Amy J. Williams

Geochemistry of the Bagnold dune field as observed by ChemCam and comparison with other aeolian deposits at Gale Crater

The Curiosity rover conducted the first field investigation of an active extraterrestrial dune. This study of the Bagnold dunes focuses on the ChemCam chemical results and also presents findings on the grain size distributions based on the ChemCam Remote Micro-Imager and Mars Hand Lens Imager images. These active dunes are composed of grains that are mostly 150 μm grain-size dump piles have shown that coarser grains (150–250 μm) are enriched in the mafic elements Fe and Mn, suggesting a larger content in olivine compared to smaller grains (<150 μm) of the Bagnold dunes. Moreover, the chemistry of soils analyzed in the vicinity of the dunes indicates that they are similar to the dune material. All these observations suggest that the olivine content determined by X-ray diffraction of the <150 μm grain-size sample should be considered as a lower limit for the Bagnold dunes.

Composition of conglomerates analyzed by the Curiosity rover: Implications for Gale Crater crust and sediment sources

The Curiosity rover has analyzed various detrital sedimentary rocks at Gale Crater, among which fluvial and lacustrine rocks are predominant. Conglomerates correspond both to the coarsest sediments analyzed and the least modified by chemical alteration, enabling us to link their chemistry to that of source rocks on the Gale Crater rims. In this study, we report the results of six conglomerate targets analyzed by Alpha-Particle X-ray Spectrometer and 40 analyzed by ChemCam. The bulk chemistry derived by both instruments suggests two distinct end-members for the conglomerate compositions. The first group (Darwin type) is typical of conglomerates analyzed before sol 540; it has a felsic alkali-rich composition, with a Na2O/K2O > 5. The second group (Kimberley type) is typical of conglomerates analyzed between sols 540 and 670 in the vicinity of the Kimberley waypoint; it has an alkali-rich potassic composition with Na2O/K2O < 2. The variety of chemistry and igneous textures (when identifiable) of individual clasts suggest that each conglomerate type is a mixture of multiple source rocks. Conglomerate compositions are in agreement with most of the felsic alkali-rich float rock compositions analyzed in the hummocky plains. The average composition of conglomerates can be taken as a proxy of the average igneous crust composition at Gale Crater. Differences between the composition of conglomerates and that of finer-grained detrital sediments analyzed by the rover suggest modifications by diagenetic processes (especially for Mg enrichments in fine-grained rocks), physical sorting, and mixing with finer-grained material of different composition.

Xeropreservation of Functionalized Lipid Biomarkers in Hyperarid Soils in the Atacama Desert

Our understanding of long-term organic matter preservation comes mostly from studies in aquatic systems. In contrast, taphonomic processes in extremely dry environments are relatively understudied and are poorly understood. We investigated the accumulation and preservation of lipid biomarkers in hyperarid soils in the Yungay region of the Atacama Desert. Lipids from seven soil horizons in a 2.5 m vertical profile were extracted and analyzed using GC-MS and LC-MS. Diagnostic functionalized lipids and geolipids were detected and increased in abundance and diversity with depth. Deeper clay units contain fossil organic matter (radiocarbon dead) that has been protected from rainwater since the onset of hyperaridity. We show that these clay units contain lipids in an excellent state of structural preservation with functional groups and unsaturated bonds in carbon chains. This indicates that minimal degradation of lipids has occurred in these soils since the time of their deposition between >40,000 and 2 million years ago. The exceptional structural preservation of biomarkers is likely due to the long-term hyperaridity that has minimized microbial and enzymatic activity, a taphonomic process we term xeropreservation (i.e. preservation by drying). The degree of biomarker preservation allowed us to reconstruct major changes in ecology in the Yungay region that reflect a shift in hydrological regime from wet to dry since the early Quaternary. Our results suggest that hyperarid environments, which comprise 7.5% of the continental landmass, could represent a rich and relatively unexplored source of paleobiological information on Earth.