Amaury Taboada-Rodríguez

Dealcoholized wines by spinning cone column distillation: phenolic compounds and antioxidant activity measured by the 1,1-diphenyl-2-picrylhydrazyl method.

Spinning cone column (SCC) distillation has been shown to be a commercially suitable technique for dealcoholized wine (DW) manufacturing, but there are not enough studies about its influence on the DW quality. So, the effect of this technique on the antioxidant activity (% of remaining 1,1-diphenyl-2-picrylhydrazyl radical) and the phenolic compound composition of red, rose, and white DW, obtained at pilot plant scale, has been analyzed. Nineteen raw wines (RWs) from different grape varieties and five different Spanish viticultural regions have been studied before and after dealcoholization. The total phenolic content, flavonols, tartaric esters, and anthocyanins, was determined by spectrophotometry, while the content of phenolic compounds such as stilbenes (trans- and cis-resveratrol), flavonols (rutin, quercetin, and myricetin), flavan-3-ols [(+)-catechin and (-)-epicatechin], anthocyanins (malvidin 3-glucoside), and non-flavonoids (gallic, caffeic, and p-coumaric acids) was determined by high-performance liquid chromatography (HPLC). The resveratrol contents in red wines were between 1.81 and 34.01 mg/L in RWs and between 2.12 and 39.57 mg/L in DWs, Merlot being the grape producing the RWs and DWs with higher resveratrol content. In general, the percent of remaining DPPH(*) was similar or slightly higher (until 5 units of % of remaining DPPH(*)) in DWs versus RWs. This small difference may be due to removal of SO2 (that is an antioxidant) from RWs during distillation. DWs and RWs show similar contents of the studied phenolic compounds, with a tendency, in some cases, to exhibit increases after dealcoholization, caused by the concentration effect via removal of the ethanol. From this work, we can deduce that SCC distillation is a dealcoholization technique minimally destructive with the wine phenolic compounds.

Aroma Recovery in Wine Dealcoholization by SCC Distillation

The aroma recovery in wine dealcoholization by spinning cone column (SCC) distillation technique has been studied, with the analysis of the influence of the process factors: raw wine flow rate and aromatic extraction percentage. This aroma recovery has been measured in terms of aromatic richness (number of peaks obtained in the chromatogram) and aromatic intensity (total peaks area of the chromatogram) using the parameters global aromatic intensity (Iga) and aromatic concentration factor. The headspace solid-phase microextraction method and gas chromatography have been used for the determination of the aromatic compounds in raw wine and in the corresponding dealcoholized wine and the aromatic fraction separated during the SCC distillation. The optimal conditions for SCC distillation process were selected as the ones that separate the aromatic fraction with the highest Iga and the highest aromatic richness (percentage of recovered peaks) as well as with the lowest ethanol content.

Processing, Packaging, and Storage of Tomato Products: Influence on the Lycopene Content

AbstractAccording to several epidemiological studies, the lycopene content of tomato and tomato-based products is related to a variety of health benefits. This has sparked interest in knowing the effect of processing and storage of tomato products on this carotenoid, in order to preserve it during manufacturing and distribution till consumption. Furthermore, in the last few years special attention has been paid to the changes of all-trans and cis-isomers of lycopene during processing and storage. In fact, cis-isomers have shown higher health-promoting properties than all-trans isomers. Heat, light, oxygen, food matrices, and ingredients such as oil are factors that have an important effect on the main lycopene degradation reactions: isomerization and oxidation. These reactions could affect the bioavailability and reduce the bioactivity of these compounds. This article reviews the lycopene changes in tomato and tomato products during preparation operations, processing, and storage using different packaging materials. Special attention has been paid to those technological conditions which may affect the lycopene stability, particularly those able to enhance the cis-forms content that have greater bioavailability than all-trans lycopene isomers.

Hydrophobic properties of cardboard coated with polylactic acid and ethylene scavengers

The corrugated cardboard used in food packaging readily absorbs moisture from the environment, especially when stored under high humidity conditions. In this research, the water barrier of cardboard was modified by changing the wettability of the cardboard surface, applying hydrophobic coatings of polylactic acid (PLA), alone or in combination with other substances that absorb gases (ethylene scavengers) such as clinoptilolite (C), sepiolite (S), and sepiolite permanganate (SP). The water barrier properties tested as water vapor permeability (WVP), water absorptiveness (WA), and water drop contact angle (CA) showed that the water resistance of the resulting cardboard was improved by the coating. The best results of these properties were obtained by using a coating of PLA 2% alone. In addition, PLA 2% with C 1.5% also showed good results, but the WA results were higher. The use of PLA coating produces a greater uniformity and smoothness of the coated cardboard surface due to the best filling of the pores or spaces between cellulose fibers. Our findings and the environmentally friendly nature of PLA strengthen the advantages of using these kinds of coatings on cardboard trays for the packaging, storage, and transport of foods such as fresh fruit and vegetables.

Control of Native Spoilage Yeast on Dealcoholized Red Wine by Preservatives Alone and in Binary Mixtures

In order to preserve a commercial dealcoholized red wine (DRW), a study with 4 preservatives and binary mixtures of them were performed against 2 native spoilage yeasts: Rhodotorula mucilaginosa and Saccharomyces cerevisiae. Minimal inhibitory concentration (MIC) and minimal fungicidal concentration (MFC) for potassium sorbate, sodium benzoate, sodium metabisulfite and dimethyl dicarbonate (DMDC) were evaluated in DRW stored at 25 °C. MICs of potassium sorbate and sodium metabisulfite were 250 and 60 mg/kg, respectively for both target strains. However for sodium benzoate, differences between yeasts were found; R. mucilaginosa was inhibited at 125 mg/kg, while S. cerevisiae at 250 mg/kg. Regarding MFC, differences between strains were only found for sodium metabisulfite obtaining a MFC of 500 mg/kg for R. mucilaginosa and a MFC of 250 mg/kg for S. cerevisiae. Potassium sorbate and sodium benzoate showed the MFC at 1000 mg/kg and DMDC at 200 mg/kg. Regarding the effect of binary mixtures the Fractional Fungicidal Concentration Index (FFCi ) methodology showed that binary mixtures of 100 mg/kg DMDC/200 mg/kg potassium sorbate (FFCi = 0.7) and 50 mg/kg DMDC / 400 mg/kg sodium benzoate (FFCi = 0.65) have both synergistic effect against the 2 target strains. These binary mixtures can control the growth of spoilage yeasts in DRW without metabisulfite addition. The results of this work may be important in preserving the health of DRW consumers by eliminating the use of metabisulfite and reducing the risk of growth of R. mucilagosa, recently recognized as an emerging pathogen.