Alistair G.L. Borthwick

Adsorption of Pb2 +, Cd2 +, Cu2 + and Cr3 + onto titanate nanotubes: Competition and effect of inorganic ions

Adsorption of Pb(2+), Cd(2+), Cu(2+) and Cr(3+) from aqueous solutions onto titanate nanotubes (TNTs) in multiple systems was systematically studied. Particular attention was paid to competitive adsorption and the effect of inorganic ions. TNTs showed large adsorption capacity for the four heavy metals, with the mechanism of ion-exchange between metal ions and H(+)/Na(+) located in the interlayers of TNTs. Binary or quaternary competitive adsorption indicated that the adsorption capacity of the four heavy metals onto TNTs followed the sequence of Pb(2+) (2.64 mmol g(-1)) ≫ Cd(2+) (2.13 mmol g(-1)) > Cu(2+) (1.92 mmol g(-1)) ≫ Cr(3+) (1.37 mmol g(-1)), which followed the reverse order of their hydration energies. Moreover, inorganic ions including Na(+), K(+), Mg(2+) and Ca(2+) inhibited the adsorption of heavy metals on TNTs, because they competed for adsorption sites, decreased the activity of heavy metal ions, and promoted the aggregation of TNTs. However, Al(3+) and Fe(3+) generally enhanced adsorption because the resulting hydroxyl-Al/Fe intercalated or coated TNTs could also capture metal ions. Furthermore, minor effect of inorganic ions on adsorption of Pb(2+) resulted from its strong affinity to TNTs. Difficult desorption and small inhibiting effect by Na(+), K(+), Mg(2+) and Ca(2+) on adsorption of Cr(3+) was due to the formed stable complex of HOCr(OTi)₂ ≡ with TNTs. Present study indicated potential applications of TNTs in wastewater treatment for heavy metals.

Adaptive Q‐tree Godunov‐type scheme for shallow water equations

SUMMARY This paper presents details of a second-order accurate, Godunov-type numerical model of the twodimensional shallow water equations (SWEs) written in matrix form and discretized using finite volumes. Roe’s flux function is used for the convection terms and a non-linear limiter is applied to prevent unwanted spurious oscillations. A new mathematical formulation is presented, which inherently balances flux gradient and source terms. It is, therefore, suitable for cases where the bathymetry is non-uniform, unlike other formulations given in the literature based on Roe’s approximate Riemann solver. The model is based on hierarchical quadtree (Q-tree) grids, which adapt to inherent flow parameters, such as magnitude of the free surface gradient and depth-averaged vorticity. Validation tests include windinduced circulation in a dish-shaped basin, two-dimensional frictionless rectangular and circular dambreaks, an oblique hydraulic jump, and jet-forced flow in a circular reservoir. Copyright

The available power from tidal stream turbines in the Pentland Firth

This paper assesses an upper bound for the tidal stream power resource of the Pentland Firth. A depth-averaged numerical model of the tidal dynamics in the region is set-up and validated against field measurements. Actuator disc theory is used to model the effect of turbines on the flow, and to estimate the power available for generation after accounting for losses owing to mixing downstream of the turbines. It is found that three rows of turbines extending across the entire width of the Pentland Firth and blocking a large fraction of the channel can theoretically generate 1.9 GW, averaged over the spring–neap cycle. However, generation of significantly more power than this is unlikely to be feasible as the available power per additional swept area of turbine is too small to be viable. Our results differ from those obtained using simplified tidal channel models of the type used commonly in the literature. We also use our numerical model to investigate the available power from rows of turbines placed across various subchannels within the Pentland Firth, together with practical considerations such as the variation in power over the spring–neap tidal cycle and the changes to natural tidal flows which result from power extraction.

Palm oil mill effluent treatment using a two-stage microbial fuel cells system integrated with immobilized biological aerated filters.

An integrated system of two-stage microbial fuel cells (MFCs) and immobilized biological aerated filters (I-BAFs) was used to treat palm oil mill effluent (POME) at laboratory scale. By replacing the conventional two-stage up-flow anaerobic sludge blanket (UASB) with a newly proposed upflow membrane-less microbial fuel cell (UML-MFC) in the integrated system, significant improvements on NH(3)-N removal were observed and direct electricity generation implemented in both MFC1 and MFC2. Moreover, the coupled iron-carbon micro-electrolysis in the cathode of MFC2 further enhanced treatment efficiency of organic compounds. The I-BAFs played a major role in further removal of NH(3)-N and COD. For influent COD and NH(3)-N of 10,000 and 125 mg/L, respectively, the final effluents COD and NH(3)-N were below 350 and 8 mg/L, with removal rates higher than 96.5% and 93.6%. The GC-MS analysis indicated that most of the contaminants were satisfactorily biodegraded by the integrated system.

Enrichment and characterization of a bacteria consortium capable of heterotrophic nitrification and aerobic denitrification at low temperature.

Nitrogen removal in wastewater treatment plants is usually severely inhibited under cold temperature. The present study proposes bioaugmentation using psychrotolerant heterotrophic nitrification-aerobic denitrification consortium to enhance nitrogen removal at low temperature. A functional consortium has been successfully enriched by stepped increase in DO concentration. Using this consortium, the specific removal rates of ammonia and nitrate at 10 °C reached as high as 3.1 mg N/(gSSh) and 9.6 mg N/(gSSh), respectively. PCR-DGGE and clone library analysis both indicated a significant reduction in bacterial diversity during enrichment. Phylogenetic analysis based on nearly full-length 16S rRNA genes showed that Alphaproteobacteria, Deltaproteobacteria and particularly Bacteroidetes declined while Gammaproteobacteria (all clustered into Pseudomonas sp.) and Betaproteobacteria (mainly Rhodoferax ferrireducens) became dominant in the enriched consortium. It is likely that Pseudomonas spp. played a major role in nitrification and denitrification, while R. ferrireducens and its relatives utilized nitrate as both electron acceptor and nitrogen source.

Quadtree grid generation: Information handling, boundary fitting and CFD applications

When solving partial differential equations by numerical methods, an automatic mesh generation technique which can accommodate local mesh refinement adaptively is desirable. One efficient technique for producing such meshes in two-dimensional space is to subdivide recursively the domain into quadrants using a quadtree to store and manipulate the mesh information. Here, the quadtree grid generation technique is reviewed and its programming discussed. Three data storage methods are examined. The conversion of the quadtree grid to a triangular finite element mesh is also described, along with methods for fitting the mesh to smooth boundary contours. Results from viscous flow and standing wave simulations are used to illustrate mesh adaptivity about internal and boundary features.

Water wave diffraction by a cylinder array. Part 1. Regular waves

Diffraction of irregular waves, focused wave groups, and random seas by an array of vertical bottom-mounted circular cylinders is investigated using theoretical, computational and experimental methods. This is an extension of our study of such an array in regular waves, reported in Part 1. Linear focused wave group theory is reviewed as a method for predicting the probable shape of extreme events from random wave spectra. Measurements are presented of the free surface elevation distribution in the vicinity of a multi-column structure in an offshore basin when subjected to irregular waves having peak frequencies and significant wave heights in the range 0.449 k p a H s < 0.124 respectively, where a is the cylinder radius. Analytical linear diffraction theory is extended for application to focused wave groups and random seas. Experimental irregular wave data are analysed for comparison with this theory. Linear diffraction theory for random seas is shown to give an excellent prediction of incident wave spectral diffraction, while linear diffraction theory for focused wave groups works well for linearized extreme events. Due to the phase shifting of incident wave spectral components, diffraction is shown to generate focused wave groups in the vicinity of the cylinder array.

Measurement and assessment of carrying capacity of the environment in Ningbo, China

Carrying Capacity of the Environment (CCE) provides a useful measure of the sustainable development of a region. Approaches that use integrated assessment instead of measurement can lead to misinterpretation of sustainable development because of confusion between Environmental Stress (ES) indexes and CCE indexes, and the selection of over-simple linear plus models. The present paper proposes a comprehensive measurement system for CCE which comprises models of natural resources capacity, environmental assimilative capacity, ecosystem services capacity, and society supporting capacity. The corresponding measurable indexes are designed to assess CCE using a carrying capacity surplus ratio model and a vector of surplus ratio of carrying capacity model. The former aims at direct comparison of ES and CCE based on the values of basic indexes, and the latter uses a Euclidean vector to assess CCE states. The measurement and assessment approaches are applicable to Strategic Environmental Assessment (SEA) and environmental planning and management. A case study is presented for Ningbo, China, whereby all the basic indexes of ECC are measured and the CCE states assessed for 2005 and 2010.

From the paddle to the beach - A Boussinesq shallow water numerical wave tank based on Madsen and Sørensen's equations

This article describes a one-dimensional numerical model of a shallow-water flume with an in-built piston paddle moving boundary wavemaker. The model is based on a set of enhanced Boussinesq equations and the nonlinear shallow water equations. Wave breaking is described approximately, by locally switching to the nonlinear shallow water equations when a critical wave steepness is reached. The moving shoreline is calculated as part of the solution. The piston paddle wavemaker operates on a movable grid, which is Lagrangian on the paddle face and Eulerian away from the paddle. The governing equations are, however, evolved on a fixed mapped grid, and the newly calculated solution is transformed back onto the moving grid via a domain mapping technique. Validation test results are compared against analytical solutions, confirming correct discretisation of the governing equations, wave generation via the numerical paddle, and movement of the wet/dry front. Simulations are presented that reproduce laboratory experiments of wave runup on a plane beach and wave overtopping of a laboratory seawall, involving solitary waves and compact wave groups. In practice, the numerical model is suitable for simulating the propagation of weakly dispersive waves and can additionally model any associated inundation, overtopping or inland flooding within the same simulation.

Water quality in Sepetiba Bay, Brazil.

Sepetiba Bay is located at 23 degrees S, 44 degrees W in Rio de Janeiro State, Brazil. Water samples were taken at eight locations adjacent to the north shore of the Bay, near to villages and towns without sewage treatment provision. The samples were analysed and total and faecal coliform concentrations determined. A hydrodynamic model of the Bay was used together with a species dispersion model based on an adaptive quadtree mesh to predict faecal concentrations in the Bay. Effluent sources used in the model were defined using population data from census returns with flow and concentration values estimated using standard values recommended by the World Bank (WB) and the World Health Organisation (WHO). Sufficient agreement was obtained between the measured and predicted concentrations to support the use of WB and WHO summary statistics to estimate sources of sewage.