Alice R. Melland

The seasonality of phosphorus transfers from land to water: Implications for trophic impacts and policy evaluation

The Nitrates Directive regulations are a Programme of Measures under the EU Water Framework Directive to protect waters from agricultural transfers of nitrogen and phosphorus. Soil phosphorus management to an agronomic optimum and closed winter periods for organic and inorganic fertiliser amendments are among a suite of policy measures to curtail diffuse pollution at catchment scale. In this investigation, two intensive grassland and two arable catchments (7-12 km(2)) in the Republic of Ireland were studied to link a high resolution spatial survey (≤2 ha) of soil P availability with P delivery in receiving rivers; monitored on a sub-hourly basis over one year. Data indicated that source risk, as defined by soil P availability and organic P loading, was less important than mobilisation and hydrological transfer potential which increased delivery due to runoff flashiness as described by a hydrological metric during the winter. Overall, however, annual TP loads were low to moderate (0.175 to 0.785 kg ha(-1) yr(-1)). The data also highlighted, without exception, the influences of summer background P loading and subsequent ecologically significant P concentrations from persistent point sources. This may have implications for expected ecological status and recovery in these catchments, which appeared more at risk in catchments with little buffering in terms of summer base flow dilution. Wetter winters and drier summers under climate change scenarios would likely increase stream P concentrations both during storms and during baseflows and would be particularly magnified in those catchments with flashy runoff and suppressed baseflow. These seasonal insights into source-to-delivery functions and risk (re)assessment were only possible with high resolution (spatial and temporal) data collection and will be important in influencing expectations of policies that are evaluated at larger scales but with coarser resolution sampling.

Loss of phosphorus and nitrogen in runoff and subsurface drainage from high and low input pastures grazed by sheep in southern Australia

High rates of fertiliser applied to boost pasture growth in the southern Australian sheep industry may lead to eutrophication of waterways and groundwater degradation. A field study was used to investigate whether higher fertiliser and stocking rates would increase nutrient loss in runoff and subsurface flow from pastures. Phosphorus (P) and nitrogen (N) concentrations in surface and subsurface flow were measured from 1998–2000 in four 0.5-ha hillslope plots. Surface flow volume was measured directly and subsurface water flux was estimated using soil moisture data and a water balance model. A simulated rainfall study was also conducted using 0.64-m2 plots. The treatments represented were: a low-P set-stocked sown pasture (SS low P), a high-P set-stocked sown pasture (SS high P), a high-P sown pasture in a 4-paddock rotation (RG 4-pdk), and an unsown set-stocked pasture (Low P volunteer). No runoff from the hillslope occurred in 1999, while the volume of runoff in 1998 and 2000 varied from 0.1 to 68 mm/year across the 4 hillslope plots. More P was lost via surface runoff (up to 0.25 kg P/ha.year) than subsurface flow (up to 0.027 kg P/ha.year). However, N loads were greater in subsurface flows (3.2–10.6 kg N/ha.year) than surface runoff (0.04–2.74 kg N/ha.year). Phosphorus concentrations were higher in runoff from the high P treatments (0.34–0.83 mg P/L) than the set-stocked low P treatment (0.19–0.22 mg P/L). Higher TP concentrations in runoff from the high P treatments were associated with greater labile P contents in the soil, dung, and herbage. However, the volume of runoff, rather than the pasture treatment, was the primary determinant of nutrient loss. Avoiding high nutrient inputs in seasonally waterlogged areas, sowing perennial pastures, and minimising stock camping helps minimise P losses to waterways and N losses to groundwater.

Evaluating the critical source area concept of phosphorus loss from soils to water-bodies in agricultural catchments

Using data collected from six basins located across two hydrologically contrasting agricultural catchments, this study investigated whether transport metrics alone provide better estimates of storm phosphorus (P) loss from basins than critical source area (CSA) metrics which combine source factors as well. Concentrations and loads of P in quickflow (QF) were measured at basin outlets during four storm events and were compared with dynamic (QF magnitude) and static (extent of highly-connected, poorly-drained soils) transport metrics and a CSA metric (extent of highly-connected, poorly-drained soils with excess plant-available P). Pairwise comparisons between basins with similar CSA risks but contrasting QF magnitudes showed that QF flow-weighted mean TRP (total molybdate-reactive P) concentrations and loads were frequently (at least 11 of 14 comparisons) more than 40% higher in basins with the highest QF magnitudes. Furthermore, static transport metrics reliably discerned relative QF magnitudes between these basins. However, particulate P (PP) concentrations were often (6 of 14 comparisons) higher in basins with the lowest QF magnitudes, most likely due to soil-management activities (e.g. ploughing), in these predominantly arable basins at these times. Pairwise comparisons between basins with contrasting CSA risks and similar QF magnitudes showed that TRP and PP concentrations and loads did not reflect trends in CSA risk or QF magnitude. Static transport metrics did not discern relative QF magnitudes between these basins. In basins with contrasting transport risks, storm TRP concentrations and loads were well differentiated by dynamic or static transport metrics alone, regardless of differences in soil P. In basins with similar transport risks, dynamic transport metrics and P source information additional to soil P may be required to predict relative storm TRP concentrations and loads. Regardless of differences in transport risk, information on land use and management, may be required to predict relative differences in storm PP concentrations between these agricultural basins.

Quantification of phosphorus transport from a karstic agricultural watershed to emerging spring water

The degree to which waters in a given watershed will be affected by nutrient export can be defined as that watersheds nutrient vulnerability. This study applied concepts of specific phosphorus (P) vulnerability to develop intrinsic groundwater vulnerability risk assessments in a 32 km(2) karst watershed (spring zone of contribution) in a relatively intensive agricultural landscape. To explain why emergent spring water was below an ecological impairment threshold, concepts of P attenuation potential were investigated along the nutrient transfer continuum based on soil P buffering, depth to bedrock, and retention within the aquifer. Surface karst features, such as enclosed depressions, were reclassified based on P attenuation potential in soil at the base. New techniques of high temporal resolution monitoring of P loads in the emergent spring made it possible to estimate P transfer pathways and retention within the aquifer and indicated small-medium fissure flows to be the dominant pathway, delivering 52-90% of P loads during storm events. Annual total P delivery to the main emerging spring was 92.7 and 138.4 kg total P (and 52.4 and 91.3 kg as total reactive P) for two monitored years, respectively. A revised groundwater vulnerability assessment was used to produce a specific P vulnerability map that used the soil and hydrogeological P buffering potential of the watershed as key assumptions in moderating P export to the emergent spring. Using this map and soil P data, the definition of critical source areas in karst landscapes was demonstrated.

Storm Event Suspended Sediment-Discharge Hysteresis and Controls in Agricultural Watersheds: Implications for Watershed Scale Sediment Management

Within agricultural watersheds suspended sediment-discharge hysteresis during storm events is commonly used to indicate dominant sediment sources and pathways. However, availability of high-resolution data, qualitative metrics, longevity of records, and simultaneous multiwatershed analyses has limited the efficacy of hysteresis as a sediment management tool. This two year study utilizes a quantitative hysteresis index from high-resolution suspended sediment and discharge data to assess fluctuations in sediment source location, delivery mechanisms and export efficiency in three intensively farmed watersheds during events over time. Flow-weighted event sediment export was further considered using multivariate techniques to delineate rainfall, stream hydrology, and antecedent moisture controls on sediment origins. Watersheds with low permeability (moderately- or poorly drained soils) with good surface hydrological connectivity, therefore, had contrasting hysteresis due to source location (hillslope versus channel bank). The well-drained watershed with reduced connectivity exported less sediment but, when watershed connectivity was established, the largest event sediment load of all watersheds occurred. Event sediment export was elevated in arable watersheds when low groundcover was coupled with high connectivity, whereas in the grassland watershed, export was attributed to wetter weather only. Hysteresis analysis successfully indicated contrasting seasonality, connectivity and source availability and is a useful tool to identify watershed specific sediment management practices.

SGS Nutrient Theme: environmental assessment of nutrient application to extensive pastures in the high rainfall zone of southern Australia

To assess the risks and benefits of more intensive pasture management, 2 or 3 treatments with contrasting fertiliser regimes were selected from each site of the Sustainable Grazing Systems national experiment. The assessment used soil coring data, modelling and runoff nutrient concentration data. Soil acidification rates were estimated from the simulated nitrate leaching and product removal estimated from the stocking rates at each site. Much higher acidification rates were estimated at sites in Victoria and southern Western Australia than in northern New South Wales. This was because of a lower level of nitrate leaching in summer-dominant rainfall environments coupled with lower stocking rates. Simulations showed highest nitrate leaching on annual pastures, but that a phalaris pasture could reduce this, and a kikuyu pasture could almost fully control leaching. The concentration of P in surface runoff was related to soil P status at the 4 southern sites, indicating that greater use of P fertiliser would increase P movement into waterways. There was no relationship between soil P status and P in surface runoff at the northern New South Wales sites, and across all sites there were no relationships between P fertility and runoff N levels. Concentrations of P and N in runoff greatly exceeded stream water quality guidelines, even on treatments where only minimal P had been applied as fertiliser. There was also evidence of high spatial variation in surface runoff generation, with surface runoff from some plots less than 5% of the streamflow in nearby reference streams. There is therefore scope to control P concentrations in streams by retiring from production the parts of the landscape that generate high quantities of surface flow, but to intensify production on areas that produce little runoff.

Integrating farming systems and landscape processes to assess management impacts on suspended sediment loads

A catchment-scale framework was developed to assess the contribution of sediment sources from farm management actions, gully and streambank erosion on the suspended sediment loads delivered to rivers and associated wetlands and floodplains for two catchments (Avon Richardson, 2885 km^2 and Avoca, 4550 km^2) in Victoria, south-eastern Australia. After considering commonly available data sets, outputs from the point-scale model (HowLeaky2008) were coupled to a catchment scale framework (CatchMODS). Spatially constant, linear scaling factors were used to link point-scale water surplus to streamflow and gross soil loss to hillslope erosion. The model was calibrated against discharge and suspended sediment loads estimated at water quality monitoring gauging stations. Following calibration, estimates of annual and monthly streamflow and 10-year average annual sediment loads were in good agreement with observations. Catchment-scale outputs, particularly sediment loads, were sensitive to scaling factors. The high sensitivity coupled with limited data hindered tight identification of sediment scaling parameters, therefore sediment outputs were uncertain, particularly in the Avoca catchment. Propagation of uncertainty in parameter estimation to model estimates was assessed qualitatively. The boundaries of model estimations were assessed by retaining predictions of behavioural parameter sets, defined as parameter sets that resulted in efficiencies of sediment load and specific sediment yield estimations not more than 5% lower than the efficiency of the optimal parameter set. Under current management conditions, mean annual suspended sediment load at the Avon-Richardson catchment outlet was estimated to be 3350 (3300-3700) t y^-^1, of which hillslope erosion contributed 65% (60-80%) and gully erosion 35% (20-40%). In the Avoca catchment, annual suspended sediment load was estimated to be 4000 (3500-5100) t y^-^1, of which hillslope erosion contributed 17% (5-24%), gully erosion 72% (55-93%), and streambank erosion 11% (1-21%). In the Avon-Richardson catchment management scenarios showed that alternative farming systems focussed on retaining vegetation cover throughout the year would yield a 50 per cent reduction of suspended sediment load, estimated at 1700 t y^-^1. In contrast, fencing and revegetation of connected gullies was estimated to yield the largest reduction in suspended sediment load (1770 t y^-^1, 44% of current load) in the Avoca catchment. The framework provides an improved tool to make more informed decisions about how much suspended sediment loads can be reduced in response to farm management actions, gully and streambank protection. Its primary strength lies in the ability to propagate farm management impacts to the catchment scale. Other valuable features for use by natural resource management agencies include a high level of transparency, availability of user-friendly interfaces, and a modular structure that provides flexibility and adaptability to new systems.

Delivery and impact bypass in a karst aquifer with high phosphorus source and pathway potential

Conduit and other karstic flows to aquifers, connecting agricultural soils and farming activities, are considered to be the main hydrological mechanisms that transfer phosphorus from the land surface to the groundwater body of a karstified aquifer. In this study, soil source and pathway components of the phosphorus (P) transfer continuum were defined at a high spatial resolution; field-by-field soil P status and mapping of all surface karst features was undertaken in a > 30 km(2) spring contributing zone. Additionally, P delivery and water discharge was monitored in the emergent spring at a sub-hourly basis for over 12 months. Despite moderate to intensive agriculture, varying soil P status with a high proportion of elevated soil P concentrations and a high karstic connectivity potential, background P concentrations in the emergent groundwater were low and indicative of being insufficient to increase the surface water P status of receiving surface waters. However, episodic P transfers via the conduit system increased the P concentrations in the spring during storm events (but not >0.035 mg total reactive P L(-1)) and this process is similar to other catchments where the predominant transfer is via episodic, surface flow pathways; but with high buffering potential over karst due to delayed and attenuated runoff. These data suggest that the current definitions of risk and vulnerability for P delivery to receiving surface waters should be re-evaluated as high source risk need not necessarily result in a water quality impact. Also, inclusion of conduit flows from sparse water quality data in these systems may over-emphasise their influence on the overall status of the groundwater body.

Trialling a web-based spatial information management tool with Land Managers in Victoria, Australia

A prototype web-based spatial information management tool (called eFarmer) was tested for its useability and usefulness by 46 Land Managers and 5 extension staff in Victoria, Australia. Participants had a range of enterprises (dairy, beef/sheep grazing, cropping, lifestyle land use), property sizes and computer ownership and expertise. A follow up study was conducted with 12 dairy farmers, where features regarding assessment of nutrient losses from paddocks (Farm Nutrient Loss Index, FNLI) were added to eFarmer. Over 27,000 maps (including 11,000 with aerial photography) were accessed by Land Managers during a 5-month trial period. Despite limited training and support, 1350 people are registered users, and approximately 700 have actively used the tool. Reasons for the success include providing improved access to spatial information, enabling measurement of farm features and creation of farm maps, providing a basis for decision-making about farm inputs, support for better farm and landscape scale action planning and production and Land Managers being able to seek management advice from the extension staff who facilitated eFarmer testing programs. For dairy farmers in the FNLI trial, awareness of off-site impacts increased and most changed management practices. Provision of on-going training and support will be at least as important as further development of the tool itself. Web-based spatial information tools have potential to improve the awareness of Land Managers about their environmental impacts and influence their decision-making. Access to spatial information has potential to reduce information asymmetry between Land Managers, extension staff and catchment planners in a constructive way. It will also change the role of extension staff away from being an expert with answers, to a facilitator enabling learning. Results have applicability in countries where there is a high level of farm computer ownership, relevant spatial information is available in GIS format, where governments are happy to make spatial information available to the public and there is pressure for increased environmental awareness and improved decision making by Land Managers.

Dairying and water-quality issues in Australia and New Zealand

The scale and intensity of dairy farming can place pressure on our freshwater resources. These pressures (e.g. excessive soil nutrient concentrations and nitrogen excretion) can lead to changes in the levels of contaminants in waterways, altering the state and potentially affecting the uses and values society ascribes to water. Resource management involves putting in place appropriate responses to address water-quality issues. In the present paper, we highlight trends in the scale and extent of dairying in Australia and New Zealand and describe water-quality pressures, state, impacts and responses that characterise the two countries. In Australia and New Zealand, dairy farming has become increasingly intensive over the past three decades, although the size of Australia’s dairy herd has remained fairly static, while New Zealand’s herd and associated excreted nitrogen loads have nearly doubled. In contrast, effluent management has been improved, and farm waterways fenced, in part to reduce pressure on freshwater. However, both countries show a range of indicators of degraded water-quality state. Phosphorus and nitrogen are the most common water-quality indicators to exceed levels beyond the expected natural range, although New Zealand also has a significant percentage of waterways with faecal contaminants beyond acceptable levels for contact recreation. In New Zealand, nitrate concentrations in waterways have increased, while phosphorus and suspended sediment concentrations have generally decreased over the past decade. Water quality in some coastal estuaries and embayments is of particular concern in Australia, whereas attention in New Zealand is on maintaining quality of high-value lakes, rivers and groundwater resources, as well as rehabilitating waterbodies where key values have been degraded. In both Australia and New Zealand, water-quality data are increasingly being collated and reported but in Australia long-term trends across waterbodies, and spatially comprehensive groundwater-quality data have not yet been reported at national levels. In New Zealand, coastal marine systems, and particularly harbours and estuaries, are poorly monitored, but there are long-term monitoring systems in place for rivers, groundwater and lakes. To minimise pressures on water quality, there is a high reliance on voluntary and incentivised practice change in Australia. In New Zealand, industry-led practice change has been important over the past decade, but regulated environmental limits for dairy farmers are increasing. Dairy industries in both countries have set targets for reducing pressures through sustainability frameworks and accords. To address future drivers such as climate change and increasing domestic and international market demand for sustainability credentials, definitions of values and appropriate targets for waterbodies draining agricultural landscapes will be required. Environmental limits (both natural and societal) will constrain future growth opportunities for dairying and research into continued growth within limits remains a priority in both countries.