and below 10 p.p.m. for all elements above Cl in atomic number. Mass absorption corrections are applied in a novel way that is independent of international rock standards. It is shown, however, that for major oxides, mass absorption corrections are negligible within fairly wide ranges of a few rock types and are trivial compared with other effects, including mineralogy and pellet variation. It is demonstrated that octahedral and tetrahedrally-coordinated alumina give rise to different alumina calibrations and this effect is, for alumina, more significant than mass absorption effects, within the common range of rock compositions. Precision and accuracy are evaluated by a most extensive series of checks and statistical treatment of the data. The accuracy varies from extremely good (e.g., TiO 2 , K 2 O, Rb and Sr) to poor (S and P 2 O 5 ) but overall the moderate accuracy and high speed justify the use of the method for serial analyses and element variation maps. Some 1,550 rocks have each been analysed for 23 elements in nine months.

Hafnium isotope evidence for a transition in the dynamics of continental growth 3.2 Gyr ago.

Earth’s lithosphere probably experienced an evolution towards the modern plate tectonic regime, owing to secular changes in mantle temperature. Radiogenic isotope variations are interpreted as evidence for the declining rates of continental crustal growth over time, with some estimates suggesting that over 70% of the present continental crustal reservoir was extracted by the end of the Archaean eon. Patterns of crustal growth and reworking in rocks younger than three billion years (Gyr) are thought to reflect the assembly and break-up of supercontinents by Wilson cycle processes and mark an important change in lithosphere dynamics. In southern West Greenland numerous studies have, however, argued for subduction settings and crust growth by arc accretion back to 3.8 Gyr ago, suggesting that modern-day tectonic regimes operated during the formation of the earliest crustal rock record. Here we report in situ uranium–lead, hafnium and oxygen isotope data from zircons of basement rocks in southern West Greenland across the critical time period during which modern-like tectonic regimes could have initiated. Our data show pronounced differences in the hafnium isotope–time patterns across this interval, requiring changes in the characteristics of the magmatic protolith. The observations suggest that 3.9–3.5-Gyr-old rocks differentiated from a >3.9-Gyr-old source reservoir with a chondritic to slightly depleted hafnium isotope composition. In contrast, rocks formed after 3.2 Gyr ago register the first additions of juvenile depleted material (that is, new mantle-derived crust) since 3.9 Gyr ago, and are characterized by striking shifts in hafnium isotope ratios similar to those shown by Phanerozoic subduction-related orogens. These data suggest a transitional period 3.5–3.2 Gyr ago from an ancient (3.9–3.5 Gyr old) crustal evolutionary regime unlike that of modern plate tectonics to a geodynamic setting after 3.2 Gyr ago that involved juvenile crust generation by plate tectonic processes.

Hf isotopes in zircon reveal contrasting sources and crystallization histories for alkaline to peralkaline granites of Temora, southeastern Australia

Peralkaline granites exhibit the hallmark features of A-type igneous rocks, but strongly differentiated chemistry and intense hydrothermal alteration camouflage their ultimate origins. We present the first in situ Hf isotope data from zircons of peralkaline granites, aimed at clarifying the protoliths of these plutons and their genetic relationship to associated metaluminous/weakly peraluminous granites. This study used rocks of the Devonian Narraburra Complex in southeastern Australia, and found that correlations between Hf isotopes and trace element ratios reveal fundamentally different origins for the nonperalkaline and peralkaline granites. The latter have a depleted mantle-like ancestry, whereas a weakly peraluminous rock formed from melts of older arc crust that were modified by interaction with juvenile, probably alkaline magmas. Juxtaposition of crust- and mantle-derived magmas reflects the high heat flow and lithosphere-scale faults associated with continental extension, and explains the diversity of A-type granites.

Episodic, mafic crust formation from 4.5 to 2.8 Ga: New evidence from detrital zircons, Slave craton, Canada

The ϵHf and δ18O values in detrital zircons from the Slave craton, Canada, indicate three episodes of crust formation between ca. 4.5 and 2.8 Ga, namely at ca. 4.4–4.5 Ga, ca. 3.8 Ga, and ca. 3.4 Ga. Most of the juvenile crust appears to have been mafic in composition, and there is no clear evidence for initial granitic protocrust in the Hadean of the Slave craton. The range of initial ϵHf values in zircons increases from 3.9 to 2.8 Ga, indicating that both extraction of new material from mantle and reworking of the older crust are important for the secular evolution of the continental crust. A preliminary review of available Hf data in zircons suggests that the three episodes of crust generation may have been of global importance. The mafic crust formed in the Archean and the Hadean was then reworked for at least ~0.5–1.5 b.y., as indicated by data from the Slave craton, Gondwana, and the Limpopo Belt of Africa.

Exploring the plutonic–volcanic link: a zircon U–Pb, Lu–Hf and O isotope study of paired volcanic and granitic units from southeastern Australia

The relationship between plutonic and volcanic rocks is central to understanding the geochemical evolution of silicic magma systems, but it is clouded by ambiguities associated with unravelling the plutonic record. Here we report an integrated U–Pb, O and Lu–Hf isotope study of zircons from three putative granitic–volcanic rock pairs from the Lachlan Fold Belt, southeastern Australia, to explore the connection between the intrusive and extrusive realms. The data reveal contrasting petrogenetic scenarios for the S- and I-type pairs. The zircon Hf–O isotope systematics in an I-type dacite are very similar to those of their plutonic counterpart, supporting an essentially co-magmatic relationship between these units. The elevated δ18O of zircons in these I-type rocks confirm a significant supracrustal source component. The S-type volcanic rocks are not the simple erupted equivalents of the granites, although the extrusive and plutonic units can be related by open-system magmatic evolution. Zircons in the S-type rocks define covariant eHf–δ18O arrays that attest to mixing or assimilation processes between two components, one being the Ordovician metasedimentary country rocks, the other either an I-type magma or a mantle-derived magma. The data are consistent with models involving incremental melt extraction from relatively juvenile magmas undergoing open-system differentiation at depth, followed by crystal-liquid mixing upon emplacement in shallow magma reservoirs, or upon eruption. The latter juxtaposes crystals with markedly different petrogenetic histories and determines whole-rock geochemical and textural properties. This scenario can explain the puzzling decoupling between the bulk rock isotope and geochemical compositions commonly observed for granite suites.

Linking granulites, silicic magmatism, and crustal growth in arcs: Ion microprobe (zircon) U-Pb ages from the Hidaka metamorphic belt, Japan

There is no consensus as to how the extreme metamorphic conditions required to form granulites are attained, or how these rocks relate to crustal growth and differentiation processes. Studying young granulites offers two advantages: the tectonic setting is likely to be well constrained, and the ambiguities that result from overprinting by younger metamorphic events are potentially avoided. We report the first ion microprobe U-Pb (zircon) ages for orthopyroxene-bearing granulites, tonalites, and gabbros of the Cenozoic Hidaka metamorphic belt (Hokkaido, Japan) to clarify the magmatic-metamorphic connection in this area. The data support a two-stage evolution for this terrane, which is attributed to episodes of supra-subduction zone magmatism (late Eocene) and back-arc extension (early Miocene). We relate granulite facies metamorphism and garnet-orthopyroxene tonalite generation to mafic magma under-accretion and lithosphere thinning due to the opening of the Japan Sea at 19 Ma. The Hidaka granulites are thus among the youngest exposed granulites on Earth, and manifest the thermal response to continental growth.