Anatoliy Glushchenko

Ferroelectric nematic suspension

We report on the development of a dilute suspension of ferroelectric particles in a nematic liquid-crystal (LC) host. We found that the submicron particles do not disturb the LC alignment and the suspension macroscopically appears similar to a pure LC with no readily apparent evidence of dissolved particles. The suspension possesses enhanced dielectric anisotropy, and is sensitive to the sign of an applied electric field.

Orientational Coupling Amplification in Ferroelectric Nematic Colloids

We investigated the physical properties of low concentration ferroelectric nematic colloids, using calorimetry, optical methods, infrared spectroscopy, and capacitance studies. The resulting homogeneous colloids possess a significantly amplified nematic orientational coupling. We find that the nematic orientation coupling increases by approximately 10% for particle concentrations of 0.2%. A manifestation of the increased orientational order is that the clearing temperature of a nematic colloid increases by up to 40 degrees C compared to the pure liquid crystal host. A theoretical model is proposed in which the ferroelectric particles induce local dipoles whose effective interaction is proportional to the square of the orientational order parameter.

Fast birefringent mode stressed liquid crystal

We report a stressed liquid crystal (SLC) that produce a large shift in phase retardation at submillisecond speeds. The SLC consists of uniformly aligned micro-domains of a liquid crystal dispersed in a polymer structure. Mechanical stress produces uniform alignment, essentially eliminates light scattering, and substantially improves the electro-optic performance. A 22-μm-thick SLC film switches more than 2μm of phase retardation in less than 1ms. The system has a linear voltage response with essentially no hysteresis.

Complementary studies of BaTiO3 nanoparticles suspended in a ferroelectric liquid-crystalline mixture

In scope of this paper, DSC, small-angle X-ray scattering (SAXS), electro-optic and dielectric studies have been done on BaTiO3 nanoparticles dispersed in a ferroelectric liquid-crystalline (FLC) matrix. Electro-optic studies showed slightly lower spontaneous polarization, faster response time and relatively higher coercive voltage for the nanocomposite as compared to the pure FLC mixture. Dielectric measurements revealed a lower relative dielectric permittivity for the nanocomposite. This paper addresses all the issues starting from the kind of nanoparticles and FLC materials used for the preparation of nanocomposites, the various measurements done and a detailed discussion on the observed results.

Preparation of ferroelectric nanoparticles for their use in liquid crystalline colloids

In this paper we summarize our many years of experience in the preparation and optimization of stable colloids of ferroelectric nanoparticles dispersed in an isotropic carrier and in a liquid crystal host. The colloids are of interest for use in electro-optic devices, photorefractive hybrids and nonlinear optical elements. We also outline some of the most interesting features the nanoparticles bring to liquid crystals, along with the potential of these relatively new colloids.

Ferroelectric Particles in Liquid Crystals: Recent Frontiers

In this article we describe electro-optical properties of recently discovered ferroelectric particles/liquid crystal colloids. We show that the presence of ferroelectric particles in a liquid crystal changes its birefringence and dielectric anisotropy. In contrast to the traditional time consuming and expensive chemical synthetic methods, this method to create liquid crystals with enhanced properties is relatively simple and has a great potential. We also demonstrate the performance of these new materials in various devices, including displays, light modulators, and beam steering devices.

Liquid crystal phase shifters at millimeter wave frequencies

We demonstrate an on-wafer liquid crystal phase shifter which has a tunable 0–300°/cm phase shift at 110 GHz. The results show no dispersion over the entire frequency range indicating a tunable “true time delay” of up to 2.5 ps/cm at all frequencies. The inherent losses in the liquid crystal are small, less than 1 dB/cm over the range of 1–110 GHz. The full tunability is achieved using small voltages, close to 10 V. We anticipate that one could achieve a phase shift of 600°/cm at 220 GHz.

Ferroelectric nanoparticle/liquid-crystal colloids for display applications

— A non-synthetic approach to modify liquid crystals (LCs) by dispersing low concentrations of ferroelectric nanoparticles is reported. These dilute colloids are stable and appear similar to a pure LC. However, by changing the concentration and the type of ferroelectric particles, the physical properties of the LC materials can be tailored, including the nematic isotropic transition temperature (TNI), the dielectric constants, the birefringence (Δn), elastic constants, and the threshold voltage. Specifically, doping low concentrations of BaTiO3 nanoparticles (∼1%) into a LC MLC-6609 increases TNI up to ∼40°C. This giant shift of TNI has never been previously reported and indicates strong interactions between the LC and ferroelectric nanoparticles on a molecular level. The doped LC also demonstrates significant enhancement in birefringence (by 10–30%), dielectric anisotropy (by ∼50%), and the elastic constant K33 (by ∼20%). Ferroparticles act as molecular additives and modify the intrinsic properties of LC materials without time consuming and expensive chemical synthesis. The new LC materials are very attractive and suitable for use in displays, switchable lenses, beam steering, as well as other light-controlling devices.

Drag on particles in a nematic suspension by a moving nematic-isotropic interface

We report a clear demonstration of drag on colloidal particles by a moving nematic-isotropic interface. The balance of forces explains our observation of periodic, striplike structures that are produced by the movement of these particles.

Harvesting single ferroelectric domain stressed nanoparticles for optical and ferroic applications

We describe techniques to selectively harvest single ferroelectric domain nanoparticles of BaTiO3 as small as 9 nm from a plethora of nanoparticles produced by mechanical grinding. High resolution transmission electron microscopy imaging shows the unidomain atomic structure of the nanoparticles and reveals compressive and tensile surface strains which are attributed to the preservation of ferroelectric behavior in these particles. We demonstrate the positive benefits of using harvested nanoparticles in disparate liquid crystal systems.