Alexander Klonczynski

ポリマーから誘導されたケイ素系セラミックス ─合成・性質・応用に関する総説─

This review presents the synthesis, characterization techniques, processing and potential applications of silicon-based ceramic materials derived from organosilicon polymers. The Si-ceramics are prepared by thermolysis of molecular precursors. The influence of the initial molecular structure of the precursor on the properties of the final ceramic material and its applications is discussed. The thermolytic decomposition of suitable Si-based polymers provides materials which are denoted as polymer-derived ceramics (PDCs). In particular, this procedure is a promising method for the preparation of ternary and multinary silicon-based ceramics in the system SiCNO. There is no other synthetic approach known to produce e.g. SiCO or SiCN based ceramics. In the case of PDCs route, common preceramic polymers are poly(organosilazanes), poly (organosilylcarbodiimides) and poly (organosiloxanes). One basic advantage of the PDC route is that the materials can be easily shaped in form of fibers, layers or bulk composite materials by applying processing techniques established in the plastic industry. The PDCs in general exhibit enhanced thermomechanical properties, i.e., temperature stabilities up to approximately 1500°C. Recent investigations have shown that in some cases the high temperature stability in terms of decomposition and/or crystallization can be increased even up to 2000°C if the preceramic polymer contains some amount of boron. The composition and microstructure of the PDC are a result of the molecular structure of the preceramic polymer. Therefore, the observed differences in the macroscopic properties are also closely related to the variation of composition and solid state structure of these materials.

Crack Propagation and Detection in PZT-Multilayer Ceramics

Piezo multilayer ceramics are increasingly used under extreme condition such as high pressures in engine injection systems. The mechanical stability and reliability of the ceramic multilayer is of major importance for proper operation. Critical functional defects are caused by material fracture and flaw extension in the device. The flaw propagation in PZT-multilayer ceramics under mechanical load was examined using impedance spectroscopy and three-point-bending studies. Initial flaws were generated by applying a sinus ac-field on the specimens. The cracks were successively promoted and after the release of the external mechanical load the impedance spectroscopy was conducted. As a measure for flaw extension, the shift in the resonance frequencies and the sub-resonance height of the impedance spectroscopy was used. A functional dependence of the resonance frequency and the phase shift on the crack length was found. The crack propagation was studied on flaws starting at the positive and negative electrode, ...