Alberto Caselli

Intense magmatic degassing through the lake of Copahue volcano, 2013-2014

Here we report on the first assessment of volatile fluxes from the hyperacid crater lake hosted within the summit crater of Copahue, a very active volcano on the Argentina-Chile border. Our observations were performed using a variety of in situ and remote sensing techniques during field campaigns in March 2013, when the crater hosted an active fumarole field, and in March 2014, when an acidic volcanic lake covered the fumarole field. In the latter campaign, we found that 566 to 1373 t d−1 of SO2 were being emitted from the lake in a plume that appeared largely invisible. This, combined with our derived bulk plume composition, was converted into flux of other volcanic species (H2O ~ 10989 t d−1, CO2 ~ 638 t d−1, HCl ~ 66 t d−1, H2 ~ 3.3 t d−1, and HBr ~ 0.05 t d−1). These levels of degassing, comparable to those seen at many open-vent degassing arc volcanoes, were surprisingly high for a volcano hosting a crater lake. Copahues unusual degassing regime was also confirmed by the chemical composition of the plume that, although issuing from a hot (65°C) lake, preserves a close-to-magmatic signature. EQ3/6 models of gas-water-rock interaction in the lake were able to match observed compositions and demonstrated that magmatic gases emitted to the atmosphere were virtually unaffected by scrubbing of soluble (S and Cl) species. Finally, the derived large H2O flux (10,988 t d−1) suggested a mechanism in which magmatic gas stripping drove enhanced lake water evaporation, a process likely common to many degassing volcanic lakes worldwide.

Costa Recta beach, Deception Island, West Antarctica: a retreated scarp of a submarine fault?

Deception Island (South Shetlands, Antarctica) is one of the most active volcanoes in Antarctica, having erupted recently in 1967, 1969 and 1970, damaging scientific stations on the island. It is also seismically very active. The island has attracted the attention of many researchers as it constitutes an undisturbed natural laboratory to study seismo-volcanic events and how they affect landscape modelling and evolution. One of the most remarkable geological and geomorphological features on Deception Island is the linearity of its easternmost coastal landform, the origin of which remains unknown. Some answers, based on presence of strike-slip fault or on the ice cap and beach geomorphological dynamics, have been reported in the literature. Our new work provides several indications of the existence of a dip-slip submarine fault, parallel to the coast (NNW–SSE), which suggests a tectonic origin for this morphological feature. Uplifted marine terraces, incision of a fluvial network over the ice cap, normal faulting parallel to the coast in the north and south rock heads bounding the beach and sharp shelf-break with rather constant slope, constitute some of this evidence. Terrace uplift and fluvial channel incision decreasing southward from Macaroni Point, indicates possible tilt movement across this inferred fault plane.

Fluvial and eolian ichnofaunas from the Lower Permian of South America (Patquía Formation, Paganzo Basin)

The Lower Permian Patquia Formation is the youngest unit of the Paganzo Basin, western Argentina. The lower section consists of red mudstones, and fine- and coarse grained sandstones deposited in fluvial systems with extensive and thick floodplain deposits. These rocks contain a low-diversity and relatively abundant association of trace fossils suggesting the activity of a sub-superficial to superficial fauna. The association is characterized by Rusophycus carbonarius (Cubichnia), Cruziana problematica (Repichnia), and Palaeophycus tubularis (Domichnia) of the Scoyenia ichnofacies. Disarticulated fish remains are also present. The upper section is dominated by red, cross-bedded, medium- to fine-grained sandstones deposited in eolian systems that host a lowdiversity and low-abundance association of trace fossils that indicates the activity of a mainly superficial fauna. Tetrapod footprints (Chelichnus duncani, oval digit imprints, short parallel grooves, and sinusoidal grooves), horizontal to vertical burrows (Palaeophycus tubularis and Skolithos isp. respectively), and arthropod trackways are the typical components of these deposits. The association shows elements of the three presently proposed eolian ichnofacies (Chelichnus, Octopodichnus and Entradichnus ichnofacies) suggesting the necessity of revision and the possible integration of these separate ichnofacies into a single model. The record of fossil vertebrate tracks is uncommon in Lower Permian strata of South America. Therefore, the ichnologic record of the Patquia Formation is a significant contribution to the understanding of Lower Permian South American ichnofaunas.

The crater lake of Copahue volcano (Argentina): geochemical and thermal changes between 1995 and 2015

Abstract The crater lake and associated hydrothermal features of Copahue volcano have been studied intensively over the last 20 years (1995–2015). The geochemical and isotopic compositions of the waters provide insights into the processes occurring in the volcanic–hydrothermal system, the crater lake and the thermal springs. Variations in the temperature and chemical composition of the waters reveal fundamental changes in the system that precede and accompany the magmatic and phreatic eruptive events at Copahue. A conceptual model of the summit system was developed involving the intrusion of slivers of magma in the hot acidic hydrothermal cell, the saturation of waters with secondary minerals leading to reduced permeability, the blocking of fluid pathways by liquid sulphur during heating events and the transport of gas from the magma through the ductile–brittle transition into the hydrothermal system. Geophysical data were integrated with the chemical data to provide new insights into the behaviour of the deep magmatic system that feeds the volcano edifice. Multidisciplinary studies were used to identify precursory signals of eruptive activity to give an early warning of pending volcanic hazards. Several geochemical ratios in river water were identified as potential indicators of upcoming volcanic activity, which could be used in co-operation with the community and local authorities to deal with these volcanic hazards.

Risk Assessment and Mitigation at Copahue Volcano

“Risk assessment” is a relatively new concept in Argentina, since the very first hazard map was only recently constructed on the basis of the 1992 eruption of Copahue volcano (Patagonia). Copahue is considered a very active volcanic system since 13 eruptive events have been recognized over the last 260 years. Most the events are phreatic and phreato-magmatic with VEI ≤ 2; nevertheless such eruptions represent a threat for the communities living in the surrounding areas of the emission centre, not only because of pyroclastic flows and tephra fall (the nearby villages, Caviahue and Copahue, have so far only experienced ash fallout), but also due to the possible formation of mud flows and flank collapse triggered by the volcanic activity. Owing to the frequent eruptions of Copahue, the most recent ones (2000, 2012) showed an increasing explosive character, hazard survey actions, such as thematic maps and contingency plans are constantly, though slowly, modified. The risk assessment described in this chapter calls for the implementation of the monitoring network in the Argentina side of the volcano, since the only currently active seismic stations (OVDAS) are located in the Chilean side of the volcanic edifice, Copahue volcano lying at the border between the two countries. Moreover, the Chilean observatory adopts criteria of alert levels, which are distinctly different with respect to those of Argentina Civil Defense, producing misleading information to the population. The villages of Copahue and Caviahue are regarded as extremely vulnerable to possible future eruptions if larger magnitude events should occur. A review of the presently available potential hazard map, an improvement of people’s education about the volcanic risks and a more interactive cooperation between the Chilean and Argentina scientific and administrative institutions are some of the immediate countermeasures to be taken into account before a new explosive phase at Copahue.