Akash Kannegulla

Photo-induced spatial modulation of THz waves: opportunities and limitations

Programmable conductive patterns created by photoexcitation of semiconductor substrates using digital light processing (DLP) provides a versatile approach for spatial and temporal modulation of THz waves. The reconfigurable nature of the technology has great potential in implementing several promising THz applications, such as THz beam steering, THz imaging or THz remote sensing, in a simple, cost-effective manner. In this paper, we provide physical insight about how the semiconducting materials, substrate dimension, optical illumination wavelength and illumination size impact the performance of THz modulation, including modulation depth, modulation speed and spatial resolution. The analysis establishes design guidelines for the development of photo-induced THz modulation technology. Evolved from the theoretical analysis, a new mesa array technology composed by a matrix of sub-THz wavelength structures is introduced to maximize both spatial resolution and modulation depth for THz modulation with low-power photoexcitation by prohibiting the lateral diffusion of photogenerated carriers.

Subwavelength focusing of terahertz waves in silicon hyperbolic metamaterials.

We theoretically demonstrate the subwavelength focusing of terahertz (THz) waves in a hyperbolic metamaterial (HMM) based on a two-dimensional subwavelength silicon pillar array microstructure. The silicon microstructure with a doping concentration of at least 1017  cm-3 offers a hyperbolic dispersion at terahertz frequency range and promises the focusing of terahertz Gaussian beams. The results agree with the simulation based on effective medium theory. The focusing effect can be controlled by the doping concentration, which determines the real part of the out-of-plane permittivity and, therefore, the refraction angles in HMM. The focusing property in the HMM structure allows the propagation of terahertz wave through a subwavelength aperture. The silicon-based HMM structure can be realized using microfabrication technologies and has the potential to advance terahertz imaging with subwavelength resolution.

Metal assisted focused-ion beam nanopatterning.

Focused-ion beam milling is a versatile technique for maskless nanofabrication. However, the nonuniform ion beam profile and material redeposition tend to disfigure the surface morphology near the milling areas and degrade the fidelity of nanoscale pattern transfer, limiting the applicability of the technique. The ion-beam induced damage can deteriorate the performance of photonic devices and hinders the precision of template fabrication for nanoimprint lithography. To solve the issue, we present a metal assisted focused-ion beam (MAFIB) process in which a removable sacrificial aluminum layer is utilized to protect the working material. The new technique ensures smooth surfaces and fine milling edges; in addition, it permits direct formation of v-shaped grooves with tunable angles on dielectric substrates or metal films, silver for instance, which are rarely achieved by using traditional nanolithography followed by anisotropic etching processes. MAFIB was successfully demonstrated to directly create nanopatterns on different types of substrates with high fidelity and reproducibility. The technique provides the capability and flexibility necessary to fabricate nanophotonic devices and nanoimprint templates.

Aluminum ultraviolet–visible plasmonic arrays for broadband and wavelength-selective enhancements of quantum dot emission

Enhancement of spontaneous emission can be achieved by the interaction between quantum emitters and the free electrons on metal surfaces, which creates additional energy relaxation channels through plasmon excitations. It can also be realized by extra near-field excitation of quantum emitters through surface plasmons created by absorption of far-field illumination. By using aluminum dimple arrays with their surface plasmon resonances (SPRs) tunable to span from the visible to UV regions, we demonstrate the control of the quantum dot (QD)-SPR coupling routes to realize either wavelength-selective enhancement of QD emission or broadband enhancement of multicolor QDs. The cost effective Al plasmonic structures enable enhancement of light emission and excitation at tailorable wavelengths and could advance the performance and design flexibility of light-emitting devices and photovoltaic technologies.

Quasi-Optical Terahertz Microfluidic Devices for Chemical Sensing and Imaging

We first review the development of a frequency domain quasi-optical terahertz (THz) chemical sensing and imaging platform consisting of a quartz-based microfluidic subsystem in our previous work. We then report the application of this platform to sensing and characterizing of several selected liquid chemical samples from 570–630 GHz. THz sensing of chemical mixtures including isopropylalcohol-water (IPA-H2O) mixtures and acetonitrile-water (ACN-H2O) mixtures have been successfully demonstrated and the results have shown completely different hydrogen bond dynamics detected in different mixture systems. In addition, the developed platform has been applied to study molecule diffusion at the interface between adjacent liquids in the multi-stream laminar flow inside the microfluidic subsystem. The reported THz microfluidic platform promises real-time and label-free chemical/biological sensing and imaging with extremely broad bandwidth, high spectral resolution, and high spatial resolution.

Surface-plasmon-enhanced photoluminescence of quantum dots based on open-ring nanostructure array

Enhanced photoluminescence (PL) of quantum dots (QD) in visible range using plasmonic nanostructures has potential to advance several photonic applications. The enhancement effect is, however, limited by the light coupling efficiency to the nanostructures. Here we demonstrate experimentally a new open-ring nanostructure (ORN) array 100 nm engraved into a 200 nm thick silver thin film to maximize light absorption and, hence, PL enhancement at a broadband spectral range. The structure is different from the traditional isolated or through-hole split-ring structures. Theoretical calculations based on FDTD method show that the absorption peak wavelength can be adjusted by their period and dimension. A broadband absorption of about 60% was measured at the peak wavelength of 550 nm. The emission spectrum of CdSe/ZnS core-shell quantum dots was chosen to match the absorption band of the ORN array to enhance its PL. The engraved silver ORN array was fabricated on a silver thin film deposited on a silicon substrate using focus ion beam (FIB) patterning. The device was characterized by using a thin layer of QD water dispersion formed between the ORN substrate and a cover glass. The experimental results show the enhanced PL for the QD with emission spectrum overlapping the absorption band of ORN substrate and quantum efficiency increases from 50% to 70%. The ORN silver substrate with high absorption over a broadband spectrum enables the PL enhancement and will benefit applications in biosensing, wavelength tunable filters, and imaging.

Broadband enhancement of quantum dot emission for microLED using Ag plasmonic nanoparticles

MicroLED display is emerging as a candidate to drive a new generation of display technology. Full-color microLED based on carbon-dots (CDs) and blue microLED utilizes photoluminescence (PL) of blue-excited red and green emission CDs to achieve large coverage of color gamut and low power consumption. There is a high demand to develop costeffective technologies to enhance CD emission and minimize blue excitation light leakage through the CD layer. Here we demonstrate the use of plasmonic nanoparticles to enhance multicolor CDs in the emitting layer of microLED while suppressing the transmission of blue excitation. Silver nanoparticles are known to have surface plasmon resonances in or close to the blue range. Blue excitation over an emitting layer formed by the mixture of CDs and metal nanoparticles leads to excitation enhancement of CDs and thus the increased quantum efficiency. We studied the emitting layers fabricated by dispersing a mixture of 30 nm silver nanoparticles and CDs at various ratios and obtained a maximum enhancement factor of ~8. The metal nanoparticles also absorbed the blue excitation and reduced the leakage of blue light. Fluorescence lifetime measurements showed negligible changes in the CD emission rate with and without the presence of metal nanoparticles. The analysis implies that the enhanced CD PL is a result of excitation enhancement rather than Purcell effect. This technique offers a low-cost, effective approach to improve the performance of microLED displays.

Large-area outcoupling of quantum dot emission on multilayer hyperbolic metamaterials

Purcell enhancement can be realized using hyperbolic metamaterials (HMMs) composed of alternating metal/dielectric multilayers of subwavelength thickness. By adjusting the filling fraction of the metal layer, this structure possesses an effective hyperbolic dispersion and can access to epsilon-near-zero (ENZ) with one of the principal components of the permittivity tensor passes through zero. The unique property theoretically yields a large local density of state (LDOS) enabling to support a high Purcell factor and enhanced spontaneous emission rate of a quantum emitter in the vicinity. However, the property of the fabricated HMM deviates from the ideal characteristics estimated by effective medium theory (EMT) due to the finite thickness of the unit cell. Therefore, the actual LDOS and Purcell factor reduce significantly. Additionally, the outcoupling of the high-k waves from HMM remains challenging. It relies on small-area nanostructure due to the incapability of large-area nanofabrication. In this paper, we experimentally and theoretically study the effect of the unit cell thickness in Ag/ITO HMMs on the enhancement of QD emission. The study on 320 nm thick HMM formed by three different unit cell thicknesses ranging from 80 to 20 nm suggested that the Purcell factor increases as the unit cell thickness decreases. We also demonstrate a large-area outcoupling method using self-assembled nanoparticle monolayer to promote the detectable QD emission in the far field. A maximum enhancement factor of ~40 was observed by incorporating the nanoparticle monolayer. This enhancement technique and large-area outcoupling will find applications in display and biosensing.

Enhanced molecular beacon based DNA detection using plasmonic open-ring nanoarrays

Molecular beacon (MB) probe is a fluorophore-labeled oligonucleotide and has been widely used in biological analysis and medical diagnostics by detecting DNA or RNA with specific sequences. The MB initially folds into a loop shape that brings the fluorophore close to a quencher for fluorescence quenching. It opens up upon the binding of target DNA that separates the fluorophore from the quencher to allow fluorescence emission. In this paper, we experimentally demonstrate the use of a silver open-ring nanostructure array (ORA) to enhance both fluorescence emission and quenching of MBs for highly sensitive DNA detection. The ORA displays a broadband resonance spectrum to enhance both the excitation and emission of fluorophores. The fluorescence enhancement is highly dependent on the distance between nanostructure and fluorophore. The couplings of the fluorescence emission and the external excitation with the proximate plasmonic nanostructure result in coherent electron oscillations that in turn act as secondary excitation of the fluorophore in a ~10 nm separation distance, leading to fluorescent enhancement. The resonance feature of ORA also improved the Förster resonance energy transfer between the fluorophore and ORA in an even shorter separation distance that promotes the fluorescence quenching. The enhanced fluorescence emission and quenching amplified the on-off ratio of the detection signal. The sensor was integrated into a microfluidic chamber to handle microliter-volume analyte and achieved a ~300 fM detection limit, an equivalent 360 zmol in a 1.2 μL analyte volume, superior to the detection on plane silver surfaces.

Quantum Dot Fullerene-Based Molecular Beacon Nanosensors for Rapid, Highly Sensitive Nucleic Acid Detection

Spherical fullerene (C60) can quench the fluorescence of a quantum dot (QD) through energy-transfer and charge-transfer processes, with the quenching efficiency regulated by the number of proximate C60 on each QD. With the quenching property and its small size compared with other nanoparticle-based quenchers, it is advantageous to group a QD reporter and multiple C60-labeled oligonucleotide probes to construct a molecular beacon (MB) probe for sensitive, robust nucleic acid detection. We demonstrated a rapid, high-sensitivity DNA detection method using the nanosensors composed of QD-C60-based MBs carried by magnetic nanoparticles. The assay was accelerated by first dispersing the nanosensors in analytes for highly efficient DNA capture resulting from short-distance three-dimensional diffusion of targets to the sensor surface and then concentrating the nanosensors to a substrate by magnetic force to amplify the fluorescence signal for target quantification. The enhanced mass transport enabled a rapid detection (<10 min) with a small sample volume (1-10 μL). The high signal-to-noise ratio produced by the QD-C60 pairs and magnetic concentration yielded a detection limit of 100 fM (∼106 target DNA copies for a 10 μL analyte). The rapid, sensitive, label-free detection method will benefit the applications in point-of-care molecular diagnostic technologies.