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Dive into the research topics where Akihito Sakakibara is active.

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Featured researches published by Akihito Sakakibara.


Journal of The Chemical Society, Chemical Communications | 1991

Molecular interactions of polysilane and unsaturated nitrogen compounds. Photochemical addition of disilene versus silylene to azobenzene

Akihito Sakakibara; Yoshio Kabe; Toshio Shimizu; Wataru Ando

Photochemical reaction of hexamesitylcyclotrisilane 1 or tetramesityldisilene 2 with azobenzene produces silanol 5via hydrolysis of diazasilacyclopropane 3 and/or 1,2-diaza-3,4-disilacyclobutane 4; the structure of 4 has been confirmed by variable temperature 1H NMR spectroscopy and single-crystal X-ray diffraction, the existence of an Si2N2 ring system is demonstrated.


Organometallics | 1988

The first spectroscopic detection of silaylides in the reaction of dimesitylsilylene with P, S, and N heteroatom-containing substrates. The stability of silaylides

Wataru Ando; Akira Sekiguchi; Kazuyoshi. Hagiwara; Akihito Sakakibara; Hitoaki. Yoshida


Organometallics | 1988

The first spectroscopic detection of silaylides in the reaction of dimesitylsilylene with phosphorus, sulfur, and nitrogen-containing substrates. The stability of silaylides

Wataru Ando; Akira Sekiguchi; Kazuyoshi. Hagiwara; Akihito Sakakibara; Hitoaki. Yoshida


Archive | 1997

Curable polymethylsiloxane composition

Maki Itoh; Tetsuyuki Michino; Akihito Sakakibara; Akihito Saitoh


Archive | 1994

Diorganopolysiloxane-rigid aromatic polymer compositions and preparation thereof

Maki Itoh; Akihito Sakakibara


Archive | 1995

Organopolysiloxane-grafted polybenzobisoxazoles and method for preparing same

Maki Itoh; Akihito Sakakibara


Journal of Polymer Science Part A | 1995

Rigid-rod polymers with polysiloxane side chains. 2. Synthesis and characterization of aromatic polybenzobisoxazoles with polysiloxane side chains and composite formation with polysiloxane matrices

Akihito Sakakibara; Maki Itoh; Itaru Mita


Journal of Synthetic Organic Chemistry Japan | 1992

Recent Developments in the Preparation of Cyclic Silicon Compounds Containing Heteroatoms (N, P, S)

Akihito Sakakibara; Wataru Ando


Nippon Kagaku Kaishi | 1990

Special articles on new aspects of silicon chemistry. Photoreactions of cyclotetrasilane and cyclotetragermane in the presence of azobenzenes.

Akihito Sakakibara; Takeshi Tsumuraya; Yoshio Kabe; Wataru Ando


Archive | 1994

Zusammensetzungen von Diorganopolysiloxan und steifem aromatischen Polymer und deren Herstellung Compositions of diorganopolysiloxane and rigid aromatic polymer and their preparation

Maki Itoh; Akihito Sakakibara

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Takeshi Tsumuraya

Osaka Prefecture University

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