Alida Timar-Gabor

A high resolution optical dating study of the Mostiştea loess-palaeosol sequence (SE Romania) using sand-sized quartz

We report on SAR-OSL dating of closely-spaced samples from the loess-palaeosol sequence near Mostiştea lake (Danube Plain, SE Romania). We used sand-sized quartz and a SAR protocol that involved a preheat of 10s at 220°C and a test dose cutheat to 180°C. It is shown that these thermal pretreatments isolate a quartz OSL signal that is dominated by the fast component. The behaviour of this signal in the SAR protocol is then documented. The ratio of the measured to given dose tends to lie slightly but systematically above unity (∼5% on average) and the recycling ratio below unity (∼6% on average); for all samples, the recuperated signal is negligible. Within analytical uncertainty, the nineteen optical ages are internally consistent and agree with the predictions from a palaeomagnetic age-depth model. Although it may be possible to optimize the SAR measurement procedure, the optical ages already confirm the chronostratigraphic position of the uppermost welldeveloped palaeosol in that it formed during MIS 5. The established chronology allows correlating the sequence near Mostiştea lake with that near Mircea VodĂ that we investigated earlier.

Multi-method luminescence investigations on quartz grains of different sizes extracted from a loess section in Southeast Romania interbedding the Campanian Ignimbrite ash layer

In this study we present luminescence investigations of four samples of loess bracketing the Campanian Ignimbrite/Y5 tephra at the Rasova-Valea cu Pietre site, on the eastern bank of the Danube River, southeastern Romania. Investigations involved SAR-OSL dating on aliquots of fine (4–11 μm) and medium-grained (63–90 μm) quartz, as well as single grain analyses on 125–180 μm quartz. Luminescence dating results coupled with glass-shard chemical fingerprinting assign the depositional age and origin of the ash layer to that of the Campanian Ignimbrite/Y5 tephra, dated elsewhere using 40Ar/39Ar to 39.28 ± 0.11 ka. Fine-grained (4–11 μm) quartz SAR-OSL analyses yielded ages of 44.4 ± 4.5 ka below the ash, and 41.4 ± 4.2 ka above the ash layer. Single grain analysis on coarse-grained quartz, however, demonstrates that coarse material from these samples exhibits low sensitivity and responds poorly to internal checks of the SAR protocol in comparison with the finer sediment. This observation highlights the need for more extensive investigations into the luminescence properties of quartz as well as into the origin of quartz contributions from different primary sources in the Lower Danube loess steppe.

A sedimentation study of St. Ana Lake (Romania) applying the 210Pb and 137Cs dating methods

The biggest problem with most lakes that have no contact with other water sources and are being charged by precipitation is the massive eutrophication. The aim of this work was to determine the sedimentation rate in order to evaluate the progress of eutrophication for St. Ana Lake (Ciomad Mountain near the Băile Tuşnad in Harghita County (Romania)). The concentration of 210Pb was determined by means of high resolution gamma spectrometry as well as derived from 210Po activity which was measured through alpha spectrometry; values obtained are in good agreement. For the excess 210Pb activity values between 4.0±0.5 Bq/kg and 218±20 Bq/kg have been found. As an alternative method, the 137Cs dating method was applied as well. Calculated mass sedimentation rates are in the range of 0.06±0.01 to 0.32±0.05 g/cm2 year with a mean of value of 0.15±0.02 g/cm2 year. Linear sedimentation rates yielded much higher sedimentation values (between 0.5±0.1 and 7.9±0.7 cm/year with a mean of 2.4±0.6 cm/year), due to the predominant organic matter composition and the long suspension time of the sediment. This is an indication for the process of eutrophication which will probably lead to the transformation of the lake into a peat bog.

Sediment dynamics and heavy metal pollution history of the Cruhlig Lake (Danube Delta, Romania)

This is the first study reporting recent sedimentation rates data (e.g. the past 120-150 years) for the Cruhlig Lake situated in the Danube Delta. The aim of this study is to analyse the recent sedimentation rates using the (210)Pb dating method and identifying the heavy metal pollutants and their variability in time. Five sediment cores were taken with a gravity corer and - after drying the sliced samples-physical parameters, organic material and inorganic carbon content were determined. The total (210)Pb content was measured via (210)Po by alpha spectrometry, while supported (210)Pb was measured by (226)Ra (trough short life (222)Rn daughters) with HPGe detectors. Heavy metals were determined by ICP-MS; from the 64 measured elements, only exceeding values of Al, As, Cd, Co, Cs, Cr, Cu, Fe, Hg, K, Li, Mg, Mn, Ni, Pb and Zn are discussed. After applying the CRS model, ages and sedimentation rates were calculated. The average sedimentation rate of the Cruhlig Lake is 0.21 ± 0.02 g/cm(2)y, Minimum values (0.05 ± 0.003 g/cm(2)y) are registered along the eastern shoreline of the lake before 1913, while maximum values are recorded due to the flooding in 2006 in the western side (1.34 ± 0.12 g/cm(2)y). Recent sedimentation rates divide the lake into three areas: the secluded eastern near shore part (0.63 ± 0.07 g/cm(2)y), the centre of the lake (0.92 ± 0.05 g/cm(2)y) and the dynamic western area, where most sediment transport takes place (1.13 ± 0.01 g/cm(2)y). The sedimentation pattern proves this lake to be very sensitive to fluvial discharge fluctuations. The building of the Iron Gate dams (1972 and 1985) had a negative impact on the sedimentation decreasing it with 58.74%, while after 1989 these values grew 2.25 times. The lake received a quantity of sediment rich in heavy metals in 1992 ± 3 y, which settled mostly on the eastern part. Values for Cd, Co, Cr, Hg, Pb and Zn are up to five times higher in 1980 ± 5 y in the eastern part of the lake, while Cd, Co, Cr and Ni are twice as high as the values measured for the marine substrate. Values of As show increasing of up to 150% in 2006 ± 2 y throughout the whole surface of the lake.

The Lower Danube Loess, New Age Constraints from Luminescence Dating, Magnetic Proxies and Isochronous Tephra Markers

Loess and loess-derivative deposits currently form some of the most ubiquitous sedimentary landforms in Europe, including important parts of Romania. Loess-palaeosol sequences (LPS) are continental archives of Quaternary paleoclimates since these deposits are a direct product of geomorphic processes driven by past climate variability. Understanding these processes needs data input provided by absolute chronologies. Loess is generally considered an ideal material for the application of luminescence dating. In this chapter, we present a review of the latest methodological advances in constraining the chronology of several key Romanian LPS alongside the dating of several loess-alluvial deposits that harbour tephra layers. Luminescence chronologies as well as time-depth models based on magnetic susceptibility variations assign the topmost loess layer to the last glacial cycle that comprises, according to the north European stratigraphic terminology, the Weichselian glaciation (Marine Isotope Stage (MIS) 4 and MIS 2 phases). The uppermost palaeosol is assigned to MIS5 especially to the Eemian interglacial (MIS5e), an equivalent to the north European stratigraphy, and to the Riss–Wurm interglacial in the Alpine stratigraphy. As proved by the high-resolution chronologies, the sedimentation rates of loess varied during the last glacial both within a specific loess section, as well as between different loess sections, the major controlling factor being the topographic context. The luminescence chronologies discussed here improved and expanded the long-held stratigraphy of Romanian loess constructed decades ago by using relative methods, suggesting that a re-evaluation of the regional chronostratigraphic inferences in a high-resolution absolute dating approach has to be conducted.

SAR-OSL dating of Late Pleistocene loess in Southern Romania using fine and coarse-quartz

Loess deposits cover significant areas in Europe, extending from NW-France and Belgium through to central Europe, the Ukraine and Western Russia. The loess palaeosol sequences of the Carpathian Basin-Lower Danube region (Romania, Serbia and Bulgaria) are thought to represent the most continuous and high resolution archives of regional climate and environmental change during the Late and Middle Pleistocene in SE Europe and a link between similar deposits in central Europe and Eurasia. However, in comparison to other loess sequences elsewhere in Western, Central and Eastern Europe, the deposits in Romania have been much less extensively studied. Luminescence dating is, at present, the only method that allows establishing an absolute chronology for loess deposits by virtue of its ability to directly date the moment of sediment deposition. Moreover, the aeolian nature of loess ensures that the luminescence signal is completely reset prior to deposition, a prime requisite for luminescence dating. Thus, loess sediments are ideal materials for developing, testing and applying luminescence techniques. This approach is essential for securely linking loess records from Romania in a chronologically reliable regional framework and to extend this information to other sites from central and eastern European loess belt, in order to understand past paleoenvironmental dynamics at both regional and continental scales.

Assessing the maximum limit of SAR-OSL dating using quartz of different grain sizes

Abstract SAR-OSL dating studies of Romanian, Serbian and Chinese loess using fine and coarse quartz have previously resulted in a series of controversial issues. We extend here the investigations using fine (4–11 μm) and different coarse quartz (>63 μm) grains extracted from aeolianites from a site on Eivissa Island (southwestern Mediterranean). Aeolianites were chosen since they contain quartz from a different geological context and have significantly lower environmental dose rates. The dose response curves of the OSL signals for fine and coarse quartz are similar to those for loess and are also represented by the sum of two saturating exponential functions. For doses up to ~200 Gy, the dose response curves of fine and coarse grains from aeolianites can be superimposed and the ages obtained for the different grain sizes are in agreement up to ~250 ka, increasing our confidence in the accuracy of the ages obtained for samples with such doses, irrespective of the magnitude of the environmental dose rate. Particularly for the fine quartz fraction, a mismatch between the SAR dose response curve and the dose response curve obtained when doses are added to the natural is reported, indicating that the application of the SAR protocol in the high dose range is problematic. This dose dependent deviation is much less pronounced for coarse grains. Thus, it seems reasonable to infer that the dose response curves for the coarse grains, although saturating earlier can be regarded as more reliable for equivalent dose calculation than those for the fine grains.

A high-resolution map of gamma dose rates in Cluj County, Romania using LiF:Mg,Cu,P detectors.

Outdoor gamma radiation measurements in Cluj County, Romania have been performed using solid-state thermoluminescent detectors in order to develop a high-resolution database for natural gamma dose rates. Integrated measurements have been carried out for an exposure time of minimum 3 weeks. According to European Union requirements, the territory has been divided into 69 grids of 10 × 10 km. The cells were monitored using LiF:Mg,Cu,P detectors. For two locations the results were 136 ± 7 and 150 ± 7 nGy h(-1), respectively. These results can be explained by the existent geological substrate. The values ranged from 56 ± 4 to 150 ± 7 nGy h(-1), with an average value of 91 ± 2 nGy h(-1), being in agreement with the 2008 United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR) Report. A high-resolution map of gamma dose rates in Cluj County is presented for the first time.

The evolution of Sf. Gheorghe (Danube) asymmetric deltaic lobe

The wave asymmetric Sf. Gheorghe lobe is the only active in the Danube delta where river mouth bar (and the associated barrier islands and spits) continuously deployed a cyclic development for almost two millennia. During first stage, the Sf. Gheorghe distributary had a small discharge (with an order of magnitude lower than present) which after that experienced a rapid increase in consequence of the successive avulsions of Impuţita (southern distributary of Sulina arm) and Dunavăţ distributaries. Our morphological analyses together with the newly obtained chronology, revealed the multiple ridgesets structure of Sf. Gheorghe deltaic lobe. In fact, all ridgesets (10) follow a common morphodynamic pattern characterized by the cyclic succession of three stages: i) subaqueous mouth bar development, ii) barrier island emergence, iii) barrier spit phase with several secondary spits derived from an updrift trunk ridge. The size of each ridgeset increased exponentially with every new cycle due to the constant lengthening of the coastline as the downdrift side of the lobe advances seaward through a series of progressively larger similar quadrilaterals, yielding to a constant enlargment of the delta front size.

The Campanian Ignimbrite tephra layer - a regional stratigraphic marker for the MIS 3 loess deposits of Romania

Loess deposits are widespread in Romania and many open profiles are found along the river valleys crossing the southern plains of the country, and these records are important resources for understanding paleoclimate dynamics and the Paleolithic cultural dispersal at the continental scale. However, loess deposits show significant lateral compositional variations, which bring about regional stratigraphic uncertainties, especially when site-to-site correlations still rely mainly on stratigraphic relationships, and only a handful of profiles having been investigated with more precise dating methods