Alban Moyeux

Cobalt-Catalyzed Cross-Coupling Reactions

3.1.2. From Vinylic Grignard Reagents 1437 3.1.3. From Aryl Halides and Alkenyl Acetates 1438 3.2. Aryl-Aryl Cross-coupling 1438 3.2.1. From Aromatic Organometallic Reagents 1438 3.2.2. From Two Aromatic Halides 1440 4. Csp2-Csp3 Cross-coupling Reactions 1440 4.1. Alkenylation 1440 4.1.1. From Aliphatic Organometallic Reagents 1440 4.1.2. From Aliphatic Halides 1442 4.2. Arylation 1442 4.2.1. From Aliphatic Halides 1442 4.2.2. From Aromatic Halides 1445 4.3. Allylation of Aromatic Organometallics 1446 5. Alkynylation 1446 5.1. Pioneering Works 1446 5.2. Benzylation of Acetylenic Grignard Reagents 1446 5.3. Alkylation of Acetylenic Grignard Reagents 1447 5.4. Alkenylation of Acetylenic Grignard Reagents 1447 6. Csp3-Csp3 Cross-coupling 1448 6.1. Allylation 1448 6.1.1. Allylation of Aliphatic Organozinc Compounds 1448

Iron‐Catalyzed Oxidative Heterocoupling Between Aliphatic and Aromatic Organozinc Reagents: A Novel Pathway for Functionalized Aryl–Alkyl Cross‐Coupling Reactions

Aryl-alkyl cross-coupling products are obtained by the iron-catalyzed oxidative heterocoupling of organozinc reagents under mild conditions. This novel reaction pathway is versatile, allowing for the use of primary and secondary aliphatic diorganozinc reagents as coupling partners as well as tolerating functionalized aryl- and alkylzinc reagents.