Álvaro M M Pinto

Roman and modern slag at S. Domingos mine (IPB, Portugal): compositional features and implications for their long-term stability and potential reuse

S. Domingos ores have been exploited for Cu and S from antiquity to 1966. Slag is composed of Fe-, Ca-, Zn- and Pb-rich silicate glass, fayalite, hedenbergite, Fe-spinel, and blebs of Fe-, Cu-, Zn- (and Pb-)sulphides, minor sulphosalts and Cu-Zn-Pb-iss with evidence for low-T exsolution and reactions. Silicates and oxides often crystallised far from equilibrium out of undercooled melts. Weathering leads to Fe-(hydro)oxide + digenite ±Fe-, Cu- and Pb-sulphate, Ca, Zn and Pb loss from glass and acid drainage. The slag is an excellent aggregate raw material but its chemical instability calls for preliminary processing, which might lead to economic metal recovery.

Gold mineralization in recent and ancient volcanic-hosted massive sulfides: The PACMANUS field and the Neves Corvo deposit

Gold mineralization in the Neves Corvo copper stockworks occurs in two geochemical associations: (1) Au+Co+Bi(±Te) and (2) Au+Cu+Ag(±Hg). Type 1 gold occurs in the deeper parts of the feeder zones. Its associated mineralogical assemblage is consistent with low sulfur activity of the fluid and high temperature (360°–400°C) conditions. The second type of gold geochemical association reflects pH increase and/or temperature decrease as the fluid moves upwards in the stockwork and reaches the base of the massive sulfide Neves Corvo is accompanied by high sulfidation parageneses. These might have resulted either from the long-lived maturation of the ore-forming system, which would have led to extreme zone refining effects, and/or from the late input of an external fluid component (possibly magmatic?) in the Neves Corvo hydrothermal system. In the PACMANUS hydrothermal field, native gold also occurs in both high and low sulfidation mineral associations. Gold occurs at the seafloor level either associated with: (1) chalcopyrite+sphalerite +tennatite, or (2) chalcopyrite+bornite ± covellite. At depth, instead, gold occurs in sphalerite as small native gold inclusions (silver-poor). Following the process of copper enrichment by zone-refining, gold frequently concentrates in the borders of the sphalerite grains.

Mineralogy and geochemistry of tin- and germanium-bearing copper ore, Barrigão re-mobilized vein deposit, Iberian Pyrite Belt, Portugal

The Barrigão re-mobilized copper vein deposit, Iberian Pyrite Belt, southern Portugal, is located about 60 km south of Beja and 10 km southeast of the Neves Corvo ore deposit, in Alentejo Province. The deposit is structurally associated with a NE–SW striking fault zone inferred to have developed during late Variscan deformation. The copper ore itself is a breccia-type ore, characterized by up to four ore-forming stages, with the late stages showing evidence of fluid-driven element re-mobilization. The ore is dominated by chalcopyrite + tennantite-tetrahedrite, with minor arsenopyrite, pyrite, and löllingite. The supergene paragenesis is composed mainly of bornite, covellite, and digenite. Whole-rock analyses show anomalous tin and germanium contents, with averages of 320 and 61 ppm, respectively. Electron microprobe analysis of Barrigão ores revealed the germanium and tin to be restricted to chalcopyrite, which underwent late-stage hydrothermal fluid overprint along distinct vein-like zones. The measured zonal enrichment of tin and germanium is related to limited element re-mobilization associated with mineral replacement, which resulted in distinctive mineral disequilibrium. Fluid-driven element zoning affected chalcopyrite and tennantite coevally. The average contents of germanium and tin in chalcopyrite are of 0.19 and 0.55 wt.%, respectively, as confirmed through additional micro-proton-induced X-ray emission (micro-PIXE) analysis. The distribution of tin and germanium in chalcopyrite correlates strongly with iron. Tin and germanium covary. Minute sub-microscopic inclusions of an unknown Cu–Sn–Ge sulphide phase have been detected in chalcopyrite and in small vugs therein. These inclusions hint at a stanniferous sulphide as the most possible host for tin and germanium in chalcopyrite, although the idea of limited incorporation of these two elements through element substitution cannot be completely excluded.

Science Education in a Museum: Enhancing Earth Sciences Literacy as a Way to Enhance Public Awareness of Geological Heritage

Today, scientific literacy has become increasingly important as a hallmark of citizenship and as a way to facilitate many of life’s daily decisions. Scientific literacy can be achieved through learning, a complex lifelong process that occurs both in school and out-of-school settings. As most adults only engage in formal education about science during compulsory schooling, all the learning that people go through in out-of-school settings and beyond compulsory schooling becomes extremely important toward the scientific literacy of the individual. The learning process in out-of-school settings requires interest from each person and can be facilitated by various agents, for example, museums. This is particularly true for Earth sciences as Geology topics are rarely taught within the science curricula during school. The Museu Nacional de História Natural e da Ciência provides realistic experiences that engage different publics into science and thus enhances the public science literacy. It is expected that by enhancing people’s Earth sciences literacy, it will also enhance their awareness of geological heritage.