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Proceedings of the National Academy of Sciences of the United States of America | 2007

Evidence for an extraterrestrial impact 12,900 years ago that contributed to the megafaunal extinctions and the Younger Dryas cooling

R. B. Firestone; Allen West; James P. Kennett; Luann Becker; Theodore E. Bunch; Zsolt Révay; Peter H. Schultz; T. Belgya; Douglas J. Kennett; Jon M. Erlandson; O. J. Dickenson; Reuben S. Harris; J. B. Kloosterman; P. Lechler; Paul Andrew Mayewski; J. Montgomery; Robert J. Poreda; Thomas H. Darrah; S. S. Que Hee; A. R. Smith; August Stich; W. Topping; James H. Wittke; Wendy S. Wolbach

A carbon-rich black layer, dating to ≈12.9 ka, has been previously identified at ≈50 Clovis-age sites across North America and appears contemporaneous with the abrupt onset of Younger Dryas (YD) cooling. The in situ bones of extinct Pleistocene megafauna, along with Clovis tool assemblages, occur below this black layer but not within or above it. Causes for the extinctions, YD cooling, and termination of Clovis culture have long been controversial. In this paper, we provide evidence for an extraterrestrial (ET) impact event at ≅12.9 ka, which we hypothesize caused abrupt environmental changes that contributed to YD cooling, major ecological reorganization, broad-scale extinctions, and rapid human behavioral shifts at the end of the Clovis Period. Clovis-age sites in North American are overlain by a thin, discrete layer with varying peak abundances of (i) magnetic grains with iridium, (ii) magnetic microspherules, (iii) charcoal, (iv) soot, (v) carbon spherules, (vi) glass-like carbon containing nanodiamonds, and (vii) fullerenes with ET helium, all of which are evidence for an ET impact and associated biomass burning at ≈12.9 ka. This layer also extends throughout at least 15 Carolina Bays, which are unique, elliptical depressions, oriented to the northwest across the Atlantic Coastal Plain. We propose that one or more large, low-density ET objects exploded over northern North America, partially destabilizing the Laurentide Ice Sheet and triggering YD cooling. The shock wave, thermal pulse, and event-related environmental effects (e.g., extensive biomass burning and food limitations) contributed to end-Pleistocene megafaunal extinctions and adaptive shifts among PaleoAmericans in North America.


Science | 2009

Nanodiamonds in the Younger Dryas Boundary Sediment Layer

Douglas J. Kennett; James P. Kennett; Allen West; C. Mercer; S. S. Que Hee; L. Bement; Theodore E. Bunch; M. Sellers; Wendy S. Wolbach

We report abundant nanodiamonds in sediments dating to 12.9 ± 0.1 thousand calendar years before the present at multiple locations across North America. Selected area electron diffraction patterns reveal two diamond allotropes in this boundary layer but not above or below that interval. Cubic diamonds form under high temperature-pressure regimes, and n-diamonds also require extraordinary conditions, well outside the range of Earths typical surficial processes but common to cosmic impacts. N-diamond concentrations range from ≈10 to 3700 parts per billion by weight, comparable to amounts found in known impact layers. These diamonds provide strong evidence for Earths collision with a rare swarm of carbonaceous chondrites or comets at the onset of the Younger Dryas cool interval, producing multiple airbursts and possible surface impacts, with severe repercussions for plants, animals, and humans in North America.


Proceedings of the National Academy of Sciences of the United States of America | 2009

Shock-synthesized hexagonal diamonds in Younger Dryas boundary sediments

Douglas J. Kennett; James P. Kennett; Allen West; G. James West; Theodore E. Bunch; Brendan J. Culleton; Jon M. Erlandson; Shane S. Que Hee; John R. Johnson; Chris Mercer; Feng Shen; M. Sellers; Thomas W. Stafford; Adrienne Stich; James C. Weaver; James H. Wittke; Wendy S. Wolbach

The long-standing controversy regarding the late Pleistocene megafaunal extinctions in North America has been invigorated by a hypothesis implicating a cosmic impact at the Ållerød-Younger Dryas boundary or YDB (≈12,900 ± 100 cal BP or 10,900 ± 100 14C years). Abrupt ecosystem disruption caused by this event may have triggered the megafaunal extinctions, along with reductions in other animal populations, including humans. The hypothesis remains controversial due to absence of shocked minerals, tektites, and impact craters. Here, we report the presence of shock-synthesized hexagonal nanodiamonds (lonsdaleite) in YDB sediments dating to ≈12,950 ± 50 cal BP at Arlington Canyon, Santa Rosa Island, California. Lonsdaleite is known on Earth only in meteorites and impact craters, and its presence strongly supports a cosmic impact event, further strengthened by its co-occurrence with other nanometer-sized diamond polymorphs (n-diamonds and cubics). These shock-synthesized diamonds are also associated with proxies indicating major biomass burning (charcoal, carbon spherules, and soot). This biomass burning at the Younger Dryas (YD) onset is regional in extent, based on evidence from adjacent Santa Barbara Basin and coeval with broader continent-wide biomass burning. Biomass burning also coincides with abrupt sediment mass wasting and ecological disruption and the last known occurrence of pygmy mammoths (Mammuthus exilis) on the Channel Islands, correlating with broader animal extinctions throughout North America. The only previously known co-occurrence of nanodiamonds, soot, and extinction is the Cretaceous-Tertiary (K/T) impact layer. These data are consistent with abrupt ecosystem change and megafaunal extinction possibly triggered by a cosmic impact over North America at ≈12,900 ± 100 cal BP.


Proceedings of the National Academy of Sciences of the United States of America | 2012

Evidence from central Mexico supporting the Younger Dryas extraterrestrial impact hypothesis

Isabel Israde-Alcántara; James L. Bischoff; Gabriela Domínguez-Vázquez; Hongchun Li; Paul S. DeCarli; Theodore E. Bunch; James H. Wittke; James C. Weaver; R. B. Firestone; Allen West; James P. Kennett; Chris Mercer; Sujing Xie; Eric K. Richman; Charles R. Kinzie; Wendy S. Wolbach

We report the discovery in Lake Cuitzeo in central Mexico of a black, carbon-rich, lacustrine layer, containing nanodiamonds, microspherules, and other unusual materials that date to the early Younger Dryas and are interpreted to result from an extraterrestrial impact. These proxies were found in a 27-m-long core as part of an interdisciplinary effort to extract a paleoclimate record back through the previous interglacial. Our attention focused early on an anomalous, 10-cm-thick, carbon-rich layer at a depth of 2.8 m that dates to 12.9 ka and coincides with a suite of anomalous coeval environmental and biotic changes independently recognized in other regional lake sequences. Collectively, these changes have produced the most distinctive boundary layer in the late Quaternary record. This layer contains a diverse, abundant assemblage of impact-related markers, including nanodiamonds, carbon spherules, and magnetic spherules with rapid melting/quenching textures, all reaching synchronous peaks immediately beneath a layer containing the largest peak of charcoal in the core. Analyses by multiple methods demonstrate the presence of three allotropes of nanodiamond: n-diamond, i-carbon, and hexagonal nanodiamond (lonsdaleite), in order of estimated relative abundance. This nanodiamond-rich layer is consistent with the Younger Dryas boundary layer found at numerous sites across North America, Greenland, and Western Europe. We have examined multiple hypotheses to account for these observations and find the evidence cannot be explained by any known terrestrial mechanism. It is, however, consistent with the Younger Dryas boundary impact hypothesis postulating a major extraterrestrial impact involving multiple airburst(s) and and/or ground impact(s) at 12.9 ka.


Proceedings of the National Academy of Sciences of the United States of America | 2013

Evidence for deposition of 10 million tonnes of impact spherules across four continents 12,800 y ago

James H. Wittke; James C. Weaver; Theodore E. Bunch; James P. Kennett; Douglas J. Kennett; A. M. T. Moore; Gordon C. Hillman; Kenneth B. Tankersley; Albert C. Goodyear; Christopher R. Moore; I. Randolph Daniel; Jack H. Ray; Neal H. Lopinot; David Ferraro; Isabel Israde-Alcántara; James L. Bischoff; Paul S. DeCarli; Robert E. Hermes; J. B. Kloosterman; Zsolt Révay; David R. Kimbel; Gunther Kletetschka; Ladislav Nabelek; Carl P. Lipo; Sachiko Sakai; Allen West; R. B. Firestone

Significance We present detailed geochemical and morphological analyses of nearly 700 spherules from 18 sites in support of a major cosmic impact at the onset of the Younger Dryas episode (12.8 ka). The impact distributed ∼10 million tonnes of melted spherules over 50 million square kilometers on four continents. Origins of the spherules by volcanism, anthropogenesis, authigenesis, lightning, and meteoritic ablation are rejected on geochemical and morphological grounds. The spherules closely resemble known impact materials derived from surficial sediments melted at temperatures >2,200 °C. The spherules correlate with abundances of associated melt-glass, nanodiamonds, carbon spherules, aciniform carbon, charcoal, and iridium. Airbursts/impacts by a fragmented comet or asteroid have been proposed at the Younger Dryas onset (12.80 ± 0.15 ka) based on identification of an assemblage of impact-related proxies, including microspherules, nanodiamonds, and iridium. Distributed across four continents at the Younger Dryas boundary (YDB), spherule peaks have been independently confirmed in eight studies, but unconfirmed in two others, resulting in continued dispute about their occurrence, distribution, and origin. To further address this dispute and better identify YDB spherules, we present results from one of the largest spherule investigations ever undertaken regarding spherule geochemistry, morphologies, origins, and processes of formation. We investigated 18 sites across North America, Europe, and the Middle East, performing nearly 700 analyses on spherules using energy dispersive X-ray spectroscopy for geochemical analyses and scanning electron microscopy for surface microstructural characterization. Twelve locations rank among the world’s premier end-Pleistocene archaeological sites, where the YDB marks a hiatus in human occupation or major changes in site use. Our results are consistent with melting of sediments to temperatures >2,200 °C by the thermal radiation and air shocks produced by passage of an extraterrestrial object through the atmosphere; they are inconsistent with volcanic, cosmic, anthropogenic, lightning, or authigenic sources. We also produced spherules from wood in the laboratory at >1,730 °C, indicating that impact-related incineration of biomass may have contributed to spherule production. At 12.8 ka, an estimated 10 million tonnes of spherules were distributed across ∼50 million square kilometers, similar to well-known impact strewnfields and consistent with a major cosmic impact event.


Proceedings of the National Academy of Sciences of the United States of America | 2012

Very high-temperature impact melt products as evidence for cosmic airbursts and impacts 12,900 years ago

Theodore E. Bunch; Robert E. Hermes; A. M. T. Moore; Douglas J. Kennett; James C. Weaver; James H. Wittke; Paul S. DeCarli; James L. Bischoff; Gordon C. Hillman; David R. Kimbel; Gunther Kletetschka; Carl P. Lipo; Sachiko Sakai; Zsolt Révay; Allen West; R. B. Firestone; James P. Kennett

It has been proposed that fragments of an asteroid or comet impacted Earth, deposited silica-and iron-rich microspherules and other proxies across several continents, and triggered the Younger Dryas cooling episode 12,900 years ago. Although many independent groups have confirmed the impact evidence, the hypothesis remains controversial because some groups have failed to do so. We examined sediment sequences from 18 dated Younger Dryas boundary (YDB) sites across three continents (North America, Europe, and Asia), spanning 12,000 km around nearly one-third of the planet. All sites display abundant microspherules in the YDB with none or few above and below. In addition, three sites (Abu Hureyra, Syria; Melrose, Pennsylvania; and Blackville, South Carolina) display vesicular, high-temperature, siliceous scoria-like objects, or SLOs, that match the spherules geochemically. We compared YDB objects with melt products from a known cosmic impact (Meteor Crater, Arizona) and from the 1945 Trinity nuclear airburst in Socorro, New Mexico, and found that all of these high-energy events produced material that is geochemically and morphologically comparable, including: (i) high-temperature, rapidly quenched microspherules and SLOs; (ii) corundum, mullite, and suessite (Fe3Si), a rare meteoritic mineral that forms under high temperatures; (iii) melted SiO2 glass, or lechatelierite, with flow textures (or schlieren) that form at > 2,200 °C; and (iv) particles with features indicative of high-energy interparticle collisions. These results are inconsistent with anthropogenic, volcanic, authigenic, and cosmic materials, yet consistent with cosmic ejecta, supporting the hypothesis of extraterrestrial airbursts/impacts 12,900 years ago. The wide geographic distribution of SLOs is consistent with multiple impactors.


Journal of Glaciology | 2010

Discovery of a nanodiamond-rich layer in the Greenland ice sheet

Andrei V. Kurbatov; Paul Andrew Mayewski; Jørgen Peder Steffensen; Allen West; Douglas J. Kennett; James P. Kennett; Theodore E. Bunch; M. Handley; Douglas S. Introne; Shane S. Que Hee; Christopher Mercer; M. Sellers; Feng Shen; Sharon B. Sneed; James C. Weaver; James H. Wittke; Thomas W. Stafford; John J. Donovan; Sujing Xie; Joshua J. Razink; Adrienne Stich; Charles R. Kinzie; Wendy S. Wolbach

We report the discovery in the Greenland ice sheet of a discrete layer of free nanodiamonds (NDs) in very high abundances, implying most likely either an unprecedented influx of extraterrestrial (ET) material or a cosmic impact event that occurred after the last glacial episode. From that layer, we extracted n-diamonds and hexagonal diamonds (lonsdaleite), an accepted ET impact indicator, at abundances of up to about 5×10 6 times background levels in adjacent younger and older ice. The NDs in the concentrated layer are rounded, suggesting they most likely formed during a cosmic impact through some process similar to carbon-vapor deposition or high-explosive detonation. This morphology has not been reported previously in cosmic material, but has been observed in terrestrial impact material. This is the first highly enriched, discrete layer of NDs observed in glacial ice anywhere, and its presence indicates that ice caps are important archives of ET events of varying magnitudes. Using a preliminary ice chronology based on oxygen isotopes and dust stratigraphy, the ND-rich layer appears to be coeval with ND abundance peaks reported at numerous North American sites in a sedimentary layer, the Younger Dryas boundary layer (YDB), dating to 12.9 ± 0.1 ka. However, more investigation is needed to confirm this association.


Proceedings of the National Academy of Sciences of the United States of America | 2015

Bayesian chronological analyses consistent with synchronous age of 12,835-12,735 Cal B.P. for Younger Dryas boundary on four continents.

James P. Kennett; Douglas J. Kennett; Brendan J. Culleton; J. Emili Aura Tortosa; James L. Bischoff; Theodore E. Bunch; I. Randolph Daniel; Jon M. Erlandson; David Ferraro; R. B. Firestone; Albert C. Goodyear; Isabel Israde-Alcántara; John R. Johnson; Jesús Francisco Jordá Pardo; David R. Kimbel; Malcolm LeCompte; Neal H. Lopinot; William C. Mahaney; A. M. T. Moore; Christopher R. Moore; Jack H. Ray; Thomas W. Stafford; Kenneth B. Tankersley; James H. Wittke; Wendy S. Wolbach; Allen West

Significance A cosmic impact event at ∼12,800 Cal B.P. formed the Younger Dryas boundary (YDB) layer, containing peak abundances in multiple, high-temperature, impact-related proxies, including spherules, melt glass, and nanodiamonds. Bayesian statistical analyses of 354 dates from 23 sedimentary sequences over four continents established a modeled YDB age range of 12,835 Cal B.P. to 12,735 Cal B.P., supporting synchroneity of the YDB layer at high probability (95%). This range overlaps that of a platinum peak recorded in the Greenland Ice Sheet and of the onset of the Younger Dryas climate episode in six key records, suggesting a causal connection between the impact event and the Younger Dryas. Due to its rarity and distinctive characteristics, the YDB layer is proposed as a widespread correlation datum. The Younger Dryas impact hypothesis posits that a cosmic impact across much of the Northern Hemisphere deposited the Younger Dryas boundary (YDB) layer, containing peak abundances in a variable assemblage of proxies, including magnetic and glassy impact-related spherules, high-temperature minerals and melt glass, nanodiamonds, carbon spherules, aciniform carbon, platinum, and osmium. Bayesian chronological modeling was applied to 354 dates from 23 stratigraphic sections in 12 countries on four continents to establish a modeled YDB age range for this event of 12,835–12,735 Cal B.P. at 95% probability. This range overlaps that of a peak in extraterrestrial platinum in the Greenland Ice Sheet and of the earliest age of the Younger Dryas climate episode in six proxy records, suggesting a causal connection between the YDB impact event and the Younger Dryas. Two statistical tests indicate that both modeled and unmodeled ages in the 30 records are consistent with synchronous deposition of the YDB layer within the limits of dating uncertainty (∼100 y). The widespread distribution of the YDB layer suggests that it may serve as a datum layer.


The Journal of Geology | 2014

Nanodiamond-Rich Layer across Three Continents Consistent with Major Cosmic Impact at 12,800 Cal BP

Charles R. Kinzie; Shane S. Que Hee; Adrienne Stich; Kevin A. Tague; Chris Mercer; Joshua J. Razink; Douglas J. Kennett; Paul S. DeCarli; Theodore E. Bunch; James H. Wittke; Isabel Israde-Alcántara; James L. Bischoff; Albert C. Goodyear; Kenneth B. Tankersley; David R. Kimbel; Brendan J. Culleton; Jon M. Erlandson; Thomas W. Stafford; J. B. Kloosterman; A. M. T. Moore; R. B. Firestone; J.E. Aura Tortosa; Jesús Francisco Jordá Pardo; Allen West; James P. Kennett; Wendy S. Wolbach

A major cosmic-impact event has been proposed at the onset of the Younger Dryas (YD) cooling episode at ≈12,800 ± 150 years before present, forming the YD Boundary (YDB) layer, distributed over >50 million km2 on four continents. In 24 dated stratigraphic sections in 10 countries of the Northern Hemisphere, the YDB layer contains a clearly defined abundance peak in nanodiamonds (NDs), a major cosmic-impact proxy. Observed ND polytypes include cubic diamonds, lonsdaleite-like crystals, and diamond-like carbon nanoparticles, called n-diamond and i-carbon. The ND abundances in bulk YDB sediments ranged up to ≈500 ppb (mean: 200 ppb) and that in carbon spherules up to ≈3700 ppb (mean: ≈750 ppb); 138 of 205 sediment samples (67%) contained no detectable NDs. Isotopic evidence indicates that YDB NDs were produced from terrestrial carbon, as with other impact diamonds, and were not derived from the impactor itself. The YDB layer is also marked by abundance peaks in other impact-related proxies, including cosmic-impact spherules, carbon spherules (some containing NDs), iridium, osmium, platinum, charcoal, aciniform carbon (soot), and high-temperature melt-glass. This contribution reviews the debate about the presence, abundance, and origin of the concentration peak in YDB NDs. We describe an updated protocol for the extraction and concentration of NDs from sediment, carbon spherules, and ice, and we describe the basis for identification and classification of YDB ND polytypes, using nine analytical approaches. The large body of evidence now obtained about YDB NDs is strongly consistent with an origin by cosmic impact at ≈12,800 cal BP and is inconsistent with formation of YDB NDs by natural terrestrial processes, including wildfires, anthropogenesis, and/or influx of cosmic dust.


Journal of the Geological Society | 2013

Weathering rinds as mirror images of palaeosols: examples from the Western Alps with correlation to Antarctica and Mars

William C. Mahaney; Leslie Keiser; David H. Krinsley; Prasanna Pentlavalli; Christopher C. R. Allen; Peeter Somelar; Stéphane Schwartz; James M. Dohm; Randy W. Dirszowsky; Allen West; P. Julig; Pedro J.M. Costa

Weathering rinds have been used for decades as relative age indicators to differentiate glacial deposits in long Quaternary sequences, but only recently has it been shown that rinds contain long and extensive palaeoenvironmental records that often extend far beyond mere repositories of chemical weathering on both Earth and Mars. When compared with associated palaeosols in deposits of the same age, rinds often carry a zonal weathering record that can be correlated with palaeosol horizon characteristics, with respect to both abiotic and biotic parameters. As demonstrated with examples from the French and Italian Alps, rinds in coarse clastic sediment contain weathering zones that correlate closely with horizon development in associated palaeosols of presumed Late Glacial age. In addition to weathering histories in both rinds and palaeosols, considerable evidence exists to indicate that the black mat impact (12.8 ka) reached the European Alps, a connection with the Younger Dryas readvance supported by both mineral and chemical composition. Preliminary metagenomic microbial analysis using density gradient gel electrophoresis suggests that the eubacterial microbial population found in at least one Ah palaeosol horizon associated with a rind impact site is different from that in other Late Glacial and Younger Dryas surface palaeosol horizons.

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R. B. Firestone

Lawrence Berkeley National Laboratory

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Douglas J. Kennett

Pennsylvania State University

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James L. Bischoff

United States Geological Survey

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Isabel Israde-Alcántara

Universidad Michoacana de San Nicolás de Hidalgo

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