Akumbom Vishiti

Host rock geochemistry, texture and chemical composition of magnetite in iron ore in the Neoarchaean Nyong unit in southern Cameroon

ABSTRACT A combination of petrography, whole-rock geochemistry, geochronology and compositional variation in magnetite is employed in this study to elucidate the nature and origin of enigmatic magnetite mineralisation hosted within gneissic rocks in the Nyong Unit in southern Cameroon. The mineralisation occurs as magnetite-bearing calc–silicate gneisses. The host rock mineral assemblage comprises quartz–plagioclase–biotite–amphibole–chlorite–clinopyroxene–garnet that provides evidence of medium-grade metamorphism and retrograde alteration. Textural and chemical analyses of the magnetite grains show variable textural and trace element chemical characteristics attributed to metamorphic-hydrothermal overprint and weathering. Magnetite occurs as disseminations and stringers commonly intergrown with amphiboles. It is also observed to show vermiforms wrapped around quartz and clinopyroxenes within a biotite–chlorite- plagioclase groundmass. Massive-granoblastic magnetite is rare and mainly observed within vein-like domains. On backscattered secondary electron images the magnetite grains are anhedral, with minor spinel exsolution lamellae. Electron microprobe analysis on magnetite suggests both a hydrothermal skarn and banded iron formation (BIF) affinity. The lack of negative Ce anomalies excludes a Proterozoic BIF setting, but it is in agreement with Archaean BIF. Sensitive high resolution ion microprobe U-Pb isotope data on zircon in the magnetite gneiss define an identical Wetherill concordia and Tera–Wasserburg Neoarchaean age of 2699 ± 7 Ma (1σ; MSWD (mean square weighted deviation) = 1.3; n = 13), and Pan-African disturbance at about 500 ± 200 Ma. The Neoarchaean age is in accordance with the known onset of BIF deposition at the northern edge of the Congo Craton and therefore constrains the maximum age of formation of the Nyong magnetite gneisses.

Hydrothermal Alteration of Basaltic Rocks at Eruptive Vents on Mount Cameroon Volcano, West Africa

The study of changes in rocks due to interaction with hydrothermal fluids at active volcanoes provides insights into wall rock alteration associated with ore deposits formed in the geological past. Therefore, the nature of mineral alteration and chemical changes experienced by wall rocks can be investigated at eruptive sites on active volcanoes and the results used to better constrain ore-forming processes. In this study, we investigated the alteration at eruptive sites at Mount Cameroon volcano. These eruptive vents lie along NE-SW-trending fissures that define the Mount Cameroon rift. The vents are surrounded by cones composed largely of pyroclastic materials and to a lesser extent lava. Fumaroles (volcanic gases) rising through the vents during and after the 1999 eruption have resulted in the alteration of the pyroclastic robble along the fissures and the inner walls of the cones. Consequently, altered basaltic materials are covered with thin films of reddish, yellowish to whitish secondary minerals. These coatings result from an interaction between the surfaces of the basaltic glass with volcanically-derived acidic fluids. Petrographic investigations and XRD analysis of the basalts have identified primary mineral phases, such as olivine, pyroxene (mainly augite) and feldspars. Alteration products revealed include ubiquitous silica as well as gypsum, magnetite, feldspar, alunite and jarosite. Jarosite occurrence indicates that SO2 is the primary volcanically-derived acid source involved in coating formation. High contents of sulfur identified in the basalts indicate that melts at Mount Cameroon can be sulfur saturated as backed by previous melt inclusion data. Whole rock geochemical analysis shows a gain in silica in the altered samples and this ties with the mass balance calculations although minor gains of Al2O3, , MgO, MnO, CaO and K2O are shown by some samples.

Wallrock alteration categories and their geochemical signatures in gold-bearing Neoproterozoic granitoids, Batouri gold district, southeastern Cameroon

Hydrothermally altered granitoids in the Batouri district host gold mineralization. Gold and associated metals occur as disseminated, stockwork and veins. The granitoids range from quartz-alkali granitoids sensu stricto to diorite with various types of wallrock alterations including K-feldspar alteration, sericitization, silicification, and sulphidation/ferruginization. Most gold-bearing samples are extensively brecciated. Gold mineralization is accompanied with sericitization, silicification, and sulphidation/ferruginization alterations. Gold concentrations reach a high of 103.7 ppm. The granitic rocks are sub-alkaline. They show enrichment in the LREE, a negative Eu anomaly and a depletion in the HREE reflecting the breakdown and mobility of the initial plagioclase feldspar bearing HREE during fluid-rock interaction. On multielement variation diagrams, spikes at K, Ba, Pb, and Th are depicted resulting from selective enrichment during alteration. Mass gains/losses during alteration calculated using the immobile element method indicate, amongst others, gains in SiO2 (silicification), K2O (K-feldspar alteration), SO3 and Fe2O3 (sulphidation/ferruginization) with losses in Na2O linked to sericitization. The samples show Pd and Pt as high as 2 ppm. Gold mineralization is associated with wallrock alteration zones with elevated contents of As-Ba-Cu-Pb-Rb-Sr-Zn and Zr due to the neominerals developed during hydrothermal alteration. Au-Ag-Zn defines a potential pathfinder element cluster in the Batouri district.

Arsenian pyrite-bearing altered volcanics dredged SE of Cheshire Seamount, western Woodlark Basin, Papua New Guines

In many subaerial hydrothermal ore deposits arsenian pyrite is an important host for Au, however, arsenian pyrite is rare on the modern seafloor. During a recent survey for submarine hydrothermal mineralization in the western Woodlark Basin volcanic breccias containing abundant arsenian pyrite were dredged from the flanks of a volcanic seamount in a water depth of 2000 m. This area is particularly interesting because it is located at the transition from continental splitting to oceanic spreading where enhanced heat flow and deep crustal faults may fertilize mineralization. The sulfidic breccia is essentially monomictic and matrix-supported containing altered dacitic clasts. Mineralogical investigation of the breccia reveals silicification and sulfidation as the main alteration types. Quartz occurs in fragments and also constitutes the breccia matrix attesting to silicification as a significant alteration process. Pyrite is the dominant ore mineral with only minor amounts of Fe-oxyhydroxide and goethite. Bulk geochemistry shows a slight enrichment of Au (0.12 ppm) in association with elements such as As-Ag-Hg-Zn-Pb-Sb, key elements indicative of a low sulfidation environment. Three generations of pyrite are recognized on the basis of morphology. Arsenic-free, early framboidal pyrite (py1) is overgrown by arsenian colloform (py2) or massive pyrite (py3) containing up to 3.93 wt% As. Arsenic speciation in the pyrite is in the form of As1- and As3+. The presence of arsenian pyrite in hydrothermal breccias at this seamount indicates the potential for Au mineralization in the area.