Alexander M. Stolyarov

Multimaterial piezoelectric fibres

Fibre materials span a broad range of applications ranging from simple textile yarns to complex modern fibre-optic communication systems. Throughout their history, a key premise has remained essentially unchanged: fibres are static devices, incapable of controllably changing their properties over a wide range of frequencies. A number of approaches to realizing time-dependent variations in fibres have emerged, including refractive index modulation, nonlinear optical mechanisms in silica glass fibres and electroactively modulated polymer fibres. These approaches have been limited primarily because of the inert nature of traditional glassy fibre materials. Here we report the composition of a phase internal to a composite fibre structure that is simultaneously crystalline and non-centrosymmetric. A ferroelectric polymer layer of 30 mum thickness is spatially confined and electrically contacted by internal viscous electrodes and encapsulated in an insulating polymer cladding hundreds of micrometres in diameter. The structure is thermally drawn in its entirety from a macroscopic preform, yielding tens of metres of piezoelectric fibre. The fibres show a piezoelectric response and acoustic transduction from kilohertz to megahertz frequencies. A single-fibre electrically driven device containing a high-quality-factor Fabry-Perot optical resonator and a piezoelectric transducer is fabricated and measured.

In-Fiber Semiconductor Filament Arrays

We report a novel physical phenomenon in which a cylindrical shell undergoing a scaling process evolves into an ordered array of filaments upon reaching a characteristic thickness. We observe that the tendency to breakup is related to the material viscosity in a manner reminiscent of capillary instability. However, unlike the classical breakup of a fluid cylinder into droplets, the structural evolution in our system occurs exclusively in the cross sectional plane while uniformity is maintained in the axial direction. We propose a fluid front instability mechanism to account for the observed phenomena. The fleeting evolution of fluid breakup from a thin film to a filament array is captured in the frozen state by a thermal drawing process which results in extended lengths of solid sub-100 nm filaments encapsulated within a polymer fiber. Hundreds of glassy semiconductor filament arrays are precisely oriented within a polymer fiber matrix making electrical connections trivial. This approach offers unique opportunities for fabrication of nanometer scale devices of unprecedented lengths allowing simplified access and connectivity.

All-in-Fiber Chemical Sensing

A new all-in-fiber trace-level chemical sensing approach is demonstrated. Photoconductive structures, embedded directly into the fiber cladding along its entire length, capture light emitted anywhere within the fibers hollow core and transform it directly into an electrical signal. Localized signal transduction circumvents problems associated with conventional fiber-optics, including limited signal collection efficiency and optical losses. This approach facilitates a new platform for remote and distributed photosensing.

Enhanced chemiluminescent detection scheme for trace vapor sensing in pneumatically-tuned hollow core photonic bandgap fibers

We demonstrate an in-fiber gas phase chemical detection architecture in which a chemiluminescent (CL) reaction is spatially and spectrally matched to the core modes of hollow photonic bandgap (PBG) fibers in order to enhance detection efficiency. A peroxide-sensitive CL material is annularly shaped and centered within the fibers hollow core, thereby increasing the overlap between the emission intensity and the intensity distribution of the low-loss fiber modes. This configuration improves the sensitivity by 0.9 dB/cm compared to coating the material directly on the inner fiber surface, where coupling to both higher loss core modes and cladding modes is enhanced. By integrating the former configuration with a custom-built optofluidic system designed for concomitant controlled vapor delivery and emission measurement, we achieve a limit-of-detection of 100 parts per billion (ppb) for hydrogen peroxide vapor. The PBG fibers are produced by a new fabrication method whereby external gas pressure is used as a control knob to actively tune the transmission bandgaps through the entire visible range during the thermal drawing process.

Bragg waveguides with low-index liquid cores.

The spectral properties of light confined to low-index media by binary layered structures is discussed. A novel phase-based model with a simple analytical form is derived for the approximation of the center of arbitrary bandgaps of binary layered structures operating at arbitrary effective indices. An analytical approximation to the sensitivity of the bandgap center to changes in the core refractive index is thus derived. Experimentally, significant shifting of the fundamental bandgap of a hollow-core Bragg fiber with a large cladding layer refractive index contrast is demonstrated by filling the core with liquids of various refractive indices. Confirmation of these results against theory is shown, including the new analytical model, highlighting the importance of considering material dispersion. The work demonstrates the broad and sensitive tunability of Bragg structures and includes discussions on refractive index sensing.

Fabrication and characterization of fibers with built-in liquid crystal channels and electrodes for transverse incident-light modulation

We report on an all-in-fiber liquid crystal (LC) structure designed for the modulation of light incident transverse to the fiber axis. A hollow cavity flanked by viscous conductors is introduced into a polymer matrix, and the structure is thermally drawn into meters of fiber containing the geometrically scaled microfluidic channel and electrodes. The channel is filled with LCs, whose director orientation is modulated by an electric field generated between the built-in electrodes. Light transmission through the LC-channel at a particular location can be tuned by the driving frequency of the applied field, which directly controls the potential profile along the fiber.

Direct atomic-level observation and chemical analysis of ZnSe synthesized by in situ high-throughput reactive fiber drawing.

We demonstrate a high-throughput method for synthesizing zinc selenide (ZnSe) in situ during fiber drawing. Central to this method is a thermally activated chemical reaction occurring across multiple interfaces between alternately layered elemental zinc- (Zn-) and selenium- (Se-) rich films embedded in a preform and drawn into meters of fiber at a temperature well below the melting temperature of either Zn or ZnSe. By depositing 50 nm thick layers of Zn interleaved between 1 μm thick Se layers, a controlled breakup of the Zn sheet is achieved, thereby enabling a complete and controlled chemical reaction. The thermodynamics and kinetics of this synthesis process are studied using thermogravimetric analysis and differential scanning calorimetry, and the in-fiber compound is analyzed by a multiplicity of materials characterization tools, including transmission electron microscopy, Raman microscopy, energy-dispersive X-ray spectroscopy, and X-ray diffraction, all resulting in unambiguous identification of ZnSe as the compound produced from the reactive fiber draw. Furthermore, we characterize the in-fiber ZnSe/Se97S3 heterojunction to demonstrate the prospect of ZnSe-based fiber optoelectronic devices. The ability to synthesize new compounds during fiber drawing at nanometer scale precision and to characterize them at the atomic-level extends the architecture and materials selection compatible with multimaterial fiber drawing, thus paving the way toward more complex and sophisticated functionality.

Asymmetric wave propagation in planar chiral fibers.

We demonstrate the realization of a two-dimensional chiral optical waveguide with an infinite translational symmetry that exhibits asymmetric wave propagation. The low-symmetry geometry of the cross-section that lacks any rotational and mirror symmetries shows in-principal directional asymmetric polarization rotation. We use general symmetry arguments to provide qualitative analysis of the waveguides eigenstates and numerically corroborate this using finite element simulation. We show that despite the only perturbative break of time-reversal symmetry via small modal losses, the structure supports a non-degenerate pair of co-rotating elliptical modes. We fabricated meters long fiber with a spiral structure and studied its optical properties.

Sub‐Micrometer Surface‐Patterned Ribbon Fibers and Textiles

The worldwide annual production volume of textiles is nearly one hundred million metric tons. Most of these undergo treatments to achieve specific properties, such as color, hydrophobicity, antimicrobial, or UV protection, using chemicals that lead to collateral environmental consequences. There is great interest in developing alternative and sustainable strategies to achieve textile functionality that do not involve chemical treatment. Here we present a thermal drawing approach to achieve fiber surface gratings on a rectangular cross-section. We demonstrate directional wetting properties as well as structural coloration based on the gratings. Periods down to ≈ 600 nm were established on the surface of a fiber. Fabrics displaying higher-order diffraction peaks in the visible regime were produced from surface-patterned fibers using convetional weaving machinery.

Preparation and transmission of low-loss azimuthally polarized pure single mode in multimode photonic band gap fibers

We demonstrate the preparation and transmission of the lowest loss azimuthally polarized TE₀₁₋ like mode in a photonic band gap (PBG) fiber. Using the nature of the mode and the properties of the band gap structure we construct a novel coupler that operates away from the band gaps center to enhance the differential losses and facilitate the radiative loss of hybrid fundamental fiber modes. Remarkably, even though the coupler is highly multimoded, a pure azimuthally polarized mode is generated after only 17 cm. Theoretical calculations verify the validity of this technique and accurately predict the coupling efficiency. The generation and single mode propagation of this unique azimuthally polarized, doughnut shaped mode in a large hollow-core fiber can find numerous applications including in optical microscopy, optical tweezers, and guiding particles along the fiber.