Alwar Ramani

Synthesis, anti-microbial activities and anti-electrostatic properties of phosphonium-based ionic liquids

A range of phosphonium ionic liquids having the generic formula [PR3R′]X (R and R′ are alkyl groups; X is halide, trifluoromethanesulfonate, bis(trifluoromethylsulfonyl)imide, nitrate, dialkylphosphinate, dicyanamide, decanoate, tetrafluoroborate, hexafluorophosphate, or diisobutyldithiophosphinate have been prepared, characterised, and tested for anti-microbial activity and anti-electrostatic properties. Within this group of phosphonium salts, in contrast to their 1-alkyl-3-methylimidazolium analogues, both cation structure and the type of anion have effects on their biological activity. The ionic liquids also showed high anti-electrostatic effect.

Metal bis{(trifluoromethyl)sulfonyl}amide complexes: highly efficient Friedel?Crafts acylation catalystsElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b4/b403650f/

A range of metal bis[(trifluoromethyl)sulfonyl]amide complexes, including many unreported ones, have been synthesised, most of which have been found to be excellent Friedel-Crafts acylation catalysts in the absence of solvent; these reactions have also been carried out in ionic liquids, which allow the catalysts to be recycled and reused.