Alessandro Veltri

Development of a new kind of switchable holographic grating made of liquid-crystal films separated by slices of polymeric material

We present a new kind of UV-cured holographic grating that consists of polymer slices alternated with pure nematic films. By preventing the appearance of the nematic phase during the curing process, it is possible to avoid the formation of liquid-crystal droplets and obtain a sharp and uniform morphology, which reduces scattering losses and increases diffraction efficiency.

Model for the photoinduced formation of diffraction gratings in liquid-crystalline composite materials

We modelize the photoinduced formation of switchable diffraction gratings in polymer-based liquid-crystalline composite materials. The model assumes that redistribution of molecules is due to mass diffusion and incorporates a realistic kinetic description of polymerization processes. Numerical simulations predict two different kinds of structure that have already been experimentally observed. Two parameters governing the phenomenon are pointed out, which determine the structure that will be formed after the curing process has been completed.

Composite holographic gratings containing light-responsive liquid crystals for visible bichromatic switching.

Photosensitive liquid crystals (PLCs) are promising materials that can combine a high-refractive-index modulation, typical of LCs, with high photosensitivity, due to the presence of photochromic molecules such as azobenzene and derivates. [1] These can undergo a reversible isomerization from a thermodynamically stable trans to a cis conformation when acted on by UV or visible light; a reverse transition can be obtained upon heating or irradiation with a different (longer wavelength) visible light. Thanks to these materials andprocesses, thepossibility toconfine and stabilize photosensitive materials has been considered in the past [2] and the perspective of producing fast photonic devices of scientific and technological interest looks highly realistic. There is, however, a serious problem represented by instability far from room temperature. [2] One way to reduce this effect has been found in using composite polymeric materials: [3] Holographic diffraction gratings, which exploit LC composite materials (HPDLCs), [4] are low-cost components with a wide range of possible photonic and optoelectronics applications. Therefore, the possibility of fabricating an optically controllable photonic device has been investigated by combining the photosensitivity of azobenzene materials with the optical properties of HPDLCs. [5] Devices of this kind can exhibit, however, an intrinsic drawback when the droplet size of the LC component inside the polymeric matrix is comparable with the wavelength of the diffracted light, thus yielding a strong light scattering. [6] Recently, a good improvement has been obtained by using a new kind of holographic diffraction grating with better optical qualities, which consists of polymer slices alternated to films of regularly aligned nematic LC (NLC). Depending on the particular procedure utilized for its fabrication, this structure is called POLIPHEM [7] orPOLICRYPS [8] andisobtainedby UV-curingofa mixture of monomer and NLC. In a recent attempt [9] to fabricate

Characterization of the diffraction efficiency of new holographic gratings with a nematic film-polymer-slice sequence structure

We have performed a first characterization of the diffraction efficiency of gratings written in liquid-crystalline composite materials by the interference pattern of two curing beams. The grating fringes consist of polymer slices separated by films of continuous nematic phase. The dependence of the diffraction efficiency on temperature reveals a nonmonotonic behavior, with several maxima and minima. The shapes of curves are dependent on slight changes in the initial concentration of the nematic component of the mixture; the number of extrema increases with an increase of this concentration. The dependence of the diffraction efficiency on an applied external voltage also appears to be nonmonotonic: The shape depends on the sample’s temperature. Both switch-on and switch-off responses have been observed. The behavior of our gratings can be explained in the framework of the conventional Kogelnik theory for the diffraction efficiency of Bragg gratings.

Electro-optic properties of switchable gratings made of polymer and nematic liquid-crystal slices

We report the diffraction properties at wavelengths of 632.8 and 1550 nm for volume transmission gratings made of a sequence of continuously aligned nematic liquid-crystal layers separated by isotropic polymer slices. The gratings are generated by holographically curing a solution of liquid crystal diluted in an isotropic prepolymer by means of a laser beam at a wavelength of 352 nm with a total intensity of approximately 10 mW/cm2. A diffraction efficiency of 98% was measured, and an electric field as low as 5 V/microm switches off the phase grating. Measured angular spectra are fitted by use of the modified coupled-mode theory including the effects of grating birefringence.

In situ optical control and stabilization of the curing process of holographic gratings with a nematic film-polymer-slice sequence structure

We report on the realization of what we believe to be a new holographic setup for the fabrication of polymer liquid-crystal polymer-slice diffraction gratings, which utilizes an optical-feedback-driven nanopositioning technique. We have increased the stability of the interference pattern by means of a simple piezomirror used in a feedback configuration to keep constant the phase of the interferometer. The feedback system is driven by a proportional, integral, derivative control software, and the stability degree is controlled by the reference signal coming from a standard test grating. A preliminary experimental characterization indicates that good control and stabilization of parasitic fluctuations of the interference pattern are obtained.

All-optical switching of holographic gratings made of polymer-liquid-crystal-polymer slices containing azo-compounds

We present the observation of an all-optical switching effect that takes place when a light beam of suitable wavelength irradiates a “layered” structure made of polymer slices alternated to films of well aligned liquid crystal (LC) which contain also a small percentage of azo-LC molecules. The simple and reliable fabrication procedure exploits a holographic UV curing technique. The observed switching effect takes place in samples that exhibit diffraction efficiency as high as 85% and is induced in less than 0.5 s by an unfocused pump beam of 245 mW/cm2 power density.

POLICRYPS structures as switchable optical phase modulators.

We report on the electrically controlled optical phase modulator behavior of light sculptured periodic structures made of polymer slices alternated to films of well aligned Liquid Crystals (POLICRYPS). Arbitrarily polarized light normally incident on the structure experiences a birefringence that depends on the anisotropy of the composite liquid crystalline material and on the geometrical cell parameters. The sample behaves as a retardation plate in good agreement with the Jones matrices formalism. Birefringence tuning is obtained by applying a suitable voltage, while a negligible birefringence variation is detected by increasing the incidence power. This makes POLICRYPS structures suitable as switchable phase retarders for high power laser beams.

Kogelnik-like model for the diffraction efficiency of POLICRYPS gratings

We report on diffraction gratings consisting of continuous and well-aligned nematic films separated by polymer slices, which are originated in nematic-containing polymer composites when cured by a UV interference pattern. The diffraction efficiency of these gratings is experimentally investigated in detail; its temperature dependence reveals a rather complex, nonmonotonic shape, with a next-to-unit maximum at high temperatures and a next-to-zero minimum at lower ones. When the influence of an external electric field is investigated, the dependence of the diffraction efficiency on the applied voltage appears to be nonmonotonic too, the particular shape depending on the actual value of the sample temperature; in general, both switch-on and switch-off of the diffraction mechanism can be observed as an effect of the external field. For this kind of grating, a Kogelnik-like model has been implemented that makes use of only real values of some physical quantities, without the necessity of any fitting parameter. Numerical solutions account for the temperature dependence of the diffraction efficiency with good accuracy.

Observation of two-wave coupling during the formation of POLICRYPS diffraction gratings.

We report on the experimental observation of two-wave mixing that occurs inside a sample between the beams used for the fabrication of polymer-liquid-crystal-polymer slices (POLICRYPS) diffraction gratings. The effect depends on the phase shift between the curing interference pattern and the grating being cured. This shift can be mechanically induced by accidental vibrations of the experimental setup; thus a high setup stability is needed. We devised a mechanism that enables us to control setup vibrations in situ and used it to monitor the experiment. When the mechanically induced shift was significantly small, wave mixing was observed only if the initial intensities of the two curing beams were different from each other.