Ajay Katiyar

Superior dielectric breakdown strength of graphene and carbon nanotube infused nano-oils

Nano-oils comprising stable and dilute dispersions of synthesized Graphene (Gr) nanoflakes and carbon nanotubes (CNT) have been experimentally observed for the first time to exhibit augmented dielectric breakdown strengths compared to the base transformer oils. Variant nano-oils comprising different Gr and CNT samples suspended in two different grades of transformer oils have yielded consistent and high degrees of enhancement in the breakdown strength. The apparent counter-intuitive phenomenon of enhancing insulating caliber of fluids utilizing nanostructures of high electronic conductance has been shown to be physically consistent thorough theoretical analysis. The crux mechanism has been pin pointed as efficient charge scavenging leading to hampered streamer growth and development, thereby delaying probability of complete ionization. The mathematical analysis presented provides a comprehensive picture of the mechanisms and physics of the electrohydrodynamics involved in the phenomena of enhanced breakdown strengths. Furthermore, the analysis is able to physically explain the various breakdown characteristics observed as functions of system parameters, viz. nanostructure type, size distribution, relative permittivity, base fluid dielectric properties, nanomaterial concentration and nano-oil temperature. The mathematical analyses have been extended to propose a physically and dimensionally consistent analytical model to predict the enhanced breakdown strengths of such nano-oils from involved constituent material properties and characteristics. The model has been observed to accurately predict the augmented insulating property, thereby rendering it as an extremely useful tool for efficient design and prediction of breakdown characteristics of nanostructure infused insulating fluids. The present study, involving experimental investigations backed by theoretical analyses and models for an important dielectric phenomenon such as electrical breakdown can find utility in design of safer and more efficient high operating voltage electrical drives, transformers and machines.

Large electrorheological phenomena in graphene nano-gels

Large-scale electrorheology (ER) response has been reported for dilute graphene nanoflake-based ER fluids that have been engineered as novel, readily synthesizable polymeric gels. Polyethylene glycol (PEG 400) based graphene gels have been synthesized and a very high ER response (∼125 000% enhancement in viscosity under influence of an electric field) has been observed for low concentration systems (∼2 wt.%). The gels overcome several drawbacks innate to ER fluids. The gels exhibit long term stability, a high graphene packing ratio which ensures very high ER response, and the microstructure of the gels ensures that fibrillation of the graphene nanoflakes under an electric field is undisturbed by thermal fluctuations, further leading to mega ER. The gels exhibit a large yield stress handling caliber with a yield stress observed as high as ∼13 kPa at 2 wt.% for graphene. Detailed investigations on the effects of graphene concentration, electric field strength, imposed shear resistance, transients of electric field actuation on the ER response and ER hysteresis of the gels have been performed. In-depth analyses with explanations have been provided for the observations and effects, such as inter flake lubrication/slip induced augmented ER response. The present gels show great promise as potential ER gels for various smart applications.

Smart viscoelastic and self-healing characteristics of graphene nano-gels

Readily synthesizable nano-graphene and poly ethylene glycol based stable gels have been synthesized employing an easy refluxing method, and exhaustive rheological and viscoelastic characterizations have been performed to understand the nature of such complex gel systems. The gels exhibit shear thinning response with pronounced yield stress values which is indicative of a microstructure, where the graphene nanoflakes intercalate (possible due to the refluxing) with the polymer chains and form a pseudo spring damper network. Experimentations on the thixotropic behavior of the gels indicate that the presence of the G nanoflakes leads to immensely augmented structural stability capable of withstanding severe impact shears. Further information about the localized interactions of the G nanoflakes with the polymer chains is revealed from the amplitude and frequency sweep analyses in both linear and non-linear viscoelastic regimes. Massively enhanced cross over amplitude values are recorded and several smart eff...

Enhanced breakdown performance of Anatase and Rutile titania based nano-oils

Nano-oils synthesized by dispersing dielectric nanostructures counter common intuition as such nano-oils possess substantially higher positive dielectric breakdown voltage with reduced streamer velocities than the base oils. Nano-oils comprising stable and dilute homogeneous dispersions of two forms of titanium (IV) oxide (TiO2) nanoparticles (Anatase and Rutile) have been experimentally examined and observed to exhibit highly enhanced dielectric breakdown strength compared to the conventional transformer oils. The present study involves titania dispersed in two different grades of transformer oils, both with varied levels of thermal treatment, to obtain consistent and high degrees of enhancement in the breakdown strength, as well as high degrees of increment in the survival of the oils at elevated electrical stressing compared to the base oils, as obtained via detailed twin parameter Weibull distribution analysis of the experimental observations. The experimental results demonstrate higher augmented breakdown strength for Anatase compared to the Rutile phase of titania. In-depth survey of literature indicates that mostly Rutile based oils are used. However, the present study shows that they exhibit relatively less breakdown strength enhancement compared to the Anatase based oils. It is also observed that heat treatment of the nano-oils further enhances the dielectric breakdown performance. The differences in the performance of Anatase and Rutile has been explained based on the electronic structure of the two and the affinity towards electron scavenging and the theory has been found to validate the experimental observations.

Role of Fibrillation on the Magnetorheological and Viscoelastic Effects in Fe, Ni, and Co Nanocolloids

Magnetic metallic nanoparticle (NP)-based colloidal systems have the ability to show highly augmented magnetorheological (MR) and magnetoviscoelastic responses under the influence of magnetic fields. Magnetic metal NPs, viz., iron (Fe), nickel (Ni), and cobalt (Co) have been employed to formulate oleo magnetic-nanocolloids. The magnetocolloids have been characterized for rheological behavior and have been observed to demonstrate superior magnetoviscous effects under magnetic field due to fibrillation by the particles. The magnitude of maximum dynamic yield stress and viscosity of Fe magnetocolloids attained is 18 kPa and 4 kPa.s, respectively, for 15 wt% particle concentration and at ~1.2 T magnetic field intensity. Furthermore, Fe-based colloids are found to be the best candidate among the three types of metallic colloids in terms of high MR effect under magnetic field. The same has been observed for magnetoviscoelastic effects in terms of the enhanced linear viscoelastic range, thixotropy, and strain creep behavior. The experimental observations also show that formulated colloids have highly stable structure under magnetic field even at high shear loads and demonstrate reversible behavior when subjected to rise and decay of magnetic fields.

Influence of temperature and particle concentration on the pH of complex nanocolloids

The pH of colloids is an important electrokinetic property which determines phase stability. We report the effect of temperature and nanoparticle concentration on pH of different nanocolloids of nanomaterials of varied morphologies and sizes. Measurements over a temperature range show that the pH of nanocolloids is a strong function of temperature and the concentration of the dispersed phase. Charge transport mechanisms leading to changes in the effective proton population are discussed. The mannerism in which the electric double layer (EDL) at the particle-fluid interface affects the pH of nanocolloids is presented by appealing to the DLVO theory of electrokinetics dispersion.