Alexander N. Larionov

The Vendian alkaline igneous suite of northern Timan: ion microprobe U–Pb zircon ages of gabbros and syenite

Abstract Near the Barents Sea coast in northern Timan, turbidites of probable Neoproterozoic age are intruded by pre-tectonic dolerites and a major suite of gabbros, granites and syenites (some nepheline bearing). Zircon ion microprobe dating of three plutons has yielded well-defined ages of 613–617 Ma. This alkaline igneous activity apparently represents a final phase of Vendian extensional magmatism prior to Timanian Orogeny. Previous work on late to post-orogenic calc-alkaline granites in the basement beneath the Pechora Basin, three hundred kilometres towards the SE, has yielded c. 550–560 Ma single zircon Pb-evaporation ages. These compositionally different intrusive suites are inferred to constrain the main phase of Timanian Orogeny to c. 610–560 Ma.

Grenvillian basement and a major unconformity within the Caledonides of Nordaustlandet, Svalbard

Abstract Variously deformed granites and migmatites underlie the Neoproterozoic successions of Nordaustlandet, Svalbard. New U Pb zircon investigations of two types of intrusions from Lapponiahalvoya, northwestern Nordaustlandet, have yielded ages of 939 ± 8 Ma (Kontaktberget granite) and 961 ± 17 Ma (Lappoinafjellet granite), confirming previous, less precise multi-grain, Pb Pb evidence of Grenvillian igneous activity. The Kontaktberget granite cuts metasediments (Brennevinsfjorden Group), that are tightly folded and are separated from overlying volcanic and volcaniclastic rocks (Kapp Hansteen Group) by a major discordance (the Botniahalvoya Unconformity). The latter has been mapped in northwestern Nordaustlandet and is inferred to exist in central areas between Vestfonna and Austfonna. The Kapp Hansteen Group, with associated intrusive quartz porphyries, are probably a late orogenic expression of the Grenvillian igneous activity. The lack of igneous rocks in the overlying Neoproterozoic succession (Murchisonfjorden Supergroup) suggests that the base of this major unit is also a significant unconformity. This new evidence emphasizes the importance of the belt of Grenvillian tectonothermal activity, referred to here as the Nordauslandet Orogeny, that reaches from the classical provinces of North America and southern Scandinavia, via the East Greenland Caledonides, into the high Arctic.

The Grenville-Sveconorwegian orogen in the high Arctic

Throughout the high Arctic, from northern Canada (Pearya) to eastern Greenland, Svalbard, Franz Josef Land, Novaya Zemlya, Taimyr and Severnaya Zemlya and, at lower Arctic latitudes, in the Urals and the Scandinavian Caledonides, there is evidence of the Grenville–Sveconorwegian Orogen. The latest orogenic phase ( c . 950 Ma) is well exposed in the Arctic, but only minor Mesoproterozoic fragments of this orogen occur on land. However, detrital zircons in Neoproterozoic and Palaeozoic successions provide unambiguous Mesoproterozoic to earliest Neoproterozoic ( c . 950 Ma) signatures. This evidence strongly suggests that the Grenville–Sveconorwegian Orogen continues northwards from type areas in southeastern Canada and southwestern Scandinavia, via the North Atlantic margins to the high Arctic continental shelves. The widespread distribution of late Mesoproterozoic detrital zircons far to the north of the Grenville–Sveconorwegian type areas is usually explained in terms of long-distance transport (thousands of kilometres) of either sediments by river systems from source to sink, or of slices of lithosphere (terranes) moved on major transcurrent faults. Both of these interpretations involve much greater complexity than the hypothesis favoured here, the former involving recycling of the zircons from the strata of initial deposition into those of their final residence and the latter requiring a diversity of microcontinents. Neither explains either the fragmentary evidence for the presence of Grenville–Sveconorwegian terranes in the high Arctic, or the composition of the basement of the continental shelves. The presence of the Grenville–Sveconorwegian Orogen in the Arctic, mainly within the hinterland and margins of the Caledonides and Timanides, has profound implications not only for the reconstructions of the Rodinia supercontinent in early Neoproterozoic time, but also the origin of these Neoproterozoic and Palaeozoic mountain belts.

A revised Aquitanian age for the emplacement of the Ronda peridotites (Betic Cordilleras, southern Spain)

The hot emplacement of the Ronda peridotites (Betic Cordilleras) developed a dynamothermal aureole and partial melts that led to the intrusion of granite dykes in the peridotites. Previous geochronological data place rather broad limits for this event between 22 and 19 Ma. Analyses of neocrystalline zircon rims from large zircon populations yield a U–Pb SHRIMP age of 22.3±0.7 Ma for the dynamothermal aureole formation, and intrusion ages of granite dykes between 22.6±1.8 and 21.5±3.8 support that conclusion. Therefore, these new ages provide a more robust constraint on the hot emplacement of the Ronda peridotites at middle crustal levels.

Zircon geochronology and trace element characteristics of eclogites and granulites from the Orlica-Śnieżnik complex, Bohemian Massif

U–Pb zircon geochronology and trace element analysis was applied to eclogites and (ultra)high-pressure granulites that occur as volumetrically subordinate rock bodies within orthogneisses of the Orlica-Śnieznik complex, Bohemian Massif. Under favourable circumstances such data may help to unravel protolith ages and yet-undetermined aspects of the metamorphic evolution, for example, the time span over which eclogite-facies conditions were attained. By means of ion-probe and laser ablation techniques, a comprehensive database was compiled for samples collected from prominent eclogite and granulite occurrences. The 206 Pb/ 238 U dates for zircons of all samples show a large variability, and no single age can be calculated. The protolith ages remain unresolved due to the lack of coherent age groups at the upper end of the zircon age spectra. The spread in apparent ages is interpreted to be mainly caused by variable and possibly multi-stage Pb-loss. Further complexities are added by metamorphic zircon growth and re-equilibration processes, the unknown relevance of inherited components and possible mixing of different aged domains during analysis. A reliable interpretation of igneous crystallization ages is not yet possible. Previous studies and the new data document the importance of a Carboniferous metamorphic event at c. 340 Ma. The geological significance of this age group is controversial. Such ages have previously either been related to peak (U)HP conditions, the waning stages of eclogite-facies metamorphism or the amphibolite-facies overprint. This study provides new arguments for this discussion because, in both rock types, metamorphic zircon is characterized by very low total REE abundances, flat HREE patterns and the absence of an Eu anomaly. These features strongly suggest contemporaneous crystallization of zircon and garnet and strengthen interpretations proposing that the Carboniferous ages document late-stage eclogite-facies metamorphism, and not amphibolite-facies overprinting.

Grenvillian and Caledonian tectono-magmatic activity in northeasternmost Svalbard

Abstract The Nordaustlandet Terrane of NE Svalbard forms an exposed part of the Barentsia microcontinent. Augen gneisses, migmatites, granites and gabbros dominate the scattered outcrops along the northeastern coast of Nordaustlandet, and on the smaller islands to the north and east, as far as Kvitøya. These outcrops probably represent the deepest exposed crustal levels within the folded Caledonian basement of the Nordaustlandet Terrane. In the present study, a variety of rock types have been analysed by different U-Pb dating techniques (conventional, Pb-evaporation and ion microprobe) on zircon, titanite and monazite The major and trace element compositions and Sm-Nd isotope geochemistry of these rocks have also been investigated. The augen gneisses yield U-Pb ages of c. 950 Ma, indicating that they are deformed late Grenvillian granites, similar to the Grenville-age granites and augen gneisses of northwestern and central Nordaustlandet. Migmatites, grey granites, aplitic dykes and a syenite (boulder) yield U-Pb ages mainly falling in the 430–450 Ma range, slightly older than the 410–420 Ma late-tectonic Caledonian granites further west. Both the Grenvillian and Caledonian granites are of crustal anatectic origin, and the Caledonian granites and migmatites may have formed largely by remelting of Grenvillian crust. The ages of the mafic rocks are uncertain, but Sm-Nd data indicate a possible emplacement age of c. 700 Ma for two of the gabbros, suggesting that they may be the result of rift-related magmatism in connection with the opening of the Iapetus Ocean. A few enigmatic inherited zircons of similar late Neoproterozoic age found in younger granites may possibly be related to this event. No evidence for late Neoproterozoic orogenic activity, similar to that in the Timanides of northern Russia, is seen in eastern Svalbard. At this time, eastern Svalbard (Barentsia) was probably part of the Laurentian margin, and probably located far away from northern Baltica.

Protolith age and provenance of metasedimentary rocks in Variscan allochthon units: U–Pb SHRIMP zircon data from the Orlica–Śnieżnik Dome, West Sudetes

New U–Pb sensitive high-mass resolution ion microprobe (SHRIMP) data from detrital zircons within the Orlica–Śnieznik Dome provide new insights into the stratigraphic and palaeogeographic position of assumed relict Precambrian basement preserved in the Variscan collisional orogen of the West Sudetes, SW Poland. Hitherto, the Mlynowiec Formation and the Stronie Formation within the Orlica–Śnieznik Dome were assumed to represent two metavolcano-sedimentary successions of Proterozoic and early Palaeozoic age, respectively. However, when previous U–Pb data and mapping data from the Orlica–Śnieznik Dome are combined with the new detrital zircon isotopic ages both from paragneisses within the Mlynowiec Formation and from light-coloured quartzites and mica schists within the Stronie Formation, the result strongly suggests that the protoliths of these two formations actually form a continuous succession. This continuous succession is herein designated the Mlynowiec–Stronie Group. The rocks of this group were deposited during middle Cambrian–early Ordovician times ( c. 520–470 Ma), presumably at the northern edge of West Gondwana after the 10–20 Ma period of tectonic quiescence that followed the terminal stage of the Cadomian collisions. Monotonous Mlynowiec metagreywackes form the lower part of the succession, and the lithologically diverse schistose Stronie Formation forms its upper part. The change from greywacke (Mlynowiec) to volcano-sedimentary (Stronie) facies coincided with the onset of rather short-lived volcanic activity which climaxed around 505–495 Ma and which supplied the volcanogenic components to the Stronie Formation. No ‘Cadomian unconformity’ has been observed in the region. Xenocrystic zircons from the Mlynowiec–Stronie Group retain records of Archaean (3.0–2.3 Ga), Palaeoproterozoic (2.1–1.8 Ga) and Neoproterozoic to early Cambrian (660–530 Ma) zircon-forming events. These zircon ages, together with the lack of 1.7–1.2 Ga zircon ages, suggest that the source areas for the metasedimentary rocks may have been the West Africa craton, which therefore differs from the Amazonian affinity of the adjacent Brunovistulia Terrane. Nevertheless, two zircons, c. 1.0 and 1.1 Ga old, respectively, indicate that the Mlynowiec–Stronie Group sedimentary basin must have still been within the delivery reach of detritus ultimately derived from the Grenvillian-age belt(s). The detrital components of the supracrustal formations of the Orlica–Śnieznik Dome were mainly derived from Neoproterozoic zircon-bearing crystalline rocks that were accreted to, and included in, the Cadomian basement in several intrusive pulses that culminated at 660–640 Ma, 620 Ma and 570–530 Ma.

SHRIMP U-Th-Pb zircon dating of the granitoid massifs in the Malé Karpaty Mountains (Western Carpathians): evidence of Meso-Hercynian successive S- to I-type granitic magmatism

SHRIMP U-Th-Pb zircon dating of the granitoid massifs in the Malé Karpaty Mountains (Western Carpathians): evidence of Meso-Hercynian successive S- to I-type granitic magmatism Representative granitic rock samples from the Malé Karpaty Mountains of the Western Carpathians (Slovakia) were dated by the SHRIMP U-Th-Pb isotope method on zircons. Oscillatory zoned zircons revealed concordant Mississippian magmatic ages: 355±5 Ma in Bratislava granodiorite, and 347±4 Ma in Modra tonalite. The results document nearly synchronous, successive Meso-Hercynian plutonic events from S-type to I-type granites. The Neo-Proterozoic inherited zircon cores (590±13 Ma) were identified in the Bratislava S-type granitic rocks whereas scarce Paleo-Proterozoic inherited zircons (1984±36 Ma) were detected within the Modra I-type tonalites.

Single‐zircon Pb‐evaporation and 40Ar/39Ar dating of the metamorphic and granitic rocks in north‐west Spitsbergen

North-west Spitsbergen consists of a complex of Caledonian and Grenvillian crystalline rocks, situated at the north-west corner of the Barents Shelf. The aim of this study is to understand the extent of pre-Caledonian basement rocks and their protoliths. Micas and zircon grains from six rocks from north-west Spitsbergen have been dated by the 40Ar/39Ar and single-zircon Pb-evaporation methods. Two grey granites yielded Late Caledonian mica 40Ar/39Ar and zircon ages of ca. 420-430 My, with inherited zircon grains as old as 1725 My. Zircon grains from a gneissose granite xenolith in a grey granites gave crystallization ages of ca. 960 My; some grains from a migmatite neosome show similar ages. Zircon grains yielding Archean and late Palaeoproterozoic ages (1600-1800 My) are interpreted as xenocrysts of detrital origin. The youngest ages obtained from detrital zircon grains from a greenschist facies quartzite of the Signehamna unit are ca. 1800 My. Similar schists are included as xenoliths in the 960 My old gneissose granite; therefore, the sedimentary protoliths of the unit are Mesoproterozoic. The dating results suggest a significant tectonothermal event during Grenvillian time; subsequent Caledonian events had less extensive thermal effects. However, it is still a matter of debate whether Grenvillian or Caledonian metamorphism produced the majority of the migmatites. A large population of zircon grains with Late Palaeoproterozoic ages suggests a wide surface exposure of rocks of this age in the source area, with some Archean zircons.

Caledonian granites of western and central Nordaustlandet, northeast Svalbard

Abstract The Nordaustlandet Terrane of northeast Svalbard is the easternmost of the Caledonian terranes of the Svalbard archipelago. Here, a Grenville-age basement is overlain by Neoproterozoic to Early Palaeozoic platform sediments, and intruded by Caledonian granites. These include the Nordkapp, Rijpfjorden and Winsnesbreen granites of western and central Nordaustlandet, which are peraluminous, crustal anatectic two-mica granites, formed in a Caledonian late- to post-tectonic setting. Sm-Nd isotope characteristics show them to have formed largely by anatexis of the Grenvillian crust, which is supported by the presence of abundant Grenville-age and earlier Mesoproterozoic inherited zircons. U-Pb dating of new-formed zircon overgrowths and whole crystals using the NORDSIM ion microprobe, as well as conventional U-Pb dating of monazite, and single zircon and monazite Pb-evaporation dating, yield ages of 440–410 Ma, indicating formation during the main, Silurian to early Devonian stage of the Caledonian Orogeny. These results show the importance of applying single crystal Pb-evaporation and ion microprobe spot analyses for the dating of complex zircons in crustal anatectic granites containing abundant inherited material.