Andrea Rubano

Observation of optical polarization Möbius strips

Light with twist and structure Möbius strips are three-dimensional structures consisting of a surface with just a single side. Readily demonstrated by snipping a paper ring, adding a twist, and then joining the ends of paper together again, these structures have intriguing mathematical properties in terms of topology and geometry. Bauer et al. used a liquid crystal to engineer the wavefront of a laser beam to make an optical version of the Möbius strip by effectively “snipping and twisting” the polarization properties of the light beam. Science, this issue p. 964 An optical version of a Möbius strip has been realized. Möbius strips are three-dimensional geometrical structures, fascinating for their peculiar property of being surfaces with only one “side”—or, more technically, being “nonorientable” surfaces. Despite being easily realized artificially, the spontaneous emergence of these structures in nature is exceedingly rare. Here, we generate Möbius strips of optical polarization by tightly focusing the light beam emerging from a q-plate, a liquid crystal device that modifies the polarization of light in a space-variant manner. Using a recently developed method for the three-dimensional nanotomography of optical vector fields, we fully reconstruct the light polarization structure in the focal region, confirming the appearance of Möbius polarization structures. The preparation of such structured light modes may be important for complex light beam engineering and optical micro- and nanofabrication.

Direct Femtosecond Laser Surface Structuring with Optical Vortex Beams Generated by a q-plate

Creation of patterns and structures on surfaces at the micro- and nano-scale is a field of growing interest. Direct femtosecond laser surface structuring with a Gaussian-like beam intensity profile has already distinguished itself as a versatile method to fabricate surface structures on metals and semiconductors. Here we present an approach for direct femtosecond laser surface structuring based on optical vortex beams with different spatial distributions of the state of polarization, which are easily generated by means of a q-plate. The different states of an optical vortex beam carrying an orbital angular momentum ℓ = ±1 are used to demonstrate the fabrication of various regular surface patterns on silicon. The spatial features of the regular rippled and grooved surface structures are correlated with the state of polarization of the optical vortex beam. Moreover, scattered surface wave theory approach is used to rationalize the dependence of the surface structures on the local state of the laser beam characteristics (polarization and fluence). The present approach can be further extended to fabricate even more complex and unconventional surface structures by exploiting the possibilities offered by femtosecond optical vector fields.

Blue luminescence of SrTiO3 under intense optical excitation

The blue-green photoluminescence emitted by pure and electron-doped strontium titanate under intense pulsed near-ultraviolet excitation is studied experimentally, as a function of excitation intensity and temperature. Both emission spectra and time-resolved decays of the emission are measured and analyzed in the framework of simple phenomenological models. We find an interesting blue-to-green transition occurring for increasing temperatures in pure samples, which is instead absent in doped materials. The luminescence yield and decay rate measured as a function of temperature can be modeled well as standard activated behaviors. The leading electron-hole recombination process taking place in the initial decay is established to be second-order, or bimolecular, in contrast to recent reports favoring a third-order interpretation as an Auger process. The temporal decay of the luminescence can be described well by a model based on two interacting populations of excitations, respectively identified with interacting defect-trapped (possibly forming excitons) and mobile charges. Finally, from the measured doping and sample dependence of the luminescence yield, we conclude that the radiative centers responsible for the luminescence are probably intrinsic structural defects other than bulk oxygen vacancies.

Femtosecond laser surface structuring of silicon using optical vortex beams generated by a q-plate

We report on laser surface structuring of silicon using Ti:Sa femtosecond laser ablation with optical vortex beams. A q-plate is used to generate an optical vortex beam with femtosecond pulse duration through spin-to-orbital conversion of the angular momentum of light. The variation of the produced surface structures is investigated as a function of the number of pulses, N, at laser fluence slightly above the ablation threshold value. At low N (≈10), only surface corrugation of the irradiated, ring-shaped area is observed. This is followed by a progressive formation of regular ripples at larger N (≈100–500), which eventually transform in smaller columnar structures for N ≈ 1000. Moreover, the central, non-ablated part is gradually decorated by nanoparticles produced during laser ablation, a process which eventually leads to the formation of a central turret of assembled nanoparticles. Our experimental findings suggest the importance of a feedback mechanism and a cumulative effect on the formation of ripples with interesting patterns not achievable by the more standard beams with a Gaussian intensity profile.

Q-plates as higher order polarization controllers for orbital angular momentum modes of fiber.

We demonstrate that a |q|=1/2 plate, in conjunction with appropriate polarization optics, can selectively and switchably excite all linear combinations of the first radial mode order |l|=1 orbital angular momentum (OAM) fiber modes. This enables full mapping of free-space polarization states onto fiber vector modes, including the radially (TM) and azimuthally polarized (TE) modes. The setup requires few optical components and can yield mode purities as high as ∼30  dB. Additionally, just as a conventional fiber polarization controller creates arbitrary elliptical polarization states to counteract fiber birefringence and yield desired polarizations at the output of a single-mode fiber, q-plates disentangle degenerate state mixing effects between fiber OAM states to yield pure states, even after long-length fiber propagation. We thus demonstrate the ability to switch dynamically, potentially at ∼GHz rates, between OAM modes, or create desired linear combinations of them. We envision applications in fiber-based lasers employing vector or OAM mode outputs, as well as communications networking schemes exploiting spatial modes for higher dimensional encoding.

Recombination kinetics of a dense electron-hole plasma in strontium titanate

We investigated the nanosecond-scale time decay of the blue-green light emitted by nominally pure

Direct femtosecond laser ablation of copper with an optical vortex beam

\mathrm{Sr}\mathrm{Ti}{\mathrm{O}}_{3}

Potential-well depth at amorphous-LaAlO3/crystalline-SrTiO3 interfaces measured by optical second harmonic generation

following the absorption of an intense picosecond laser pulse generating a high density of electron-hole pairs. Two independent components are identified in the fluorescence signal that show a different dynamics with varying excitation intensity and which can be modeled as a bimolecular and unimolecolar process. An interpretation of the observed recombination kinetics in terms of interacting electron and hole polarons is proposed.

Laser ablation of silicon induced by a femtosecond optical vortex beam.

Laser surface structuring of copper is induced by laser ablation with a femtosecond optical vortex beam generated via spin-to-orbital conversion of the angular momentum of light by using a q-plate. The variation of the produced surface structures is studied as a function of the number of pulses, N, and laser fluence, F. After the first laser pulse (N = 1), the irradiated surface presents an annular region characterized by a corrugated morphology made by a rather complex network of nanometer-scale ridges, wrinkles, pores, and cavities. Increasing the number of pulses (2   1000) and a deep crater is formed. The nanostructure variat...

Optical second-harmonic generation selection rules and resonances in buried oxide interfaces: the case of LaAlO 3 /SrTiO 3

By a combination of optical second harmonic generation and transport measurements, we have investigated interfaces formed by either crystalline or amorphous thin films of LaAlO3 grown on TiO2-terminated SrTiO3(001) substrates. Our approach aims at disentangling the relative role of intrinsic and extrinsic doping mechanisms in the formation of the two-dimensional electron gas. The different nature of the two mechanisms is revealed when comparing the sample response variation as a function of temperature during annealing in air. However, before the thermal treatment, the two types of interfaces show almost the same intensity of the second harmonic signal, provided the overlayer thickness is the same. As we will show, the second harmonic signal is proportional to the depth of the potential well confining the charges at the interface. Therefore, our result demonstrates that this depth is about the same for the two different material systems. This conclusion supports the idea that the electronic properties of ...