Alexander Cherkinsky

CAN WE GET A GOOD RADIOCARBON AGE FROM "BAD BONE"? DETERMINING THE RELIABILITY OF RADIOCARBON AGE FROM BIOAPATITE

The study of the radiocarbon age of bone bioapatite was initiated by necessity to date archaeological artifacts, which often contain little or no collagen as a result of poor preservation. Contamination of the organic fraction in the process of the burial or during museum preservation treatment generally prohibits the use of the collagen fraction for dating. Our investigation has shown that the pretreatment of bone with diluted acetic acid following a proscribed technique allows the separation of the bioapatite fraction from diagenetic carbonates. We have successfully used this technique to prepare and date samples of bone and of tooth enamel and dentin, with varying degrees of preservation condition, and from time intervals ranging from a few hundred 14C yr to greater than 40,000 14C yr.

From Shell Midden to Midden-Mound: The Geoarchaeology of Mound Key, an Anthropogenic Island in Southwest Florida, USA.

Mound Key was once the capital of the Calusa Kingdom, a large Pre-Hispanic polity that controlled much of southern Florida. Mound Key, like other archaeological sites along the southwest Gulf Coast, is a large expanse of shell and other anthropogenic sediments. The challenges that these sites pose are largely due to the size and areal extent of the deposits, some of which begin up to a meter below and exceed nine meters above modern sea levels. Additionally, the complex depositional sequences at these sites present difficulties in determining their chronology. Here, we examine the development of Mound Key as an anthropogenic island through systematic coring of the deposits, excavations, and intensive radiocarbon dating. The resulting data, which include the reversals of radiocarbon dates from cores and dates from mound-top features, lend insight into the temporality of site formation. We use these insights to discuss the nature and scale of human activities that worked to form this large island in the context of its dynamic, environmental setting. We present the case that deposits within Mound Key’s central area accumulated through complex processes that represent a diversity of human action including midden accumulation and the redeposition of older sediments as mound fill.

Maritime Hunter-Gatherers in the Chonos Archipelago (43°50’–46°50’ S), Western Patagonian Channels

ABSTRACT This article presents the current advances in archeological research on the Western Patagonian Channels, specifically the Chonos Archipelago (43°50’–46°50’ S). Based on a large spatial scale, we aim to contribute to the discussion of the dispersion and characteristics of the occupation of the Pacific coast of southernmost South America. Results show that all of the contexts recorded do not exceed 3600 cal BP. Site formation processes that may have acted in the preservation of the archeological record of this area led us to question if this region was among the last to be settled (as suggested by current chronological data), or if the dynamic tectonic activity that permanently transforms this coast is playing a major role in concealing earlier evidence, thereby introducing a significant research bias.

Compatibility of Atmospheric 14CO2 Measurements: Comparing the Heidelberg Low-Level Counting Facility to International Accelerator Mass Spectrometry (AMS) Laboratories

Combining atmospheric Δ14CO2 data sets from different networks or laboratories requires secure knowledge on their compatibility. In the present study, we compare Δ14CO2 results from the Heidelberg low-level counting (LLC) laboratory to 12 international accelerator mass spectrometry (AMS) laboratories using distributed aliquots of five pure CO2 samples. The averaged result of the LLC laboratory has a measurement bias of –0.3 ±0.5‰ with respect to the consensus value of the AMS laboratories for the investigated atmospheric Δ14C range of 9.6 to 40.4‰. Thus, the LLC measurements on average are not significantly different from the AMS laboratories, and the most likely measurement bias is smaller than the World Meteorological Organization (WMO) interlaboratory compatibility goal for Δ14CO2 of 0.5‰. The number of intercomparison samples was, however, too small to determine whether the measurement biases of the individual AMS laboratories fulfilled the WMO goal.

Alteration of rocks by endolithic organisms is one of the pathways for the beginning of soils on Earth

Subaerial endolithic systems of the current extreme environments on Earth provide exclusive insight into emergence and development of soils in the Precambrian when due to various stresses on the surfaces of hard rocks the cryptic niches inside them were much more plausible habitats for organisms than epilithic ones. Using an actualistic approach we demonstrate that transformation of silicate rocks by endolithic organisms is one of the possible pathways for the beginning of soils on Earth. This process led to the formation of soil-like bodies on rocks in situ and contributed to the raise of complexity in subaerial geosystems. Endolithic systems of East Antarctica lack the noise from vascular plants and are among the best available natural models to explore organo-mineral interactions of a very old “phylogenetic age” (cyanobacteria-to-mineral, fungi-to-mineral, lichen-to-mineral). On the basis of our case study from East Antarctica we demonstrate that relatively simple endolithic systems of microbial and/or cryptogamic origin that exist and replicate on Earth over geological time scales employ the principles of organic matter stabilization strikingly similar to those known for modern full-scale soils of various climates.

Stable isotope analysis on human remains from the final Early Holocene in the southern Puna of Argentina: The case of Peñas de las Trampas 1.1

In this work are presented the results of isotopic analyses made on bone remains of human individuals (n = 6) from the southern Puna of Argentina dated to the final Early Holocene (ca. 8230–8000 BP). They were found in structures located in Peñas de las Trampas 1.1, a rockshelter at 3582 m.a.s.l. in Antofagasta de la Sierra, in the southern Argentinian Puna. They contain multiple secondary burials. Bone fragments were recovered from at least six individuals, three in each structure. Stable isotopes of Carbon (δ13C) and Nitrogen (δ15N) analysis were aimed at defining aspects related to the palaeodiet of the six individuals within the palaeo-economic subsistence spectrum typical of hunter–gatherers. It is worth noting that these human remains are among the earliest from North-Western Argentina, where funeral practices are related with the transportation of certain anatomical parts. The palaeodietary inference considers, on the one hand, the extreme aridity of this geographical area and its impact on the isotopic ecology. And, on the other, it takes into account the fact that four of the six individuals under study were breastfed infants. The results are in agreement with the expected values of the period, which has been characterized as the beginning of the arid Altithermal.

Bayesian Approach to 14C Dates for Estimation of Long-Term Archaeological Sequences in Arid Environments: The Holocene Site of Takarkori Rockshelter, Southwest Libya

Caves and rockshelters are critical loci for the analysis and understanding of human trajectories in the past. Use and re-uses of the same context, however, might have had serious impacts on depositional aspects. This is particularly true for the archaeological history of desert environments, such as the central Sahara, where most of the deposits are made of loose sand, rich in organic matter. Besides traditional stratigraphic reconstructions and a detailed study of the material culture, radiocarbon measurements from different contexts analyzing several types of material (bone, dried and charred coprolite, uncharred and charred plant remains, etc.) can highlight intrinsic critical aspects of 14C determinations. These measurements must be carefully evaluated to provide a correct chronological assessment of the life history of the site. We present the statistics derived from the set of about 50 14C measurements from the site of Takarkori, southwest Libya, where early Holocene foragers and then groups of cattle herders inhabited the area from ~10,200 to 4600 cal yr BP. We have used the BCal Bayesian 14C calibration program designed for statistical presentation of the calibrated data and the estimation of their probability for different phases. Results indicate that the Takarkori rockshelter was occupied during 4 phases of the following cultures: Late Acacus from 10,170 to 8180 cal yr BP; Early Pastoral, 8180–6890 cal yr BP; Middle Pastoral, 7160–5610 cal yr BP; and Late Pastoral, 5700–4650 cal yr BP.

Spatiotemporal Variability in ΔR in the Northern Gulf of Mexico, USA

Strombus alatus and Busycon sinistrum are large marine gastropods that are frequently recovered from archaeological contexts in southeastern North America. We previously proposed a reservoir age offset (ΔR) for B. sinistrum from the northern Gulf of Mexico region based on known-age pre-bomb 20th-century specimens. We also reported significant variability in radiocarbon both among and within S. alatus specimens, which precluded a reliable estimation of ΔR for this taxon. In this paper, we present a complementary data set from archaeological contexts to re-evaluate marine reservoir effects in the northern Gulf Coast region at multiple spatial and temporal scales. The new data set consists of a total of 13 14 C age determinations from well-associated marine ( B. sinistrum and S. alatus ) and terrestrial ( Odocoileus virginianus ) samples from a closed context at the Bayou St. John (1BA21) archaeological site. We suggest a slightly updated ∆R value of –2±53 14 C yr for late Holocene-age B. sinistrum from the northern Gulf Coast region. S. alatus , and possibly other species of strombid conchs, are poor candidates for 14 C dating due to the highly variable 14 C content observed within and among specimens. Though subregional variability in inputs of 14 C-depleted waters is likely, life-history factors related to ontogenetic niche and/or habitat shifts appear to be a major influence in shell 14 C for S. alatus .

Radiocarbon Age of Soil Organic Matter Fractions Buried by Tephra in Alaska

Radiocarbon ages were determined on different fractions extracted from buried paleosols in south-central Alaska as an experiment to establish best practices for analysis of low-organic-matter paleosols. Seven samples were collected from directly beneath tephra deposits to determine the eruption frequency of Mount Spurr Volcano, Alaska. Soil development near the volcano is poor due to the high-latitude climate and frequent burial of soil surfaces by tephra. Contamination of soils by local wind-blown material is a concern. The humic acid 14 C ages are consistently younger than both the bulk soil and residue after extraction ages. The difference in ages between the humic acid extract and bulk soil range from 60–1130 14 C yr BP and 180–4110 14 C yr BP, respectively, for residue. Previous observations from dating different soil fractions show that residue ages are typically younger than humic acid extracts presumably because they contain a fraction of younger plant material including roots. We attribute the older ages to contamination by old carbon from eolian charcoal particles. This study supports the use of accelerator mass spectrometry (AMS) 14 C dating of the humic acid fraction in order to estimate the age of soil that presumably marks the age of burial and avoids suspected contamination by old carbon.

The Age and Origin of Olivella Beads from Oregon’s LSP-1 Rockshelter: The Oldest Marine Shell Beads in the Northern Great Basin

Beads manufactured frommarine shells originating along the Pacific Coast have been found at numerous sites in the western United States. Because they were conveyed across substantial distances and widely exchanged during ethnographic times, researchers generally assume that shell beads were also traded prehistorically. By examining the spatial and temporal distribution of beads, researchers have reconstructed prehistoric exchange networks. In this report, we present stable isotope data and accelerator mass spectrometer (AMS) radiocarbon dates for six Callianax (previously Olivella) biplicata beads from the LSP-1 rockshelter in southcentral Oregon. Most of the beads were deposited during the early Holocene during a series of short-term occupations and the shells used to manufacture them were procured along the northern California, Oregon, or Washington coasts.