Alison Rust

Magma degassing buffered by vapor flow through brecciated conduit margins

Obsidian pyroclasts, a common component of rhyolitic tephra, preserve a range of volatile contents, which has been used to infer syneruptive conditions of magmatic degassing. Here we show that the textures of obsidian pyroclasts provide information on physical mechanisms of magma flow and degassing along conduit margins. Obsidian clasts often contain xenoliths, sheared bands of lithic powder, and textures consistent with magma autobrecciation. These features suggest that pyroclastic obsidian primarily forms near conduit walls where magma fragments and reanneals during ascent. We use these observations to develop a degassing model for pyroclastic obsidian from the A.D. 1340 Mono Craters, California, eruptions. We suggest that degassing was buffered by continual flux of vapor through highly permeable, brecciated magma along conduit walls. Continuous reequilibration of magma with vapor of relatively constant composition not only explains the CO 2 -H 2 O and δD-H 2 O data from Mono Craters pyroclastic obsidian, but also requires much lower magmatic CO 2 values than the commonly accepted model of closed-system degassing. Taken together, the chemical and physical evidence suggests that magma brecciation along conduit walls aids the degassing of ascending rhyolite.

The feasibility of generating low-frequency volcano seismicity by flow through a deformable channel

Abstract Oscillations generated by flow of magmatic or hydrothermal fluids through tabular channels in elastic rocks are a possible source of low-frequency seismicity. We assess the conditions required to generate oscillations of approximately 1 Hz via hydrodynamic flow instabilities (roll waves), flow-destabilized standing waves set up on the elastic channel walls (wall modes), and unstable normal modes ringing in an adjacent fluid reservoir (clarinet modes). Stability criteria are based on physical and dimensional arguments, and discussion of destabilized elastic modes is supplemented with laboratory experiments of gas flow through a channel in a block of gelatine, and between a rigid plate and a rubber membrane. For each of the mechanisms considered, oscillations are generated if flow speeds exceed a critical value. Roll waves are waves of channel thickness variation that propagate in the direction of flow and are equivalent to traveling crack waves. The convective instability criterion is that the flow is faster than those travelling waves. Similarly, wall modes and clarinet modes require that the flow speed exceeds a critical value related to a wave speed (e.g. elastic or acoustic wave) multiplied by a geometrical factor. Flow destabilized modes offer a plausible explanation for low-frequency volcano seismicity, but there are limitations on what kind of standing waves comprises them.

Gas migration regimes and outgassing in particle-rich suspensions

Understanding how gases escape from particle-rich suspensions has important applications in nature and industry. Motivated by applications such as outgassing of crystal-rich magmas, we map gas migration patterns in experiments where we vary (1) particle fractions and liquid viscosity (10 Pa s – 500 Pa s), (2) container shape (horizontal parallel plates and upright cylinders), and (3) methods of bubble generation (single bubble injections, and multiple bubble generation with chemical reactions). We identify two successive changes in gas migration behavior that are determined by the normalized particle fraction (relative to random close packing), and are insensitive to liquid viscosity, bubble growth rate or container shape within the explored ranges. The first occurs at the random loose packing, when gas bubbles begin to deform; the second occurs near the random close packing, and is characterized by gas migration in a fracture-like manner. We suggest that changes in gas migration behavior are caused by dilation of the granular network, which locally resists bubble growth. The resulting bubble deformation increases the likelihood of bubble coalescence, and promotes the development of permeable pathways at low porosities. This behavior may explain the efficient loss of volatiles from viscous slurries such as crystal-rich magmas.

The role of bubbles in generating fine ash during hydromagmatic eruptions

The abundant fine ash produced in the 2011 subglacial eruption of Grimsvotn, Iceland, highlights the fragmentation efficiency of mafic hydromagmatic eruptions, which is considerably higher than for comparable “dry” eruptions. Ash from the 2011 eruption can be divided into three morphological components—vesicular particles, shards, and dense fragments—distinguished by the size and abundance of constituent vesicles. We use the vesicle characteristics to define a new shape factor, the concavity index, which provides an unbiased way to classify individual ash particles as either bubbly (vesicular particles and shards) or dense. The relative proportion of bubbly and dense particles varies systematically with grain size, with the proportion of bubbly grains decreasing as the particle size approaches the modal bubble diameter. Measured bubble volume distributions are similar to those of rapidly quenched pyroclasts from Hawaiian fountains and suggest a comparable degassing history during magma ascent. Yet concordance between the size distributions of ash and of bubbles in the Grimsvotn samples stands in contrast to the size distributions in Hawaiian fountains, where pyroclasts are orders of magnitude larger than individual bubbles. We propose that the Grimsvotn ash formed by brittle disintegration of vesicular pyroclasts and that fragmentation efficiency was amplified by residual thermal stresses in glass quenched by glacial water. The strong control of resulting particle sizes and morphologies by the size and spatial distribution of bubbles demonstrates that the bubble population cannot be ignored when modeling hydromagmatic fragmentation.

Impact of the lateral blast on the spatial pattern and grain size characteristics of the 18 May 1980 Mount St. Helens fallout deposit

The 18 May 1980 eruption of Mount St. Helens started with a lateral blast that fed a pyroclastic surge, which then uplifted to form a co-blast plume. Thirty minutes later, Plinian activity started at the vent and fluctuated in intensity for ~9 h. The resulting fallout deposit, documented to > 600 km from vent, presents some striking features: (1) displacement of the overall deposit to the north of the vent, (2) a secondary thickness and mass maximum at ~300 km from vent, (3) a total grain size distribution dominated by fine ash (62 wt % of the deposit < 63 µm), and (4) individual grain size distributions that vary dramatically in the crosswind direction from strongly bimodal in the south to skewed unimodal in the north. Results from a new deconvolution of the individual grain size distributions show that they are a combination of a coarse subpopulation that decreases in size with distance from vent and a constant fine subpopulation with a mean of ∼15 µm. Relative proportions of each subpopulation vary asymmetrically in the crosswind directions, with the fine subpopulation preponderant toward the north and the coarse one dominating the south of the deposit, both reach their absolute maxima in mass on the deposit axis. Componentry analyses of selected samples show that blast-derived material is greatly enriched toward the north of the deposit. These results indicate that the co-blast plume dispersed fine-grained material over great distances and dominated the fine subpopulation. Comparison with reanalysis data of atmospheric wind fields and satellite images of the spreading ash cloud suggests contrasting ash transport and depositional processes for the (early) co-blast plume and the (later) vent-derived Plinian plumes. The co-blast plume is displaced to the north; it had a high overshoot height, and eastward dispersion via strong winds low in the stratosphere (~10–15 km). The Plinian plumes were lower and dispersed most of the material to the southeast as the direction of high-velocity winds shifted just before the late climactic Plinian eruptive phase. Fine ash (fine subpopulation) was deposited continuously throughout the deposit, with an increase of sedimentation rate ~300 km from the vent where there is a secondary maximum in the deposit mass and thickness. Fine ash probably settled by a combination of enhanced sedimentation mechanisms, including not only aggregation but also gravitational convective instabilities of cloud base, hydrometeor formation and destruction, and entrainment of small particles by larger ones. Finally, we show that half of the deposit (by mass) in the medial area was deposited by the co-blast plume, and that a significant proportion of the Mount St. Helens fallout deposit is nonjuvenile, which has implications for the magmatic budget of this eruption.

Subvolcanic plumbing systems imaged through crystal size distributions

The configuration of subvolcanic magma storage regions exercises a fundamental control on eruptive style and hazard. Such regions can be imaged remotely, using seismic, geodetic, or magnetotelluric methods, although these are far from routine and rarely unambiguous. The textures of erupted volcanic rocks, as quantified through crystal size distributions (CSD), provide space- and time-integrated information on subvolcanic plumbing systems, although these data cannot be used readily for reconstruction of key parameters such as conduit geometry or magma chamber depth. Here we develop a numerical approach to interpretation of CSD in products of steady eruptions, based on crystallization kinetics and hydrodynamic flow simulation, to image subvolcanic plumbing systems. The method requires knowledge of magma properties, crystal growth kinetics (measured experimentally), and discharge rate (measured observationally). The method is applicable to steady-state eruptive regimes. Distributions of pressure, temperature, crystal content, and conduit cross-section area with depth are obtained from a CSD from a sample erupted from Mount St. Helens volcano, USA. Values of average conduit diameter (∼30 m) and magma chamber depth (∼14 km below the summit) are in good agreement with independent estimates.

Consistent decrease in North Atlantic Tropical Cyclone frequency following major volcanic eruptions in the last three centuries

Injection of sulphate aerosols into the stratosphere following major volcanic eruptions alters global climate through the absorption and scattering of solar radiation. One proposed consequence is a decrease in North Atlantic Tropical Cyclone (TC) activity, as was observed following the El Chichon (1982) and Mount Pinatubo (1991) eruptions. We test this relationship using documentary and proxy reconstructions of major volcanic eruptions and TC frequency in the North Atlantic basin over the last three centuries. We find a consistent reduction in the number of TCs formed during the 3 years following major eruptions compared to the preceding 3 years, including after eruptions located at northern high latitudes. Our findings suggest that low-latitude eruptions reduce Atlantic TC frequency by decreasing local sea surface temperatures, whereas the mechanisms for the decrease in TC frequency following high-latitude eruptions are less clear and attribution is hampered by poor identification of these events.

MeMoVolc consensual document: a review of cross-disciplinary approaches to characterizing small explosive magmatic eruptions

A workshop entitled “Tracking and understanding volcanic emissions through cross-disciplinary integration: a textural working group” was held at the Université Blaise Pascal (Clermont-Ferrand, France) on the 6–7 November 2012. This workshop was supported by the European Science Foundation (ESF). The main objective of the workshop was to establish an initial advisory group to begin to define measurements, methods, formats and standards to be applied in the integration of geophysical, physical and textural data collected during volcanic eruptions. This would homogenize procedures to be applied and integrated during both past and ongoing events. The workshop comprised a total of 35 scientists from six countries (France, Italy, Great Britain, Germany, Switzerland and Iceland). The four main aims were to discuss and define: standards, precision and measurement protocols for textural analysis; identification of textural, field deposit, chemistry and geophysical parameters that can best be measured and combined; the best delivery formats so that data can be shared between and easily used by different groups; and multi-disciplinary sampling and measurement routines currently used and measurement standards applied, by each community. The group agreed that community-wide, cross-disciplinary integration, centred on defining those measurements and formats that can be best combined, is an attainable and key global focus. Consequently, we prepared this paper to present our initial conclusions and recommendations, along with a review of the current state of the art in this field that supported our discussions.

Contrasting mechanisms of magma fragmentation during coeval magmatic and hydromagmatic activity: the Hverfjall Fires fissure eruption, Iceland

Growing evidence for significant magmatic vesiculation prior to magma-water interaction (MWI) has brought into question the use of ‘diagnostic’ features, such as low vesicularities and blocky morphologies, to identify hydromagmatic pyroclasts. We address this question by quantifying co-variations in particle size, shape and texture in both magmatic and hydromagmatic deposits from the Hverfjall Fires fissure eruption, Iceland. Overlapping vesicularity and bubble number density distributions measured in rapidly quenched magmatic and hydromagmatic pyroclasts indicate a shared initial history of bubble nucleation and growth, with substantial vesiculation prior to MWI. Hydromagmatic fragmentation occurred principally by brittle mechanisms, where the length scale and geometry of fracturing was controlled by the bubble population. This suggests that the elevated fragmentation efficiency of hydromagmatic deposits is driven, at least in part, by brittle disintegration of vesicular pyroclasts due to high thermal stress generated during rapid cooling. In this way, the shape and size distributions of hydromagmatic pyroclasts, both critical input parameters for ash dispersion models, are strongly influenced by the dynamics of vesiculation prior to MWI. This result underlines the need to analyse multiple grain-size fractions to characterise the balance between magmatic and hydromagmatic processes. During the Hverfjall Fires eruption, the external water supply was sufficient to maintain MWI throughout the eruption, with no evidence for progressive exhaustion of a water reservoir. We suggest that both the longevity and the spatial distribution of MWI were determined by the pre-existing regional hydrology and represent continuous interaction between a propagating dike and a strong groundwater flow system hosted within permeable basalt lavas.

Geology of the Don Manuel igneous complex, central Chile: Implications for igneous processes in porphyry copper systems

The Don Manuel igneous complex and associated porphyry copper mineralization in the Andean Cordillera of central Chile demonstrate similarities between intrusive complexes associated with porphyry copper deposits and arc volcanoes that generate porphyritic volcanics. The Don Manuel igneous complex intrusions progressed from quartz monzonite through rhyolite and biotite tonalite to intermediate porphyritic and basaltic andesite dikes, which intrude the older units. Mineralization is associated with the biotite tonalite and intermediate porphyries, which also contain the greatest abundance of mafic enclaves. Zoning patterns within plagioclase phenocrysts suggest that the later intermediate porphyries comprise a hybridized suite formed by magma mixing. New zircon U-Pb ages and whole-rock Ar-Ar ages indicate that the Don Manuel igneous complex was emplaced between ca. 4 and 3.6 Ma. The time scale for the episodic intrusion of the Don Manuel igneous complex units is similar to observed episodicity of eruption and degassing events in active arc volcanoes. Observations from the Don Manuel igneous complex are consistent with the close spatial and temporal association of mineralization with episodic intrusion and interaction between silicic and mafic magmas during emplacement. The observations are also consistent with the hypothesis that mafic magma provides a source of sulfur for porphyry copper deposit formation.